公开(公告)号：US20090311531A1

公开(公告)日：2009-12-17

申请号：US12481823

申请日：2009-06-10

申请人： Kyung Seog Youk ,  Hyun Jin Shin ,  Han Hong Kim

发明人： Kyung Seog Youk ,  Hyun Jin Shin ,  Han Hong Kim

IPC分类号： B32B27/30 ,  C08F14/06 ,  C08F4/34 ,  C08F4/04

CPC分类号： C08K5/42 ,  C08F2/22 ,  C08F2/24 ,  C08F114/06 ,  Y10T428/2982

摘要： The present invention relates to a large-sized vinyl chloride seed with an average particle size of 0.65 to 1.5 μm, a vinyl chloride resin with improved low-viscosity properties, and preparation methods thereof. The preparation of the large-sized vinyl chloride seed includes adding a vinyl chloride monomer, an emulsifier, and a polymerization initiator to an aqueous medium; homogenizing the mixed solution using a rotor-stator type homogenizer; and subjecting the resultant monomer droplets to a polymerization reaction.

摘要翻译： 本发明涉及平均粒径为0.65〜1.5μm的大型氯乙烯种子，具有改善的低粘度特性的氯乙烯树脂及其制备方法。 大型氯乙烯种子的制备包括向水介质中加入氯乙烯单体，乳化剂和聚合引发剂; 使用转子 - 定子式均质器均化混合溶液; 并使得到的单体液滴进行聚合反应。

公开(公告)号：US08691927B2

公开(公告)日：2014-04-08

申请号：US13377466

申请日：2010-06-10

申请人： Hyun Jin Shin ,  Kyung Seog Youk ,  Han Hong Kim

发明人： Hyun Jin Shin ,  Kyung Seog Youk ,  Han Hong Kim

IPC分类号： C08F114/06 ,  C08F2/24

CPC分类号： C08F14/06 ,  C08F259/04 ,  C08F2/18 ,  C08F2/22 ,  C08F214/20

摘要： Provided are a vinyl chloride-based resin formed by polymerization of vinyl chloride-based small seed particles having an average particle diameter range of 0.15 μm to 0.5 μm prepared by emulsion polymerization and vinyl chloride-based large seed particles having an average particle diameter range of 0.51 μm to 0.8 μm prepared by micro-suspension polymerization, in which a content ratio (weight ratio) of the large seed particles to the small seed particles is in a range of 1 to 2, and a method of preparing the vinyl chloride-based resin. Excellent low viscosity characteristics of the vinyl chloride resin at high and low shear rates may be obtained by controlling the particle size of the small seed prepared by emulsion polymerization.

摘要翻译： 本发明提供一种氯乙烯系树脂，其通过聚合具有通过乳液聚合制备的平均粒径范围为0.15μm至0.5μm的氯乙烯基小种子颗粒和平均粒径范围为氯乙烯的大型种子颗粒 通过微悬浮聚合制备的0.51μm〜0.8μm，其中大种子颗粒与小种子颗粒的含量比（重量比）在1至2的范围内，以及制备氯乙烯基 树脂。 通过控制通过乳液聚合制备的小种子的粒度，可以获得高低剪切速率下氯乙烯树脂的优异的低粘度特性。

公开(公告)号：US20120123077A1

公开(公告)日：2012-05-17

申请号：US13377466

申请日：2010-06-10

申请人： Hyun Jin Shin ,  Kyung Seog Youk ,  Han Hong Kim

发明人： Hyun Jin Shin ,  Kyung Seog Youk ,  Han Hong Kim

IPC分类号： C08F114/06 ,  C08F2/24

CPC分类号： C08F14/06 ,  C08F259/04 ,  C08F2/18 ,  C08F2/22 ,  C08F214/20

摘要： Provided are a vinyl chloride-based resin formed by polymerization of vinyl chloride-based small seed particles having an average particle diameter range of 0.15 μm to 0.5 μm prepared by emulsion polymerization and vinyl chloride-based large seed particles having an average particle diameter range of 0.51 μm to 0.8 μm prepared by micro-suspension polymerization, in which a content ratio(weight ratio) of the large seed particles to the small seed particles is in a range of 1 to 2, and a method of preparing the vinyl chloride-based resin. Excellent low viscosity characteristics of the vinyl chloride resin at high and low shear rates may be obtained by controlling the particle size of the small seed prepared by emulsion polymerization.

摘要翻译： 本发明提供一种氯乙烯系树脂，其通过聚合具有通过乳液聚合制备的平均粒径范围为0.15μm至0.5μm的氯乙烯基小种子颗粒和平均粒径范围为氯乙烯的大型种子颗粒 通过微悬浮聚合制备的0.51μm〜0.8μm，其中大种子颗粒与小种子颗粒的含量比（重量比）在1至2的范围内，以及制备氯乙烯基 树脂。 通过控制通过乳液聚合制备的小种子的粒度，可以获得高低剪切速率下氯乙烯树脂的优异的低粘度特性。