公开(公告)号：US20130053240A1

公开(公告)日：2013-02-28

申请号：US13635782

申请日：2011-03-28

申请人： Nobuko Takahama ,  Takao Masuda ,  Yoshimi Ikezawa ,  Takahito Ochiai ,  Shinichiro Matsumoto ,  Yohei Uesugi

发明人： Nobuko Takahama ,  Takao Masuda ,  Yoshimi Ikezawa ,  Takahito Ochiai ,  Shinichiro Matsumoto ,  Yohei Uesugi

IPC分类号： B41M5/26 ,  B05D3/02 ,  B05D3/12 ,  B29C51/02

CPC分类号： B41M5/42 ,  B41M5/323 ,  B41M5/327 ,  B41M5/3275 ,  B41M5/3335 ,  B41M5/3336 ,  B41M5/3338 ,  B41M5/3375 ,  B41M2205/04 ,  B41M2205/38

摘要： Provided is a thermal recording material comprising an intermediate layer and a heat-sensitive recording layer for color formation by heat stacked in this order onto a support, the thermal recording material being characterized in that the intermediate layer contains a bellows-shaped hollow resin and that the roughness of the surface on the color forming side is 1.0 μm or less as measured by Parker Print Surf. The method for producing such a thermal recording material comprises the steps of: applying a coating liquid containing heat-expandable resin particles to a support, drying the coated support at a temperature lower than the expansion starting temperature of the heat-expandable resin particle, and subjecting the coated support to thermoforming for formation of an intermediate layer; and applying, to the intermediate layer, heat-sensitive recording-related components which contribute to color formation by heat, for formation of a heat-sensitive recording layer.

摘要翻译： 提供了一种热敏记录材料，其包括中间层和用于通过热量依次堆叠在支撑体上的用于着色的热敏记录层，该热敏记录材料的特征在于，中间层包含波纹管形中空树脂，并且 通过Parker Print Surf测量，成色侧的表面粗糙度为1.0μm以下。 制造这种热敏记录材料的方法包括以下步骤：将含有热膨胀性树脂颗粒的涂布液施加到载体上，在低于热膨胀性树脂颗粒的膨胀起始温度的温度下干燥涂覆的载体，以及 使涂覆的载体经受热成型以形成中间层; 以及向所述中间层施加有助于通过加热形成颜色的热敏记录相关组分，以形成热敏记录层。

公开(公告)号：US20060266696A1

公开(公告)日：2006-11-30

申请号：US11289763

申请日：2005-11-29

申请人： Takao Masuda ,  Teruoki Tago ,  Shuichi Yoshida ,  Toshihiro Tomita ,  Kenji Suzuki

发明人： Takao Masuda ,  Teruoki Tago ,  Shuichi Yoshida ,  Toshihiro Tomita ,  Kenji Suzuki

IPC分类号： B01D71/04

CPC分类号： B01D71/04 ,  B01D67/0051 ,  B01D69/02 ,  B01D69/12 ,  B01D2325/04 ,  B01D2325/30 ,  B01D2325/36

摘要： The present invention provides an inorganic separation membrane including a silicalite nanocrystalline layer formed on a porous ceramic substrate, and a porous inorganic protective layer is formed on the nanocrystalline layer. The crystal grain diameter of the silicalite nanocrystal is preferably 150 nm or less, and the thickness of the silicalite nanocrystalline layer is preferably 1.0 to 4.0 μm. The separation membrane may be manufactured by: immersing a porous ceramic substrate in a dispersion solution of silicalite nanocrystals; laminating the silicalite nanocrystals on the surface of the porous ceramic substrate by evacuating the insider of the porous ceramic substrate; forming a porous inorganic protective layer on the silicalite nanocrystalline layer by a hydrothermal synthesis by heating after immersing the porous substrate in a zeolite synthesis solution containing a silica source; and removing organic components in the silicalite nanocrystal by liquid phase oxidation.

