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    Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties
    1.
    发明申请
    Ethylene/dicyclopentadiene/norbornene terpolymer materials having desirable structural and thermal properties 审中-公开
    乙烯/二环戊二烯/降冰片烯三元共聚物材料具有理想的结构和热性能

    公开(公告)号：US20080221275A1

    公开(公告)日：2008-09-11

    申请号：US12074213

    申请日：2008-02-29

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Abhimanyu O. Patil ,  Beverly J. Poole ,  Kevin D. Robinson ,  Kevin R. Squire

    IPC分类号： C08F4/76 ,  C08F36/00 ,  C08F36/04 ,  C08F4/80

    CPC分类号： C08C19/06 ,  C08F8/04 ,  C08F8/08 ,  C08F210/02

    摘要： Provided are selected types of terpolymer components comprising terpolymers having monomer units derived from ethylene (E), dicyclopentadiene (DCPD) and norbornene-based (NB) co-monomers. Such terpolymer components have certain specified amounts of each co-monomer as well as certain specified molecular weight and glass transition temperature characteristics. Terpolymer components which are derivatized by hydrogenation and/or by epoxidation and/or hydroxylation are also disclosed, as well as thermoplastic polyolefin compositions which contain the terpolymer components and which have especially desirable structural and thermal properties.Also provided are processes for preparing and derivatizing the terpolymer components herein. Such preparation processes comprise: a) contacting ethylene with a polymerization mixture comprising selected amounts of both DCPD and NB co-monomers, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst under specific polymerization conditions to thereby form the desired ethylene-dicyclopentadiene-norbornene terpolymer components within the polymerization mixture. These terpolymer components can then be subsequently derivatized by hydrogenation or functionalization of the residual double bonds therein.

    摘要翻译： 提供了包含来自乙烯（E），二环戊二烯（DCPD）和降冰片烯基（NB））共聚单体的单体单元的三元共聚物的选择类型的三元共聚物组分。 这些三元共聚物组分具有特定量的每种共聚单体以及某些特定的分子量和玻璃化转变温度特性。 还公开了通过氢化和/或通过环氧化和/或羟基化衍生化的三元共聚物组分，以及含有三元共聚物组分并且具有特别期望的结构和热性质的热塑性聚烯烃组合物。 还提供了用于制备和衍生本文中三元共聚物组分的方法。 这样的制备方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在特定的聚合条件下，使乙烯与包含选定量的DCPD和NB共聚单体的聚合混合物接触，从而形成所需的乙烯 - 二环戊二烯 - 降冰片烯三元共聚物组分在聚合混合物内。 然后可以通过氢化或官能化其中的残余双键将这些三元共聚物组分衍生化。

    Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof
    3.
    发明申请
    Ethylene/dicyclopentadiene copolymers and functionalized derivatives thereof 有权
    乙烯/二环戊二烯共聚物及其官能化衍生物

    公开(公告)号：US20080015314A1

    公开(公告)日：2008-01-17

    申请号：US11801633

    申请日：2007-05-10

    申请人： Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

    发明人： Lisa Saunders Baugh ,  Abhimanyu Onkar Patil ,  Christian Peter Mehnert ,  Kevin R. Squire ,  Kenneth A. Cook ,  Caiguo Gong ,  Enock Berluche ,  Karla Schall Colle ,  Alan J. Oshinski ,  Stephen Zushma ,  Beverly J. Poole

    IPC分类号： C08L45/00

    CPC分类号： C08F210/02 ,  C08F8/04 ,  C08F8/08 ,  C08F232/00

    摘要： Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)≧[(mole % DCPD×3.142)−4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicylopentadiene copolymers. Such copolymers can be readily derivatized by hydrogention and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Also disclosed are processes for preparing and optionally further derivatizing ethylene/dicyclopentadiene copolymers having the characteristics hereinbefore described. Such processes comprise: a) contacting ethylene with a polymerization mixture comprising greater than about 4.0 molar dicyclopentadiene, in the presence of a selected activated cyclopentadienyl-fluorenyl metallocene catalyst bearing a substituent, preferably a methyl substituent, at the 3-position of the cyclopentadienyl ring, under specific polymerization conditions including relatively high ethylene pressures to thereby form the desired ethylene-dicyclopentadiene copolymers within the polymerization mixture. Such copolymers are then recovered and/or further hydrogenated or functionalized.

