公开(公告)号：US20130261351A1

公开(公告)日：2013-10-03

申请号：US13848944

申请日：2013-03-22

Applicant: IFP ENERGIES NOUVELLES

Inventor： Fabrice GIROUDIERE ,  Michel THOMAS ,  Cedric NEBOIS

IPC: C07C29/76

CPC classification number: C07C29/76 ,  C01B3/323 ,  C01B3/38 ,  C01B2203/1229 ,  C01B2203/1247 ,  C01B2203/1258 ,  C01B2203/1604

Abstract: The present invention describes a process for pre-treating a steam reforming feed containing sulphur-containing compounds, using two desulphurization reactors: a temporary desulphurization reactor (1010) containing an active adsorbent solid; a permanent desulphurization reactor (1003) placed upstream of the steam reforming unit, which contains an adsorbent solid in the passivated state, necessitating a depassivation phase in order to be rendered active; the temporary desulphurization reactor (1010) being disconnected as soon as the adsorbent solid of the permanent desulphurization reactor (1003) has been activated, and the volume of the temporary desulphurization reactor being in the range 1/20 to 1/200 times the volume of the permanent desulphurization reactor.

Abstract translation: 本发明描述了一种使用两个脱硫反应器预处理包含含硫化合物的蒸汽重整进料的方法：一种含有活性吸附剂固体的临时脱硫反应器（1010） 永久性脱硫反应器（1003）放置在蒸汽重整单元的上游，其含有处于钝化状态的吸附剂固体，需要去钝化阶段以使其具有活性; 一旦永久性脱硫反应器（1003）的吸附固体被激活，临时脱硫反应器（1010）就断开，临时脱硫反应器的体积在1/10至1/200倍的量的范围内 永久性脱硫反应器。