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公开(公告)号：EP3374353A1
公开(公告)日：2018-09-19
申请号：EP17735072.5
申请日：2017-06-28
Applicant: Evonik Degussa GmbH
Inventor： MEIER, Ralf , BAJUS, Stephanie , DÖRING, Jens
IPC: C07D301/12 , C07D225/02 , C07C45/58 , C07C249/08 , B01J38/64 , B01J38/66 , B01J23/30
CPC classification number: C07D301/12 , B01J23/30 , B01J38/64 , B01J38/66 , C07C45/58 , C07C249/08 , C07C2601/20 , C07D225/02 , Y02P20/584 , C07C49/413 , C07C251/44
Abstract: The invention relates to a method for reactivating homogeneous catalyst systems from organic reaction mixtures. The catalyst systems are suitable for oxidating organic compounds such as, for example cyclododecene. The reactivation is carried out by means of an aqueous base.
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2.发明公开A process for regenerating a deactivated heteropolymolybdophosphoric acid catalyst 有权维生素zur再生eines deaktivierten杂多聚磷酸盐
公开(公告)号：EP2433709A1
公开(公告)日：2012-03-28
申请号：EP11183099.8
申请日：2011-09-28
Applicant: Shanghai HuaYi Acrylic Acid Co. Ltd.
Inventor： Wen Xin , Zuo Linghua , Luo Ge , Zhao Xiaoqi , Zhuang Yan , Chu Xiaodong , Shao Jingming
CPC classification number: B01J38/66 , B01J23/002 , B01J27/19 , B01J27/199 , B01J27/285 , B01J37/0009 , B01J37/0036 , B01J38/02 , B01J38/12 , B01J2523/00 , C07C51/252 , Y02P20/584 , B01J2523/13 , B01J2523/15 , B01J2523/17 , B01J2523/51 , B01J2523/52 , B01J2523/53 , B01J2523/55 , B01J2523/68 , C07C57/04
Abstract: The present invention provided a process for regenerating a deactivated heteropolymolybdophosphoric acid catalyst comprising the steps of grinding the deactivated catalyst into particles having a particle size of 40 mesh or less, mixing same with a mixture consisting of aqua ammonia, an aqueous solution containing ammonium ion and organic auxiliaries and kneading same in a kneader to obtain a paste, drying the paste and molding into cylindrical particle with a through hole in its longitudinal axis, and heating in atmosphere at 350 - 450°C for 1 ~ 10 hours to produce the generated catalyst. The catalytic capacity of such a catalyst having keggin structure of heteropoly acid fully recovered is fully restored for selective oxidation of lower unsaturated aldehydes (such as acrolein or isobutyraldehyde) to produce unsaturated acids. The regeneration is conducted under mild condition by a simple and easy process with good reproducibility.
Abstract translation: 本发明提供了一种再生失活的杂多磷酸催化剂的方法，包括以下步骤：将失活的催化剂研磨成粒度为40目以下的颗粒，将其与由氨水，含有铵离子的水溶液和 在捏合机中进行有机助剂和捏合以获得糊剂，将其干燥并在其纵轴上成型为具有通孔的圆柱形颗粒，并在350-450℃的气氛中加热1〜10小时以产生所产生的催化剂 。 完全回收杂多酸的keggin结构的催化剂的催化能力完全恢复，用于选择性氧化低级不饱和醛（如丙烯醛或异丁醛）以产生不饱和酸。 再生是在温和的条件下，通过简便易行的过程进行，重复性好。
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3.发明公开
公开(公告)号：EP2367630A1
公开(公告)日：2011-09-28
申请号：EP09775199.4
申请日：2009-12-16
CPC classification number: B01J31/403 , B01J23/75 , B01J38/02 , B01J38/10 , B01J38/66 , B01J2531/845 , C10G2/332 , C10G2300/70
Abstract: A process for regenerating one or more deactivated cobalt comprising Fischer-Tropsch catalyst particle (s)
in situ in a reactor tube, said process comprising the steps of : (i) oxidising the catalyst particle(s) at a temperature between 20 and 400 °C; (ii) treating the catalyst particle (s) for more than 5 minutes with a solvent, (iii) drying the catalyst particle (s); and (iv) optionally reducing the catalyst with hydrogen or a hydrogen comprising gas. This process may be preceded by a step in which Fischer-Tropsch product is removed from the catalyst particle(s).