    摘要翻译： 公开了一种选择类型的共聚物组合物，其包含具有衍生自乙烯和二环戊二烯（DCPD）共聚单体的单元的共聚物。 这种共聚物组合物：a）具有约25摩尔％至约45摩尔％的DCPD衍生的共聚单体单元含量; b）具有大于约170,000的重均分子量，M < c）包含非晶材料，并且具有约8℃至约129℃的玻璃化转变温度，其也适合方程式T（g） （℃）] = [（摩尔％DCPDx 3.142）-4.67]; 和d）在乙烯 - 二茂二烯共聚物内不含有显着量的结晶聚乙烯均聚物或可结晶的聚乙烯链段。 这样的共聚物可以通过水合和/或环氧化来容易地衍生，以提供适合用作工程热塑性塑料的聚合材料。 还公开了制备和任选地进一步衍生具有上述特征的乙烯/二环戊二烯共聚物的方法。 这样的方法包括：a）在选择的活化的环戊二烯基 - 芴基茂金属催化剂存在下，在含有大于约4.0摩尔二环戊二烯的聚合混合物的存在下，使乙烯与环戊二烯基环的3位具有取代基，优选甲基取代基接触 在包括相对较高的乙烯压力的特定聚合条件下，从而在聚合混合物内形成所需的乙烯 - 二环戊二烯共聚物。 然后回收和/或进一步氢化或官能化此类共聚物。

    Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers
    6.
    发明申请
    Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers 审中-公开
    包含环烯烃共聚物和聚烯烃改性剂的聚合物组合物

    公开(公告)号：US20080033112A1

    公开(公告)日：2008-02-07

    申请号：US11820739

    申请日：2007-06-20

    申请人： Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

    发明人： Kevin R. Squire ,  Alan J. Oshinski ,  Kevin D. Robinson ,  Christian Peter Mehnert ,  Marsha M. Arvedson ,  Beverly J. Poole ,  Abhimanyu Onkar Patil ,  Lisa Saunders Baugh ,  Karla Schall Colle

    IPC分类号： C08L23/00

    CPC分类号： C08L23/0823 ,  C08L23/16 ,  C08L53/00 ,  C08L2314/06 ,  C08L2666/24 ,  C08L2666/06

    摘要： A polymer composition comprises (a) greater than 50 wt % (based upon the weight of the composition) of a cyclic olefin copolymer comprising at least one acyclic olefin and at least 20 weight % of one or more cyclic olefins (based upon the weight of the cyclic olefin copolymer), wherein at least a portion of the cyclic olefin copolymer has a glass transition temperature of greater than 150° C.; and (b) less than 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier, at least a portion of the modifier having a glass transition temperature of less than −30° C.; and no portion of the modifier having a softening point greater than +30° C., wherein the Bicerano solubility parameter of the modifier being no more than 0.6 J0.5/cm1.5 less than the Bicerano solubility parameter of the cyclic olefin copolymer. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 500 J/m and a heat distortion temperature measured using a 0.46 MPa load of greater than 135° C.

    摘要翻译： 聚合物组合物包含（a）大于50重量％（基于组合物的重量）的包含至少一种非环烯烃和至少20重量％的一种或多种环烯烃的环烯烃共聚物（基于 环烯烃共聚物），其中至少一部分环烯烃共聚物的玻璃化转变温度大于150℃; 和（b）小于50重量％（基于组合物的重量）非环烯烃聚合物改性剂，至少一部分改性剂的玻璃化转变温度低于-30℃; 并且所述改性剂的任何部分的软化点大于+ 30℃，其中所述改性剂的二辛醇溶解度参数不大于0.6J / 小于环烯烃共聚物的Bicerano溶解度参数。 该聚合物组合物在23℃下测得的切口悬臂梁式冲击强度大于500J / m，并且使用大于135℃的0.46MPa载荷测量的热变形温度。

