Electrolyte additive for lithium-ion battery

    公开(公告)号:US10193186B2

    公开(公告)日:2019-01-29

    申请号:US15037450

    申请日:2014-11-17

    摘要: Electrolyte for a lithium-ion battery comprising at least one block copolymer, characterized in that said block copolymer comprises at least one polymeric segment A which is soluble in said electrolyte and at least one polymeric segment B having a temperature for dissolution “T” in said electrolyte, the polymeric segments A and B being present in amounts sufficient to make possible an increase in the viscosity of the electrolyte, preferably up to gelling of the electrolyte, at a temperature greater than or equal to the temperature “T”; the ionic conduction is produced by a solvent comprising the copolymer and lithium salts.

    SOLID POLYMER ELECTROLYTE
    6.
    发明申请

    公开(公告)号:US20210005928A1

    公开(公告)日:2021-01-07

    申请号:US16919374

    申请日:2020-07-02

    摘要: A method for preparing a film of solid polymer electrolyte, including: (i) providing a composition including, in one or more solvents, at least one (co)polymer of at least one cyclic monomer selected from lactones and cyclic carbonates with five to eight ring members; the (co)polymer or (co)polymers having free terminal hydroxyl functions; at least one crosslinking agent, at least one ionic conductive salt; and optionally, in the case of a crosslinking agent bearing at least one photosensitive reactive function, at least one photoinitiator compound; (ii) forming a dry film from the composition, in conditions unfavourable to crosslinking of the (co)polymer or (co)polymers; and (iii) bringing the film into conditions favourable to crosslinking of the (co)polymer or (co)polymers to form the film of solid polymer electrolyte. Also disclosed is a film of solid polymer electrolyte and use thereof in an electrochemical system, in particular in a lithium battery.