Abstract:
The invention relates to a method for curing preferably latent reactive compositions which do not cure at room temperature but can be cured by heating. The composition contains a polymer which can be obtained by reaction of certain compounds having two aldehyde groups with polyacrylate compounds having two or more acrylate groups, and a compound which carries at least two thiol groups.
Abstract:
The present invention makes a water-dispersed PSA composition capable of forming a PSA that exhibits good adhesiveness to a non-polar adherend such as polyethylene and polypropylene at a low temperature. The water-dispersed PSA composition comprises a (meth)acrylic polymer obtained by polymerizing a monomer composition comprising as a primary component an alkyl (methacrylate having an alkyl group with 1 to 18 carbon atoms, and a latex containing a rubber component that is immiscible with the (meth)acrylic polymer, the (meth)acrylic polymer and the latex being mixed at a weight ratio ((meth)acrylic polymer/rubber latex) within a range of 95/5 to 25/75 based on solid contents; wherein a storage modulus in a range of-15 °C to 25 °C is I MPa or smaller, the storage modulus being determined by a dynamic viscoelastic measurement in which shear strain is applied at a frequency of 1 Hz, the measurement being taken with respect to the water-dispersed PSA composition dried at 100 °C for 3 minutes.
Abstract:
The present invention makes a water-dispersed PSA composition capable of forming a PSA that exhibits good adhesiveness to a non-polar adherend such as polyethylene and polypropylene at a low temperature. The water-dispersed PSA composition comprises a (meth)acrylic polymer obtained by polymerizing a monomer composition comprising as a primary component an alkyl (methacrylate having an alkyl group with 1 to 18 carbon atoms, and a latex containing a rubber component that is immiscible with the (meth)acrylic polymer, the (meth)acrylic polymer and the latex being mixed at a weight ratio ((meth)acrylic polymer/rubber latex) within a range of 95/5 to 25/75 based on solid contents; wherein a storage modulus in a range of-15 °C to 25 °C is I MPa or smaller, the storage modulus being determined by a dynamic viscoelastic measurement in which shear strain is applied at a frequency of 1 Hz, the measurement being taken with respect to the water-dispersed PSA composition dried at 100 °C for 3 minutes.
Abstract:
In the method for producing a medical pressure-sensitive adhesive tape or sheet of the invention, a water dispersion-type copolymer solution having a specific composition is used. Therefore, the problem caused by high thixotropy can be eliminated and a pressure-sensitive adhesive layer can be relatively easily formed on a porous substrate by a direct method. In addition, when the medical pressure-sensitive adhesive tape or sheet obtained by the method of the invention is attached to the skin surface, skin adhesion and tube fixing are excellent and at the same time, irritation to skin is low.
Abstract:
A pressure-sensitive adhesive composition which is excellent in durability under high temperature and humidity conditions and can thus inhibit bright defect even when applied to a large-sized optical film; a pressure-sensitive adhesive; and an optical film. A pressure-sensitive adhesive composition comprising an acrylic copolymer (A) bearing a reactive functional group, an acrylic copolymer (B) and an isocyanate compound (C), wherein the quantity of the isocyanate compound (C) is 5 to 30 parts by weight per 100 parts by weight of a mixture of the acrylic copolymer (A) and the acrylic copolymer (B) and the elongation at break and 200 % modulus as determined at 25 degrees C by the tensile test are 300 to 1000 % and 0.2 to 3 N/mm 2 respectively.
Abstract:
The invention relates to adhesives comprising at least one silicon-containing C1-C20 alkyl(meth)acrylate copolymer and at least one ethylenically unsaturated acid anhydride, an ethylenically unsaturated dicarboxylic acid whose carboxylic acid groups can form an anhydride group, mixtures thereof, or at least one radically copolymerizable monomer that contains an isocyanate group.
Abstract:
The present application is directed to a colored adhesive which has various kinds of colors, darkness or brightness; can be applied and peeled easily; and has good adhesion and appearance. The acrylic colored adhesive comprises a carboxylic group-containing (meth)acrylic polymer, an inorganic filler, such as a pigment, or a dye, and an amino group-containing (meth)acrylic polymer free of aromatic vinyl monomers.
Abstract:
Pressure sensitive adhesive compositions having enhanced resistance to water-whitening comprising an aqueous emulsion polymer are disclosed. The polymer comprises the polymerization reaction product of a polymerizable aqueous emulsion comprising: (i) a hydrophobic monomer mixture of at least one alkyl acrylate or alkyl methacrylate ester of an alcohol wherein the alkyl portion of the alcohol is linear or branched and contains at least 4 carbon atoms, and at least one styrenic monomer, wherein the styrenic monomer is up to about 30 wt. % of the total hydrophobic monomer mixture, (ii) at least about 1 wt: % of at least one hydrophilic monomer, (iii) at least about 5 wt. % of at least one partially hydrophilic monomer selected from alkyl acrylate or alkyl methacrylate esters of an alcohol wherein the alkyl portion of the alcohol has 1 to 2 carbon atoms, N-vinyl-2-pyrrolidone, or mixtures thererof, and (iv) a water-soluble or water-dispersible polymerizable surfactant selected from compounds having a terminal allyl amine moiety, polyoxyalkylene-1-(allyloxymethyl) alkyl ether sulfate salts, or mixtures thereof, and the average particle size of the polymer is less than or equal to 200nm. Also disclosed are processes for preparing same.
Abstract:
Pressure sensitive adhesives can be formed using gamma irradiation. One embodiment is a pressure sensitive adhesive which is a polymeric reaction product formed by gamma ray irradiation of an emulsion composition. The emulsion composition includes water; (meth)acrylate monomer material; polar, free-radically polymerizable material that is copolymerizable with the (meth)acrylate monomer material; and at least one emulsifier.