公开(公告)号：US09166225B2

公开(公告)日：2015-10-20

申请号：US13966497

申请日：2013-08-14

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Hyung Sun Kim ,  Byung Won Cho ,  Si Hyoung Oh ,  Ju Hyeon Ahn ,  Yong Ho Lee ,  Won Chang Choi

IPC: H01M4/485 ,  C01D1/02 ,  H01M4/02 ,  C01G31/02 ,  H01M10/054

CPC classification number: H01M4/485 ,  C01D1/02 ,  C01G31/02 ,  H01M10/054 ,  H01M2004/027 ,  Y02E60/122

Abstract: There is provided a preparation method of a sodium vanadium oxide-based (Na1+xV1−xO2) anode material for a sodium ion secondary battery synthesized by mixing particles of precursors such as sodium carbonate (Na2CO3) and vanadium oxide (V2O3) and pyrolyzing a mixture in a mixed gas atmosphere composed of 90 mol % of nitrogen gas and 10 mol % of hydrogen gas through a solid-state reaction. The sodium vanadium oxide-based anode material prepared according to the present invention shows a small change in volume caused by an initial irreversible capacity and continuous charge/discharge reactions, and thus it is useful for providing a next-generation sodium ion secondary battery having stable charge/discharge characteristics and cycle performance.

Abstract translation: 提供了通过混合前体如碳酸钠（Na 2 CO 3）和氧化钒（V 2 O 3）的颗粒合成的钠离子二次电池的钠钒氧化物（Na1 + xV1-xO2）阳极材料的制备方法，并将 通过固相反应在由90mol％的氮气和10mol％的氢气组成的混合气体气氛中进行混合。 根据本发明制备的基于氧化钒的阳极材料显示由初始不可逆容量和连续充放电反应引起的体积变化小，因此可用于提供具有稳定的下一代钠离子二次电池 充放电特性和循环性能。