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    PYRIDYLDIAMIDE METAL CATALYSTS AND PROCESSES TO PRODUCE POLYOLEFINS
    5.
    发明公开
    PYRIDYLDIAMIDE METAL CATALYSTS AND PROCESSES TO PRODUCE POLYOLEFINS 审中-公开
    吡啶二酰胺金属催化剂和生产聚烯烃的方法

    公开(公告)号：EP2989130A4

    公开(公告)日：2016-05-25

    申请号：EP14788051

    申请日：2014-04-22

    申请人： EXXONMOBIL CHEM PATENTS INC

    发明人： HAGADORN JOHN R ,  BORISOV ILYA S ,  GOLENISHCHEV ARKADY K ,  UBORSKY DMITRY V ,  VOSKOBOYNIKOV ALEXANDER Z ,  SAMSONOV OLEG V ,  SHARIKOV MICHAIL I

    IPC分类号： C08F4/16 ,  C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6937 ,  C08F110/06 ,  C08F2500/03 ,  C08F2500/04 ,  C08F210/16 ,  C08F210/14 ,  C08F4/65908 ,  C08F4/64148

    摘要： Disclosed are new classes of pyridyldiamide catalyst components useful in olefin polymerization, an example of which includes: wherein M is a hafnium or zirconium; R1 and R11 are selected from phenyl and substituted phenyl, wherein the substitutions are selected from C1 to C5 hydrocarbyls, preferably C2 to C4 hydrocarbyls, and can reside in any of the ortho, meta, para positions on the phenyl ring; R2′ and R2″ are selected independently from hydrogen and C1 to C6 hydrocarbyls, preferably hydrogen; R10 is a hydrocarbyl bridging group; R3, R4, and R5 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; and R6, R7, R8, and R9 are independently selected from hydrogen, hydrocarbyls, and substituted hydrocarbyls; wherein R6 and R7 form an aromatic ring or R7 is hydrogen and R6 is selected from methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, and tert-butyl, preferably methyl.

    摘要翻译： 公开了可用于烯烃聚合的新类型的吡啶基二酰胺催化剂组分，其实例包括：其中M是铪或锆; R 1和R 11选自苯基和取代的苯基，其中取代选自C 1至C 5烃基，优选C 2至C 4烃基，并且可以位于苯环上的任何邻位，间位，对位; R2'和R2“独立地选自氢和C1至C6烃基，优选氢; R10是烃基桥联基团; R 3，R 4和R 5独立地选自氢，烃基和取代的烃基; 且R 6，R 7，R 8和R 9独立地选自氢，烃基和取代的烃基; 其中R6和R7形成芳环或R7是氢，R6选自甲基，乙基，丙基，异丙基，丁基，仲丁基和叔丁基，最好是甲基。

    IMPROVED ALKYLATION PROCESS
    8.
    发明公开
    IMPROVED ALKYLATION PROCESS 有权
    VERBESSERTES ALKYLIERUNGSVERFAHREN

    公开(公告)号：EP2571832A4

    公开(公告)日：2015-11-25

    申请号：EP11783911

    申请日：2011-04-15

    申请人： EXXONMOBIL CHEM PATENTS INC

    发明人： VINCENT MATTHEW J ,  NANDA VIJAY ,  HELTON TERRY E

    IPC分类号： C07C2/66 ,  B01J20/18 ,  C07C7/12 ,  C07C15/073 ,  C07C15/085

    CPC分类号： C07C2/66 ,  C07C7/12 ,  C07C2529/08 ,  C07C2529/18 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52 ,  C07C15/02 ,  C07C15/073 ,  C07C15/085 ,  C07C15/04

    摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in−1 (12 cm−1) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30° C. to about 300° C. to form an effluent comprising said treated alkylatable aromatic compound.

    摘要翻译： 本发明提供了一种由至少部分未经处理的具有催化剂毒素和烷基化剂的可烷化芳族化合物制备烷基化芳族化合物的改进方法，其中所述可烷化芳族化合物流用具有表面积的处理组合物处理以还原催化剂毒物 /表面积比大于或等于30in-1（12cm-1）的处理区域与烷基化反应区分离，处理条件包括温度为约30℃至约300℃至 形成包含所述经处理的可烷基化芳族化合物的流出物。