公开(公告)号：US09388107B2

公开(公告)日：2016-07-12

申请号：US14408614

申请日：2013-06-27

Applicant: CAP III B.V.

Inventor： Wilhelmus Rudolf Maria Martens ,  Robert Jan De Korte ,  Iris Verschuren ,  Corinne Daguenet ,  Johan Thomas Tinge ,  Roeland Wilhelmus Theodorus Maria Brands

IPC: C07C45/00 ,  C07C29/00 ,  C07C51/00 ,  C07C29/20 ,  C07C35/08 ,  C07C49/603 ,  C07D223/10

CPC classification number: C07C45/006 ,  C07C29/20 ,  C07C35/08 ,  C07C49/603 ,  C07C51/00 ,  C07C2601/14 ,  C07D223/10 ,  C07C49/403

Abstract: The present invention provides a process for continuously preparing a mixture of cyclohexanone and cyclohexanol comprising, a) hydrogenating phenol with gaseous hydrogen, in the presence of platinum or palladium, in a hydrogenation reactor, to produce a hydrogenation product stream comprising cyclohexanone, cyclohexanol, phenol and hydrogen; b) cooling the hydrogenation product stream to a temperature such that the fraction of phenol by mass in a first gas phase is lower than the fraction of phenol by mass in a first liquid phase; c) separating the first gas phase from the first liquid phase; d) returning at least part of the first gas phase to the hydrogenation reactor; e) heating the first liquid phase; f) purifying the first liquid phase by distillation; characterized in that heat is transferred from the hydrogenation product stream in step b) to another part of the process by means of in-process heat exchange; a mixture of cyclohexanone and cyclohexanol obtained by the process; and a chemical plant suitable for continuously preparing mixture of cyclohexanone and cyclohexanol according to the process.

Abstract translation: 本发明提供一种连续制备环己酮和环己醇的混合物的方法，其包括：a）在氢化反应器中，在铂或钯存在下，用气态氢气氢化苯酚，生成包含环己酮，环己醇，苯酚 和氢; b）将氢化产物流冷却至使第一气相中的质量分数低于第一液相中苯酚质量分数的温度; c）将第一气相与第一液相分离; d）将至少部分第一气相返回到氢化反应器; e）加热第一液相; f）通过蒸馏纯化第一液相; 其特征在于，通过在工艺中的热交换将热量从步骤b）中的氢化产物流转移到另一部分工艺; 通过该方法获得的环己酮和环己醇的混合物; 以及适用于连续制备环己酮和环己醇的混合物的化学植物。

公开(公告)号：US20180290955A1

公开(公告)日：2018-10-11

申请号：US15525448

申请日：2015-11-06

Applicant: CAP III B.V.

Inventor： Johan Thomas Tinge ,  Corinne Daguenet ,  Iris Verschuren ,  Wilhelmus Rudolf Maria Martens ,  Roeland Wilhelmus Theodorus Maria Brands ,  Robert Jan de Korte

IPC: C07C45/00 ,  C07C45/82

CPC classification number: C07C45/006 ,  C07C29/20 ,  C07C29/80 ,  C07C45/002 ,  C07C45/82 ,  C07C2601/14 ,  C07C49/403 ,  C07C35/08

Abstract: An industrial scale continuous process for the production and recovery of cyclohexanone from phenol and hydrogen, said process comprising: hydrogenating phenol in a phenol hydrogenation reactor; separating cyclohexanone from a hydrogenated product stream in a separation and purification section [II] comprising at least 4 distillation sections; wherein at least some of the reaction heat produced in the phenol hydrogenation reaction section [I] is applied for the production of steam; and wherein the molar ratio of cyclohexanone to phenol that is charged to said phenol hydrogenation reactor is from 0.02 to 0.10; and/or wherein the molar ratio of cyclohexanol to phenol that is charged to said phenol hydrogenation reactor is from 0.001 to 0.10.

公开(公告)号：US10301243B2

公开(公告)日：2019-05-28

申请号：US15525448

申请日：2015-11-06

Applicant: CAP III B.V.

Inventor： Johan Thomas Tinge ,  Corinne Daguenet ,  Iris Verschuren ,  Wilhelmus Rudolf Maria Martens ,  Roeland Wilhelmus Theodorus Maria Brands ,  Robert Jan de Korte

IPC: C07C45/82 ,  C07C45/00 ,  C07C29/20 ,  C07C29/80

Abstract: An industrial scale continuous process for the production and recovery of cyclohexanone from phenol and hydrogen, said process comprising: hydrogenating phenol in a phenol hydrogenation reactor; separating cyclohexanone from a hydrogenated product stream in a separation and purification section [II] comprising at least 4 distillation sections; wherein at least some of the reaction heat produced in the phenol hydrogenation reaction section [I] is applied for the production of steam; and wherein the molar ratio of cyclohexanone to phenol that is charged to said phenol hydrogenation reactor is from 0.02 to 0.10; and/or wherein the molar ratio of cyclohexanol to phenol that is charged to said phenol hydrogenation reactor is from 0.001 to 0.10.