公开(公告)号：US20100187467A1

公开(公告)日：2010-07-29

申请号：US12661999

申请日：2010-03-25

申请人： Masami Ono ,  Shinji Higuchi ,  Hitoshi Ishiduka ,  Shingo Takao ,  Koichiro Dohi ,  Takao Kitagawa

发明人： Masami Ono ,  Shinji Higuchi ,  Hitoshi Ishiduka ,  Shingo Takao ,  Koichiro Dohi ,  Takao Kitagawa

IPC分类号： C09K5/00

CPC分类号： C09K5/063 ,  Y02E60/147

摘要： A heat-storage agent which can store a large quantity of cold heat in the temperature range of 3-5° C., is highly effective in preventing supercooling, and can retain the supercooling-preventing effect even when hydrate solidification/melting is frequently repeated. Also provided are an aqueous solution which enables the formation of a clathrate hydrate serving as a major component of the heat-storage agent, and a process for producing the clathrate hydrate. The aqueous solution contains at least one of tetra-n-butylammonium bromide and tri-n-butyl-n-pentylammonium bromide as a solute and contains tetraisopentylammonium bromide as a supercooling inhibitor, the weight proportion of the tetraisopentylammonium bromide to the tetra-n-butylammonium bromide and/or tri-n-butyl-n-pentylammonium bromide being in a given range. This aqueous solution is cooled to or below a hydrate formation temperature to thereby produce a clathrate hydrate. The heat-storage agent contains this clathrate hydrate as a major component.

摘要翻译： 在3-5℃的温度范围内可以储存大量冷热的储热剂在防止过冷方面是非常有效的，并且即使当经常重复水合物固化/熔融时也能保持过冷却防止效果 。 还提供了能够形成作为蓄热剂的主要成分的笼形水合物的水溶液，以及生成笼形水合物的方法。 该水溶液含有四正丁基溴化铵和三正丁基 - 正戊基溴化铵作为溶质中的至少一种，并含有四异戊基溴化铵作为过冷却抑制剂，四异戊基溴化铵与四正丁基 - 正戊基溴化铵的重量比例， 丁基溴化铵和/或三正丁基 - 正戊基溴化铵在给定范围内。 将该水溶液冷却至或低于水合物形成温度，从而产生笼形水合物。 蓄热剂含有这种笼形水合物作为主要成分。