-
公开(公告)号：JPS6261014B2
公开(公告)日：1987-12-18
申请号：JP5846381
申请日：1981-04-20
发明人： TANABE MASAAKI , MATSURA AKIRA , HIOKI KATSUHIKO
-
公开(公告)号：JPS6148493B2
公开(公告)日：1986-10-24
申请号：JP1052879
申请日：1979-02-02
-
公开(公告)号：JPS6136500B2
公开(公告)日：1986-08-19
申请号：JP12011678
申请日：1978-09-29
申请人： MITSUBISHI CHEM IND
发明人： TAKEDA YOSHUKI
-
公开(公告)号：JPS59172546A
公开(公告)日：1984-09-29
申请号：JP4814383
申请日：1983-03-23
发明人： IMAZEKI SHIYUUJI , KOUBI AKIO , SATOU MIKIO , KANEKO MASAHARU , OZAWA TETSUO , YONEYAMA TOMIO
摘要： NEW MATERIAL:Anthraquinone compounds of formula I wherein R
1 WR
4 are each H, hydroxy, amino; X is S, O; R
5 is trans-4-alkylcyclohexyl, trans-4-alkoxycyclohexyl, trans-4-cyclohexylcyclohexyl; trans-4-alkylcyclohexylcyclohexyl; Y is H, -X-CH
2 -R
6 (wherein R
6 is R
5 ), a group of formula II or III (wherein Z is H, a 1W12C alkyl, a 1W12C alkoxy, dialkylamino, halogen; m is 1W3).
USE: Anthraquinone dyes which are excellent in order parameter, solubility and stability and suitable for use in liquid crystal compsn. for electrooptical element which makes good color display possible.
PREPARATION: A compd. of formula IV is alkylated with a compd. of W-CH
2 -R
2 (wherein W is halogen; R
7 is R
5 ) or a compd. of formula V or VI to obtain the desired compd.
COPYRIGHT: (C)1984,JPO&Japio摘要翻译： 新材料：式Ⅰ的蒽醌化合物，其中R 1 -R 4各自为H，羟基，氨基; X是S，O; R 5是反式-4-烷基环己基，反式-4-烷氧基环己基，反式-4-环己基环己基; 反式-4- alkylcyclohexylcyclohexyl; Y是H，-X-CH 2 -R 6（其中R 6是R 5），式II或III的基团（其中Z是H，1-12C烷基，1-12C烷氧基 ，二烷基氨基，卤素; m为1-3）。 用途：参数，溶解性和稳定性优良，适用于液晶组合物的蒽醌染料。 用于电光元件，使彩色显示成为可能。 准备： 式IV的化合物用化合物烷基化。 的W-CH 2 -R 2（其中W是卤素; R 7是R 5）或其化合物。 的式V或VI，以获得所需的化合物。
-
公开(公告)号：JPS59116245A
公开(公告)日：1984-07-05
申请号：JP22595682
申请日：1982-12-24
IPC分类号： C07C46/04 , B01J23/00 , B01J23/14 , B01J23/18 , B01J31/04 , C07B61/00 , C07C45/00 , C07C50/18 , C07C67/00
CPC分类号： Y02P20/52
摘要： PURPOSE: To prepare anthraquinone useful as an intermediate for synthesizing dye, etc. or an auxiliary for pulp digesting without hardly causing by-products, by oxidizing catalytically an anthracene derivative replaced with an alkyl in a gaseous phase, using a lead compound as a catalyst.
CONSTITUTION: In preparing anthraquinone by oxidizing an anthracene derivative shown by the formula (R is any substituent group of 1W3C alkyl; m and n are 0W4) with molecular oxygen catalytically in a gaseous phase, a lead-containing compound (e.g., metal lead, lead sulfide, lead oxide, lead halide, lead nitrate, lead acetate, etc.) is used as a catalyst. One or more of Na, K, rare earth metals, etc. as a cocatalyst may be added to the lead compound.
