METHOD FOR INCREASING THE SULFURIC ACID CONCENTRATION OF A SULFURIC ACID SOLUTION
    1.
    发明公开
    METHOD FOR INCREASING THE SULFURIC ACID CONCENTRATION OF A SULFURIC ACID SOLUTION 有权
    法提高硫酸溶液的浓度硫酸

    公开(公告)号:EP2643267A1

    公开(公告)日:2013-10-02

    申请号:EP11779372.9

    申请日:2011-10-26

    CPC classification number: C01B17/88 D01F13/04 Y02P70/629

    Abstract: The invention pertains to a method of increasing the sulfuric acid concentration of a first aqueous sulfuric acid solution with a sulfuric acid concentration of 82-89% to a concentrated sulfuric acid solution with a sulfuric acid concentration of at least 90%, comprising the steps of evaporating water from the first aqueous sulfuric acid solution in an evaporator vessel to the concentrated sulfuric acid solution, pumping around a mixture of the first aqueous sulfuric acid solution, part of the concentrated sulfuric acid solution, a second aqueous sulfuric acid solution, and hydrogen peroxide through an enameled piping system comprising the evaporator vessel and one or more heaters and pumps, which piping system is operating at a temperature of at least 180°C, characterized in that the sulfuric acid concentration of the second aqueous sulfuric acid solution is at least 90%.

    METHOD FOR SPINNING AND WASHING ARAMID FIBER AND RECOVERING SULFURIC ACID
    2.
    发明授权
    METHOD FOR SPINNING AND WASHING ARAMID FIBER AND RECOVERING SULFURIC ACID 有权
    方法自旋和芳纶纤维洗涤回收选自硫酸

    公开(公告)号:EP2205781B1

    公开(公告)日:2012-06-20

    申请号:EP08842223.3

    申请日:2008-10-10

    Abstract: The invention pertains to a method for spinning and washing aramid fiber and for recovering sulfuric acid, using a spinning unit and a sulfuric acid recovery unit, comprising the steps: a) spinning an aramid polymer from a sulfuric acid spin dope to a yarn and coagulating the yarn in a coagulation bath having an inlet for water or diluted sulfuric acid and an outlet for sulfuric acid enriched water; b) washing the yarn with water to obtain washed yarn and washing water containing 0.5-20 wt.% sulfuric acid; c) recycling the sulfuric acid enriched water and optionally the washing water to the sulfuric acid recovery unit; d) increasing the sulfuric acid content of the recycled sulfuric acid enriched water, and optionally the washing water, by evaporation to obtain 20 to 98% sulfuric acid and water; e) mixing the 20 to 98% sulfuric acid with oleum to obtain 98-105% sulfuric acid; f) recycling the 98-105% sulfuric acid to the spinning unit for use as sulfuric acid spin dope.

    Method for spinning and washing aramid fiber and recovering sulfuric acid
    5.
    发明公开
    Method for spinning and washing aramid fiber and recovering sulfuric acid 审中-公开
    一种用于纺纱和洗涤芳族聚酰胺纤维以及用于回收硫酸的方法

    公开(公告)号:EP2053147A1

    公开(公告)日:2009-04-29

    申请号:EP07020662.8

    申请日:2007-10-23

    Abstract: The invention pertains to a method for spinning and washing aramid fiber and for recovering sulfuric acid, using a spinning unit and a sulfuric acid recovery unit, comprising the steps:
    a) spinning an aramid polymer from a sulfuric acid spin dope to a yarn and coagulating the yarn in a coagulation bath having an inlet for water or diluted sulfuric acid and an outlet for sulfuric acid enriched water;
    b) washing the yarn with water to obtain washed yarn and washing water containing 0.5-20 wt.% sulfuric acid;
    c) recycling the sulfuric acid enriched water and optionally the washing water to the sulfuric acid recovery unit;
    d) increasing the sulfuric acid content of the recycled sulfuric acid enriched water, and optionally the washing water, by evaporation to obtain 20 to 98% sulfuric acid and water;
    e) mixing the 20 to 98% sulfuric acid with oleum to obtain 98-105% sulfuric acid;
    f) recycling the 98-105% sulfuric acid to the spinning unit for use as sulfuric acid spin dope.

    Abstract translation: 本发明涉及用于纺纱和洗涤芳族聚酰胺纤维的方法以及用于回收硫酸,利用纺丝单元和硫酸回收单元,其包括以下步骤:在芳族聚酰胺聚合物从硫酸纺丝原液A)纺丝的纱线和凝固 纱线在具有入口,用于水或稀释的硫酸,并在出口,用于富集水硫酸凝固浴; b)清洗与水的纱线,得到洗过的纱和洗涤水含有0.5-20重量%的硫酸。 c)中回收硫酸富集的水和任选的洗涤水到硫酸回收单元; D)增加再循环硫酸的硫酸含量富集的水,以及任选的清洗水,通过蒸发,得到20〜98%的硫酸和水; E)混合的20至98%硫酸与发烟硫酸以获得98-105%的硫酸; F)再循环98-105%硫酸至该纺纱单元用作硫酸纺丝浆液。

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