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公开(公告)号：EP1587615A4
公开(公告)日：2010-09-01
申请号：EP03714398
申请日：2003-03-25
Applicant: HEADWATERS TECH INNOVATION LLC
Inventor： BING ZHOU , RUETER MICHAEL
IPC: B01J23/44 , B01J23/96 , B01J35/10 , B01J38/12 , B01J38/52 , B01J38/62 , B01J38/66 , B01J38/68 , B01J38/72 , C01B15/023 , B01J20/00 , B01J20/34 , B01J21/00 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/08 , B01J29/06 , B01J38/50 , B01J38/56
CPC classification number: B01J38/68 , B01J23/44 , B01J23/96 , B01J35/1014 , B01J35/1061 , B01J38/12 , B01J38/52 , B01J38/62 , B01J38/66 , B01J38/72 , C01B15/023 , Y02P20/584
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5.发明公开Process for regenerating catalyst for producing a-caprolactam and process for producing e-caprolactam 审中-公开一种回收生产ε-己内酰胺及其生产ε-己内酰胺的催化剂的方法
公开(公告)号：EP1875964A1
公开(公告)日：2008-01-09
申请号：EP07111516.6
申请日：2007-07-02
Applicant: Sumitomo Chemical Company, Limited
Inventor： Sugita, Keisuke , Kitamura, Masaru
IPC: B01J29/90 , B01J38/66 , C07D201/04
CPC classification number: B01J29/90 , B01J38/66 , B01J2229/32 , C07D201/04 , Y02P20/52 , Y02P20/584
Abstract: The present invention provides a process for regenerating a catalyst for producing e-caprolactam comprising the steps of adsorbing a silicon compound on a zeolite catalyst that had been used for a Beckmann rearrangement reaction of cyclohexanone oxime and contacting the catalyst with an aqueous solution containing a compound selected from a quaternary ammonium compound, lower alkylamines and ammonia. The present invention also provides a process for producing e-caprolactam comprising subjecting cyclohexanone oxime to the Beckmann rearrangement reaction in the presence of the catalyst thus regenerated.
Abstract translation: 本发明提供了一种用于与wässrige溶液含有化合物再生为生产ε-己内酰胺，包括吸附在沸石催化剂的硅化合物步骤的催化剂也已被用于环己酮肟的贝克曼重排反应和接触催化剂 从季铵化合物，低级烷基胺和氨中。 因此，本发明提供了用于生产ε-己内酰胺包括使环己酮肟在这样再生的催化剂的存在下进行贝克曼重排反应的方法。
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公开(公告)号：EP1480931B1
公开(公告)日：2007-08-08
申请号：EP03703689.4
申请日：2003-01-03
Applicant: ExxonMobil Research and Engineering Company
CPC classification number: B01J21/063 , B01J23/40 , B01J23/6567 , B01J23/70 , B01J23/75 , B01J23/8896 , B01J23/89 , B01J23/94 , B01J23/96 , B01J38/10 , B01J38/12 , B01J38/56 , B01J38/58 , B01J38/66 , C10G2/332 , C10G2/333
Abstract: A process for enhancing metal catalysts for carbon monoxide hydrogenation comprising reducing the catalyst so that at least a portion is in the metallic state, impregnating under a non-oxidative atmosphere with a solution of a salt of at least one metal, optionally in combination with at least one of an ammonium salt, an alkyl ammonium salt, a weak organic acid and ammonia, oxidizing with a gaseous oxidant in the presence of the impregnating solution, and reducing to form an active catalyst. used catalysts enhanced by the process are initially treated to decrease their hydrocarbon content. The treatment may be carrier out in a single reactor, or by carrying out up to all steps after catalyst may be withdrawn from a reactor and returned to at least one reactor, both preferably during operations. Up to all steps may be effected in a subsequent reactor, or in specialized apparatus.
