-
公开(公告)号:US20130023403A1
公开(公告)日:2013-01-24
申请号:US13412308
申请日:2012-03-05
申请人: Randy W. Larsen , Carissa M. Vetromile , Jason A. Perman , Lukasz Wojtas , Michael J. Zaworotko , Mohamed Eddaoudi , Yunling Liu
发明人: Randy W. Larsen , Carissa M. Vetromile , Jason A. Perman , Lukasz Wojtas , Michael J. Zaworotko , Mohamed Eddaoudi , Yunling Liu
IPC分类号: B01J31/22
CPC分类号: C07F19/005 , B01J31/1691 , B01J2531/025 , C07F1/08 , C07F13/005 , C07F15/025
摘要: A supramolecular assembly comprising a metal-organic molecular framework and a heterocyclic macrocycle guest molecule. The metal-organic molecular framework comprises cubicuboctahedral cavities, octahemioctahedral cavities and trigonal cavities in a 1:1:2 ratio, respectively, and the heterocyclic macrocycle guest molecule is hosted by the octahemioctahedral cavity. In a preferred embodiment, the heterocyclic macrocycle guest molecule is a heme.
摘要翻译: 包含金属 - 有机分子骨架和杂环大环客体分子的超分子组装。 金属有机分子骨架分别以1:1:2比例的立方八面体腔,八面体腔和三角腔,并且杂环大环客体分子由八面体腔承载。 在优选的实施方案中,杂环大环客体分子是血红素。