    Heterogeneous in-reactor polymer blends
    8.
    发明授权
    Heterogeneous in-reactor polymer blends 有权
    不均匀的反应器内聚合物共混物

    公开(公告)号：US08106127B2

    公开(公告)日：2012-01-31

    申请号：US12638861

    申请日：2009-12-15

    申请人： Carlos U. De Gracia ,  Kevin R. Squire ,  Peijun Jiang ,  Armenag H. Dekmezian ,  Beverly J. Poole ,  Cesar A. Garcia-Franco

    发明人： Carlos U. De Gracia ,  Kevin R. Squire ,  Peijun Jiang ,  Armenag H. Dekmezian ,  Beverly J. Poole ,  Cesar A. Garcia-Franco

    IPC分类号： C08F8/00 ,  C08L23/04 ,  C08L23/10 ,  C08K5/00

    CPC分类号： C08L23/16 ,  C08L23/12 ,  C08L2314/06 ,  C08L2666/06

    摘要： An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than −0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C. such that the difference between the first and second melting temperatures is at least 20° C.

    摘要翻译： 反应器内聚合物共混物包含（a）含丙烯的第一聚合物; 和（b）含乙烯的第二聚合物，使得聚合物共混物包含衍生自乙烯的约50重量％至约80重量％的单元和衍生自丙烯的约50重量％至约20重量％的单元。 共混物基本上不含二烯，乙烯 - 乙烯 - 乙烯三单元组形式的第二聚合物中的乙烯含量至少为40％。 第二聚合物含有至少0.1个分支，每10,000个碳原子具有8个或更多个碳原子。 此外，共混物的应变硬化指数为至少1.8，对数（动态粘度）对log（频率）的曲线图中的剪切变稀斜率小于-0.2，并且当进行差示扫描量热法时显示出至少两个峰 （第一熔体），其对应于至少150℃的第一熔点和至少40℃的第二熔点，使得第一和第二熔融温度之间的差异为至少20℃。

    Heterogeneous In-Reactor Polymer Blends
    9.
    发明申请
    Heterogeneous In-Reactor Polymer Blends 有权
    非均相反应器聚合物共混物

    公开(公告)号：US20100152390A1

    公开(公告)日：2010-06-17

    申请号：US12638861

    申请日：2009-12-15

    申请人： Carlos U. De Gracia ,  Kevin R. Squire ,  Peijun Jiang ,  Armenag H. Dekmezian ,  Beverly J. Poole ,  Cesar A. Garcia-Franco

    发明人： Carlos U. De Gracia ,  Kevin R. Squire ,  Peijun Jiang ,  Armenag H. Dekmezian ,  Beverly J. Poole ,  Cesar A. Garcia-Franco

    IPC分类号： C08L23/06

    CPC分类号： C08L23/16 ,  C08L23/12 ,  C08L2314/06 ,  C08L2666/06

    摘要： An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than −0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C. such that the difference between the first and second melting temperatures is at least 20° C.

    摘要翻译： 反应器内聚合物共混物包含（a）含丙烯的第一聚合物; 和（b）含乙烯的第二聚合物，使得聚合物共混物包含衍生自乙烯的约50重量％至约80重量％的单元和衍生自丙烯的约50重量％至约20重量％的单元。 共混物基本上不含二烯，乙烯 - 乙烯 - 乙烯三单元组形式的第二聚合物中的乙烯含量至少为40％。 第二聚合物含有至少0.1个分支，每10,000个碳原子具有8个或更多个碳原子。 此外，共混物的应变硬化指数为至少1.8，对数（动态粘度）对log（频率）的曲线图中的剪切变稀斜率小于-0.2，并且当进行差示扫描量热法时显示出至少两个峰 （第一熔体），其对应于至少150℃的第一熔点和至少40℃的第二熔点，使得第一和第二熔融温度之间的差异为至少20℃。