COPYRIGHT: (C)1984,JPO&Japio摘要翻译： 目的：使用铅化合物作为催化剂，通过氧化催化氧化被烷基取代的蒽衍生物，使用作为合成染料等的中间体或辅助浆料而不会引起副产物的蒽醌， 。 构成：通过在气相中催化氧化式（R为1-3C烷基的任何取代基，m和n为0-4））的蒽衍生物制备蒽醌，含铅化合物（例如 ，金属铅，硫化铅，氧化铅，卤化铅，硝酸铅，醋酸铅等）用作催化剂。 作为助催化剂的Na，K，稀土金属等中的一种或多种可以添加到铅化合物中。
-
公开(公告)号：JPS5936636A
公开(公告)日：1984-02-28
申请号：JP14624782
申请日：1982-08-25
IPC分类号： C07C50/18 , B01J21/00 , B01J21/02 , B01J23/00 , B01J23/18 , B01J23/22 , B01J27/00 , B01J27/18 , C07B61/00 , C07C45/00 , C07C46/02 , C07C50/26 , C07C67/00
CPC分类号： Y02P20/52
摘要： PURPOSE: To prepare anthraquinone, in high yield, by the catalytic vapor-phase oxidation of 2-methyldiphenylmethane with O
2 in two reaction zones containing two kinds of different catalysts, especially containing a specific compound as the catalyst for the latter reaction zone, and restricting the conversion of the raw material in each reaction zone.
CONSTITUTION: Anthraquinone is prepared by the catalytic vapor-phase oxidation of 2-methyldiphenylmethane with an O
2 -containing gas. In the above process, a catalyst containing a V oxide is placed to the gas-inlet side of the reaction zone, and a catalyst containing at least a compound selected from P, Al, B and Sb and added with a V oxide is placed at the gas-outlet side of the zone. The reaction is carried out by keeping the initial conversion of 2-methyldiphenylmethane to 30W98% (especially 50W98%) and the subsequent conversion to 98W100%. The catalyst in the latter stage is preferably incorporated with an alkali metal and/or Tl to improve the effect.
EFFECT: Stable for a long period.
COPYRIGHT: (C)1984,JPO&Japio摘要翻译： 目的：通过在含有两种不同催化剂的两个反应区中，特别是含有特定化合物作为后一反应区的催化剂，通过催化气相氧化2-甲基二苯基甲烷与O 2在高产率下制备蒽醌，并限制 每个反应区的原料转化率。 构成：通过用含O2气体的2-甲基二苯基甲烷的催化气相氧化制备蒽醌。 在上述方法中，将含有V氧化物的催化剂置于反应区的气体入口侧，并且将至少含有选自P，Al，B和Sb的化合物并加入V氧化物的催化剂置于 该区域的气体出口侧。 通过保持2-甲基二苯基甲烷的初始转化率为30-98％（特别是50-98％），随后转化为98-100％来进行反应。 后期的催化剂优选与碱金属和/或Tl掺入以改善效果。 效果：长期稳定。
-
-
公开(公告)号：JPS58201742A
公开(公告)日：1983-11-24
申请号：JP8315982
申请日：1982-05-19
IPC分类号： C07C46/08 , B01J21/04 , B01J21/06 , B01J23/22 , B01J23/62 , C07B61/00 , C07C45/00 , C07C46/02 , C07C50/18 , C07C67/00
CPC分类号： Y02P20/52
摘要： PURPOSE: To obtain anthraquinone industrially in high selectivity for a long time, by catalytically oxidizing 2-methyldiphenylmethane in the vapor phase with air or a gas containing molecular oxygen in the presence of a catalyst prepared by mixing vanadium oxide with Al
2 O
3 , etc. to give a catalytically active substance.