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7.发明公开Method for producing epsilon-Carpolactam and method for reactivating catalyst for producing epsilon-Carpolactam 有权一种用于ε-己内酰胺和方法的制备方法中用于重新激活的催化剂用于生产ε-己内酰胺的
公开(公告)号：EP1593433A1
公开(公告)日：2005-11-09
申请号：EP05002577.4
申请日：2005-02-08
Applicant: Sumitomo Chemical Company, Limited
Inventor： Sugita, Keisuke , Kitamura, Masaru , Hoshino, Masahiro
IPC: B01J38/62 , B01J38/66 , B01J29/90 , C07D201/04
CPC classification number: B01J38/08 , B01J29/90 , B01J38/12 , B01J38/66 , C07D201/04 , Y02P20/52 , Y02P20/584
Abstract: A method for producing ε-caprolactam and a method for reactivating a zeolite catalyst for producing ε-caprolactam are provided. In the reactivation step, a zeolite catalyst is allowed to contact a gas containing a carboxylic acid, water and a compound selected from ammonia and amines. In accordance with the present invention, the catalytic activities of a zeolite catalyst used for the Beckmann rearrangement reaction of cyclohexanone oxime can be effectively restored. Consequently, ε-caprolactam may be produced with a high production yield for a long period of time by reusing the catalyst by the method described above.
Abstract translation: 提供一种用于生产ε-己内酰胺和用于重新激活的制造ε-己内酰胺的沸石催化剂的方法方法。 在活化步骤中，沸石催化剂允许接触含有羧酸，水和由氨和cardamines中选择的化合物的气体。 在本发明雅舞蹈，用于环己酮肟的贝克曼重排反应的沸石催化剂的催化活性可以得到有效恢复。 因此，可以以高生产成品率用于通过重新使用通过上述方法所述的催化剂的很长一段时间来产生ε-己内酰胺。
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公开(公告)号：EP0882503B1
公开(公告)日：2005-07-13
申请号：EP98114555.0
申请日：1995-05-01
Applicant: SHELL OIL COMPANY
CPC classification number: B01J23/881 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J27/188 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J37/0203 , B01J37/06 , B01J38/66 , C10G35/06 , C10G45/04 , C10G45/60 , C10G47/02 , C10G49/04
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公开(公告)号：EP0758919A1
公开(公告)日：1997-02-26
申请号：EP95918861.0
申请日：1995-05-01
Applicant: CYTEC TECHNOLOGY CORP.
CPC classification number: B01J23/881 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/94 , B01J27/188 , B01J35/023 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J37/0203 , B01J37/06 , B01J38/66 , C10G35/06 , C10G45/04 , C10G45/60 , C10G47/02 , C10G49/04
Abstract: Provided are high activity catalysts based upon gamma alumina containing substrates impregnated with one or more catalytically active metals, which catalysts in addition contain a nanocrystalline phase of alumina of a crystallite size at the surface of less than 25 Å. Also provided are processes for preparing such high activity catalysts and various uses thereof.
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公开(公告)号：EP0515116A2
公开(公告)日：1992-11-25
申请号：EP92304463.0
申请日：1992-05-18
Applicant: TEXACO CHEMICAL INC.
Inventor： Meyer, Robert Allen , Marquis, Edward Thomas
IPC: C22B34/34
CPC classification number: B01J31/34 , B01J31/0202 , B01J31/4015 , B01J38/66 , B01J2231/72 , C07C29/132 , C07D301/32 , C07F11/005 , C22B34/34 , Y02P20/52 , Y02P20/584 , C07C31/12
Abstract: An epoxidation reaction product formed by the molybdenum catalyzed reaction of propylene with tertiary butyl hydroperoxide to provide propylene oxide and tertiary butyl alcohol is separated by distillation into a propylene fraction, a propylene oxide fraction, a tertiary butyl alcohol fraction and a heavy liquid distillation fraction composed primarily of tertiary butyl hydroperoxide, tertiary butyl alcohol, dissolved molybdenum catalyst, and impurities including lower aliphatic C₁-C₄ carboxylic acids, and the heavy liquid distillation fraction is saturated with ammonia to precipitate the molybdenum therefrom for recovery.
Abstract translation: 通过丙烯与叔丁基过氧化氢的钼催化反应形成环氧丙烷和叔丁醇形成的环氧化反应产物通过蒸馏分离成丙烯馏分，环氧丙烷馏分，叔丁醇馏分和重液体蒸馏馏分 主要是叔丁基过氧化氢，叔丁醇，溶解的钼催化剂和包括低级脂肪族C 1 -C 4羧酸的杂质，重质液体蒸馏馏分用氨饱和，使钼从中回收。
