Electrochemical process to prepare a halogenated carbonyl group-containing compound
    1.
    发明授权
    Electrochemical process to prepare a halogenated carbonyl group-containing compound 有权
    电化学工艺制备含卤代羰基的化合物

    公开(公告)号:US07918987B2

    公开(公告)日:2011-04-05

    申请号:US12300621

    申请日:2007-05-11

    IPC分类号: C25B3/06

    CPC分类号: C25B3/06

    摘要: The present invention provides a process to prepare a halogenated carbonyl group-containing compound by electrochemically reacting the corresponding carbonyl group-containing compound with a hydrogen halide H—X, an organic halide R′—X and/or a halide salt Mn+—Xn− under substantially water-free conditions, wherein X is a chlorine, bromine or iodine atom, R′ is an alkyl or aryl group that may be linear or branched, optionally containing one or more heteroatoms such as oxygen, nitrogen, chloride, bromide, fluoride or iodide of which the halogen atom X can be electrochemically split off, Mn+ is a quaternary ammonium, alkaline earth metal, alkali metal or metal cation, and n is an integer of 1 to 5, depending on the valency of the metal cation Mn+.

    摘要翻译: 本发明提供通过使相应的含羰基化合物与卤化氢H-X,有机卤化物R'-X和/或卤化物盐Mn + -Xn-的化合物电化学反应来制备含卤代羰基化合物的方法, 在基本上无水条件下,其中X是氯,溴或碘原子,R'是可以是直链或支链的烷基或芳基,任选地含有一个或多个杂原子如氧,氮,氯,溴,氟 或其卤素原子X可以电化学分解的碘化物,Mn +是季铵,碱土金属,碱金属或金属阳离子,n是1至5的整数,这取决于金属阳离子Mn +的化合价。

    ELECTROCHEMICAL PROCESS TO PREPARE A HALOGENATED CARBONYL GROUP-CONTAINING COMPOUND
    2.
    发明申请
    ELECTROCHEMICAL PROCESS TO PREPARE A HALOGENATED CARBONYL GROUP-CONTAINING COMPOUND 有权
    电化学工艺制备含有羰基的含碳基团的化合物

    公开(公告)号:US20090107849A1

    公开(公告)日:2009-04-30

    申请号:US12300621

    申请日:2007-05-11

    IPC分类号: C25B3/06

    CPC分类号: C25B3/06

    摘要: The present invention provides a process to prepare a halogenated carbonyl group-containing compound by electrochemically reacting the corresponding carbonyl group-containing compound with a hydrogen halide H—X, an organic halide R′—X and/or a halide salt Mn+—Xn− under substantially water-free conditions, wherein X is a chlorine, bromine or iodine atom, R′ is an alkyl or aryl group that may be linear or branched, optionally containing one or more heteroatoms such as oxygen, nitrogen, chloride, bromide, fluoride or iodide of which the halogen atom X can be electrochemically split off, Mn+ is a quaternary ammonium, alkaline earth metal, alkali metal or metal cation, and n is an integer of 1 to 5, depending on the valency of the metal cation Mn+.

    摘要翻译: 本发明提供了一种通过使相应的含羰基化合物与卤化氢HX,有机卤化物R'-X和/或卤化物盐Mn + -Xn-在实质上相互电化学反应来制备含卤代羰基化合物的方法 无水条件,其中X是氯,溴或碘原子,R'是可以是直链或支链的烷基或芳基,任选地含有一个或多个杂原子如氧,氮,氯,溴,氟或碘 其中卤素原子X可以电化学分解,Mn +是季铵,碱土金属,碱金属或金属阳离子,n是1至5的整数,这取决于金属阳离子Mn +的化合价。