METHOD FOR MANUFACTURING RESIN BEADS, RESIN BEADS, AND PRODUCT EMPLOYING RESIN BEADS

    公开(公告)号:EP3998300A1

    公开(公告)日:2022-05-18

    申请号:EP20837372.0

    申请日:2020-07-07

    发明人: ABE Takashi

    摘要: The present invention provides a method for producing resin beads which can provide various types of products, such as cosmetics, imparted with superior tactile impression, spreadability on the skin, transparency, and product stability, and which can be substituted for resin particles composed of a synthetic material derived from petroleum. The method is a method for producing resin beads containing a cellulose derivative as a main component. The production method includes: a suspension preparation step of mixing an oil phase containing the cellulose derivative and an organic solvent that dissolves the cellulose derivative, the organic solvent having a water-solubility of 0.1 to 50.0 g, and an aqueous phase containing a dispersion stabilizer, thereby preparing a suspension containing oil droplets containing the cellulose derivative and the organic solvent; and an oil droplet contraction step of adding water to the suspension, thereby contracting the oil droplets, wherein the water is added to the suspension in such a way as to satisfy the following expression (A) until a content of the organic solvent in the suspension becomes equal to or less than the water-solubility of the organic solvent. W/S / T ≤ 1 .00 wherein
    W: an addition amount of water (parts by mass),
    S: an amount of the suspension (parts by mass), and
    T: a time (minutes) required for addition.

    COATING OF HYDROXYLATED SURFACES BY GAS PHASE GRAFTING
    4.
    发明公开
    COATING OF HYDROXYLATED SURFACES BY GAS PHASE GRAFTING 有权
    曲面由羟基化GASPHASENPFROPFUNG涂料

    公开(公告)号:EP2379636A2

    公开(公告)日:2011-10-26

    申请号:EP09801147.1

    申请日:2009-12-16

    申请人: Carlsberg A/S

    IPC分类号: C08L1/10 C08B3/08

    摘要: A method of coating hydroxylated surfaces by gas phase grafting is described. Especially acyl groups, silyl groups and/or alkyl groups are located on the surface of materials by gas phase grafting. The grafting method is a dry process. The material to coat can be organic or inorganic materials. The produced surface coated material are strong and durable and material normally not water-proof can be water-proof due to the surface treating. Examples of items produced from surface treated material may be water-proof cardboard boxes, other containers, furniture, interior for cars and boats. Items produced from organic materials such as from plant parts are biodegradable.

    CELLULOSE BASED POLYMER MATERIAL
    5.
    发明公开
    CELLULOSE BASED POLYMER MATERIAL 有权
    聚合物材料,以纤维素

    公开(公告)号:EP2379635A1

    公开(公告)日:2011-10-26

    申请号:EP09801146.3

    申请日:2009-12-16

    申请人: Carlsberg A/S

    IPC分类号: C08L1/10 C08B3/08

    摘要: The invention relates to a polymer material with several advantageous properties. The polymer material has a low degree of swelling in water, it is biodegradable, it has extremely low permeability to gasses such as CO
    2 and it has a high strength. The polymer material is useful for a number of purposes, such as for preparing containers for food or beverages. The polymer material is prepared from a prepolymerisation mixture comprising grafted plant derived material and monomers and/or cross-linkers.

    MODIFIED CELLULOSE FINE FIBERS AND METHOD FOR PRODUCING SAME

    公开(公告)号:EP3369748A1

    公开(公告)日:2018-09-05

    申请号:EP16859929.8

    申请日:2016-10-27

    申请人: KRI, Inc.

    摘要: Modified fine cellulose fibers are produced by impregnating a cellulose with a reactive fibrillation solution or mixture containing a catalyst including a base catalyst or an organic acid catalyst, a monobasic carboxylic anhydride, and an aprotic solvent having a donor number of not less than 26 to esterify and chemically fibrillate the cellulose. This method provides a simple efficient process for producing modified fine cellulose fibers that have a diameter from several nano-meters to submicrometers, a large aspect ratio, a high degree of crystallinity, less damage in the shape or crystalline structure of the fine fibers, a large aspect ratio, and an excellent dispersibility in an organic solvent; The catalyst may contain a pyridine compound. The monobasic carboxylic anhydride may be a C 2-4 aliphatic monocarboxylic anhydride. The resulting modified fine cellulose fibers modified with a monobasic carboxylic anhydride may have a degree of crystallinity of not less than 70%, an average fiber diameter of 20 to 800 nm, and an average fiber length of 1 to 200 µm.

    ACYLATION OF BIOPOLYMER COMPRISING ANHYDROGLUCOSE UNITS
    8.
    发明公开
    ACYLATION OF BIOPOLYMER COMPRISING ANHYDROGLUCOSE UNITS 审中-公开
    包含无水葡萄糖单元的生物聚合物的酰化

    公开(公告)号:EP3184549A1

    公开(公告)日:2017-06-28

    申请号:EP15202027.7

    申请日:2015-12-22

    IPC分类号: C08B3/08 C08B3/10

    CPC分类号: C08B3/08 C08B3/10

    摘要: A process for the preparation of particulate acylated biopolymer comprising anhydroglucose units, said process comprising the steps of
    a. dispersing an amount of particulate non-surface modified biopolymer comprising anhydroglucose units in an amount of a liquid alkenyl carboxylate, or of a mixture of two or more liquid alkenyl carboxylates, in order to form a first dispersion,
    b. adding a catalytic composition to the first dispersion such a to form a second dispersion,
    c. heating the second dispersion to a temperature above ambient temperature
    d. cooling the second dispersion to ambient temperature,
    e. isolating the obtained particulate acylated biopolymer,
    wherein the amount of a liquid alkenyl carboxylate, or a mixture of two or more liquid alkenyl carboxylates, corresponds to a molar excess of alkenyl carboxylate, the molar excess being defined with respect to the moles of anhydroglucose units comprised in the amount of the particulate non-surface modified biopolymer, and wherein the catalytic composition comprises an amount of one, or two or more, non-nucleophilic bases

    摘要翻译: 一种制备包含脱水葡萄糖单元的颗粒酰化生物聚合物的方法,所述方法包括以下步骤:a。 将一定量的包含脱水葡萄糖单元的颗粒状非表面改性的生物聚合物分散在一定量的液体烯基羧酸盐或两种或更多种液体烯基羧酸盐的混合物中以形成第一分散体,b。 向第一分散体中加入催化组合物以形成第二分散体,c。 将第二分散体加热至高于环境温度d的温度。 将第二分散体冷却到环境温度,例如, 分离所获得的颗粒酰化生物聚合物,其中液体烯基羧酸盐或两种或更多种液体烯基羧酸盐的混合物的量对应于摩尔过量的烯基羧酸盐,所述摩尔过量相对于包含的脱水葡萄糖单元的摩尔数 其量为所述颗粒非表面改性的生物聚合物的量,并且其中所述催化组合物包含一定量的一种或两种或更多种非亲核性碱