PROCESS FOR IMPROVING WATER-WHITENING RESISTANCE OF PRESSURE SENSITIVE ADHESIVES
    9.
    发明授权
    PROCESS FOR IMPROVING WATER-WHITENING RESISTANCE OF PRESSURE SENSITIVE ADHESIVES 有权
    提高压敏胶粘剂抗水性的方法

    公开(公告)号:EP1409560B1

    公开(公告)日:2006-12-20

    申请号:EP02744856.2

    申请日:2002-07-11

    CPC classification number: C08F220/18 C09J133/064 C09J2201/606

    Abstract: Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) a hydrophobic monomer mixture of at least one alkyl acrylate or alkyl methacrylate ester of an alcohol wherein the alkyl portion of the alcohol is linear or branched and contains at least 4 carbon atoms, and at least one styrenic monomer, wherein the styrenic monomer is up to about 30 wt. % of the total hydrophobic monomer mixture, (ii) at least about 1 wt: % of at least one hydrophilic monomer, (iii) at least about 5 wt. % of at least one partially hydrophilic monomer selected from alkyl acrylate or alkyl methacrylate esters of an alcohol wherein the alkyl portion of the alcohol has 1 to 2 carbon atoms, N-vinyl-2-pyrrolidone, or mixtures thererof, and (iv) a water-soluble or water-dispersible polymerizable surfactant selected from compounds having a terminal allyl amine moiety, polyoxyalkylene-1-(allyloxymethyl) alkyl ether sulfate salts, or mixtures thereof, and the average particle size of the polymer is less than or equal to 200nm. Also disclosed are processes for preparing same.

    Abstract translation: 公开了包含水乳液聚合物的具有增强的耐水增白性的压敏粘合剂组合物。 所述聚合物包含可聚合水性乳液的聚合反应产物,所述可聚合水性乳液包含:(i)至少一种醇的丙烯酸烷基酯或甲基丙烯酸烷基酯酯的疏水性单体混合物,其中所述醇的烷基部分为直链或支链并且含有至少4个 碳原子和至少一种苯乙烯类单体,其中苯乙烯类单体高达约30wt。 (ii)至少约1重量%的至少一种亲水单体,(iii)至少约5重量% %的至少一种部分亲水性单体,其选自其中醇的烷基部分具有1至2个碳原子的醇的丙烯酸烷基酯或甲基丙烯酸烷基酯,N-乙烯基-2-吡咯烷酮或其混合物,和(iv) 选自具有末端烯丙胺部分的化合物,聚氧化烯-1-(烯丙氧基甲基)烷基醚硫酸盐或其混合物的水溶性或水分散性可聚合表面活性剂,并且聚合物的平均粒度小于或等于200nm 。 还公开了制备它的方法。

Patent Agency Ranking