CONSTITUTION: 2-Methyldiphenylmethane is catalytically oxidized in the vapor phase with air or a gas containing molecular oxygen in the presence of a catalyst, consisting of vanadium oxide and one or more selected from Al
2 O
3 , ZrO
2 and SnO
2 , and prepared by mixing one or more compounds preferably selected from an alkali metal, Tl, P and Sb in an amount of 0.01W10wt% expressed in terms of the oxide having the maximal valence to give a catalytically active substance at 300W500°C and 500W10,000hr
-1 (S.T.P) to afford anthraquinone. The mixing weight ratio of the catalytically active substance is 1W30% vanadium oxide and 20W99% Al
2 O
3 and/or ZrO
2 and/or SnO
2 .
COPYRIGHT: (C)1983,JPO&Japio摘要翻译： 目的：通过在氧化铝与Al2O3等混合制备的催化剂存在下，通过空气或含有分子氧的气体在气相中催化氧化2-甲基二苯基甲烷，以高选择性长时间获得蒽醌，得到 催化活性物质。 构成：在由氧化钒和一种或多种选自Al 2 O 3，ZrO 2和SnO 2组成的催化剂存在下，空气或含有分子氧的气体在气相中催化氧化2-甲基二苯基甲烷，并通过混合一种或多种 优选选自碱金属，Tl，P和Sb的化合物，其量为0.01-10wt％，以具有最大化合价的氧化物表示，以在300-500℃和500-10,000hr下得到催化活性物质， -1>（STP），得到蒽醌。 催化活性物质的混合重量比为1-30％氧化钒和20-99％Al2O3和/或ZrO2和/或SnO2。
-
公开(公告)号：JPS58188834A
公开(公告)日：1983-11-04
申请号：JP6954382
申请日：1982-04-27
IPC分类号： C07C46/02 , B01J21/06 , B01J23/04 , B01J23/22 , B01J27/16 , C07B61/00 , C07C45/00 , C07C50/18 , C07C67/00
CPC分类号： Y02P20/52
摘要： PURPOSE: To prepare the titled compound in high selectivity, by the vapor-phase catalytic oxidation of 2-methyldiphenylmethane using a catalyst obtained by supporting a substance having catalytic activity and containing the oxides of V, Ti, P and Cs at specific ratios on an inert carrier.
CONSTITUTION: The objective anthraquinone is prepared by the vapor-phase catalytic oxidation of 2-methyldiphenylmethane with air or a gas containing molecular oxygen in the presence of a catalyst obtained by supporting a substance having catalytic activity and containing vanadium oxide and titanium oxide at a weight ratio of 1:99W90:10 (in terms of V
2 O
5 :TiO
2 ), and 0.05W10pts.wt. of phosphorus oxide (in terms of P
2 O
5 ) and 0.05W10pts.wt. of cesium oxide (in terms of Cs
2 O) per 100pts.wt. of the sum of vanadium oxide and titanium oxide. The oxidation is carried out at 300W480°C and a space velocity of 500W10,000 Hr
-1 .
COPYRIGHT: (C)1983,JPO&Japio摘要翻译： 目的：为了以高选择性制备标题化合物，通过使用通过将具有催化活性负载的物质以特定比例含有V，Ti，P和Cs的氧化物得到的催化剂，通过2-甲基二苯基甲烷的气相催化氧化 惰性载体。 构成：通过在通过负载具有催化活性的物质并含有氧化钒和氧化钛的重量的存在下存在的催化剂存在下，通过气相催化氧化2-甲基二苯基甲烷与空气或含有分子氧的气体制备目标蒽醌 比例为1:99-90:10（以V2O5：TiO2计）和0.05-10pts.wt。 的氧化磷（以P2O5计）和0.05-10pts.wt。 的氧化铯（以Cs 2 O计）每100pts.wt。 的氧化钒和氧化钛的总和。 氧化在300-480℃进行，空间速度为500-10,000Hr -1。
-
-
-
-
-
-
-
-
-
搜索结果
263 条记录 (耗时 0.013 秒)
