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1.发明授权
公开(公告)号：US3953383A
公开(公告)日：1976-04-27
申请号：US523160
申请日：1974-11-12
CPC分类号： C08G64/0208 , C08G64/34
摘要： A catalyst composition and a process for preparing same comprising the reaction product of (a) an organo-metallic compound having the general formula R'nM, wherein n is an integer, at least one R' is an alkyl group, an alicyclic group, or halogen, hydroxy or alkoxy derivatives thereof, or hydrogen, the remaining R' groups are alkyl groups, alicyclic groups, alkaryl groups, aralkyl groups, aryl groups, or halogen, hydroxy or alkoxy derivatives thereof, and M is a metal of Group II or Group III of the periodic Table, (b) a co-catalyst component which is sulfur or a compound containing active hydrogen atoms, and (c) carbon dioxide. The catalyst composition is used in preparing copolymers of epoxy compounds with carbon dioxide.
摘要翻译： 一种催化剂组合物及其制备方法，包括（a）具有通式R'nM的有机金属化合物的反应产物，其中n为整数，至少一个R'为烷基，脂环基， 或卤素，其羟基或烷氧基衍生物或氢，其余的R'基团是烷基，脂环基，烷芳基，芳烷基，芳基或卤素，其羟基或烷氧基衍生物，M是第II族金属 或周期表的III族，（b）作为硫或含有活性氢原子的化合物的助催化剂组分，和（c）二氧化碳。 催化剂组合物用于制备环氧化合物与二氧化碳的共聚物。
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公开(公告)号：US4166898A
公开(公告)日：1979-09-04
申请号：US740918
申请日：1976-11-11
CPC分类号： C08G64/34
摘要： A copolymer having carbonate linkages is produced by copolymerizing an epoxy compound with carbon dioxide in the presence of an isoprene-magnesium complex compound or a reaction mixture of said complex compound with an active hydrogen compound as a catalyst. The catalyst has a much improved polymerization activity when treated with carbon dioxide in advance.
摘要翻译： 通过在异戊二烯 - 镁络合物或所述络合物与活性氢化合物作为催化剂的反应混合物的存在下，使环氧化合物与二氧化碳共聚来制备具有碳酸酯键的共聚物。 催化剂预先用二氧化碳处理时具有大大改善的聚合活性。
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