摘要翻译： 本发明提供一种无机分离膜，其包括在多孔陶瓷基板上形成的硅沸石纳米晶层，在纳米晶层上形成多孔无机保护层。 硅沸石纳米晶体的晶粒直径优选为150nm以下，并且硅沸石纳米晶层的厚度优选为1.0〜4.0μm。 分离膜可以通过以下步骤制造：将多孔陶瓷基材浸渍在硅沸石纳米晶体的分散溶液中; 通过抽真空多孔陶瓷基板的内部，在多孔陶瓷基板的表面层叠硅沸石纳米晶体; 在将多孔基材浸入含有二氧化硅源的沸石合成溶液中之后通过加热通过水热合成在硅沸石纳米晶层上形成多孔无机保护层; 并通过液相氧化除去硅沸石纳米晶体中的有机成分。

公开(公告)号：US4267267A

公开(公告)日：1981-05-12

申请号：US81237

申请日：1979-10-02

申请人： Shinpei Ikenoue ,  Takao Masuda

发明人： Shinpei Ikenoue ,  Takao Masuda

IPC分类号： G03C1/498 ,  G03C1/79 ,  G03C1/02

CPC分类号： G03C1/498 ,  G03C1/49872 ,  G03C1/79 ,  Y10S430/162

摘要： A thermally developable light-sensitive element comprising a support having in one or more layers thereon at least (a0) an organic silver salt, (b) light-sensitive silver halide grains and (c) a reducing agent, wherein the average grain size of the light-sensitive silver halide grains is not less than about 0.05 .mu. and the support is gas permeable and, in addition, carries thereon a subbing layer composed of at least one copolymer selected from the group consisting of a vinyl chloride type copolymer in which vinyl chloride is present in the copolymer in an amount of about 50 molar % or higher and a vinylidene chloride type copolymer in which vinylidine chloride is present in the copolymer in an amount of about 50 molar % or higher. The thermally-developable light-sensitive element of the invention is highly sensitive and in addition, has a good storage stability retaining on storage the properties possessed by the "fresh" photosensitive element even under high humidity and/or high temperature conditions.

摘要翻译： 一种可热显影的感光元件，其包含至少（a0）有机银盐，（b）感光卤化银颗粒和（c）还原剂的至少一层或多层的载体，其中平均晶粒尺寸 感光卤化银颗粒不小于约0.05μm，并且载体是透气性的，并且还承载有由至少一种共聚物组成的底层，所述共聚物选自氯乙烯型共聚物，其中乙烯基 氯化物以约50摩尔％以上的量存在于共聚物中，其中偏二氯乙烯型共聚物中共聚物中存在氯乙烯约50摩尔％以上。 本发明的热显影光敏元件是高灵敏度的，此外，即使在高湿度和/或高温条件下，也具有良好的储存稳定性，保持了“新鲜”感光元件所具有的性能。

公开(公告)号：US4258129A

公开(公告)日：1981-03-24

申请号：US711741

申请日：1976-08-04

申请人： Shinpei Ikenoue ,  Yoshiaki Suzuki ,  Takao Masuda

发明人： Shinpei Ikenoue ,  Yoshiaki Suzuki ,  Takao Masuda

IPC分类号： G03C1/498 ,  G03C5/50 ,  G03C1/02

CPC分类号： G03C1/49845 ,  G03C5/50

摘要： A thermally developable light sensitive material which comprises: (a) an organic silver salt; (b) a photocatalyst and (c) a reducing agent in a support or in one or more layers provided on the support additionally comprises (d) at least one cerium compound selected from trivalent and/or tetravalent cerium compounds in the support and/or in one or more of the above layers. An improvement in various characteristics such as a long green shelf life, a high degree of whiteness, low thermal fog, high sensitivity and so on is obtained.

摘要翻译： 一种可热显影的感光材料，其包括：（a）有机银盐; （b）光催化剂和（c）在载体上或在一个或多个层上提供的载体上的还原剂，还包含（d）至少一种选自三价和/或四价铈化合物的铈化合物在载体和/或 在一个或多个上述层中。 获得了绿色保质期长，白度高，低雾化，高灵敏度等各种特性的改善。

公开(公告)号：US4213784A

公开(公告)日：1980-07-22

申请号：US921541

申请日：1978-07-03

申请人： Shinpei Ikenoue ,  Takao Masuda

发明人： Shinpei Ikenoue ,  Takao Masuda

IPC分类号： G03C1/498 ,  G03C1/02 ,  C07F1/10 ,  C11C1/10

CPC分类号： G03C1/49845

摘要： In a process for producing thermally developable light-sensitive composition which comprises heating a composition containing (a) an organic silver salt and (b) a light-sensitive silver halide, the improvement wherein the heating is conducted in the presence of (c) a sulfur-containing compound.

摘要翻译： 在制备可热显影的感光组合物的方法中，其包括加热含有（a）有机银盐和（b）感光卤化银的组合物，其改进在于（c）a 含硫化合物。

公开(公告)号：US4140532A

公开(公告)日：1979-02-20

申请号：US860652

申请日：1977-12-14

申请人： Hideo Sato ,  Nobuyoshi Sekikawa ,  Toshinao Ukai ,  Takao Masuda

发明人： Hideo Sato ,  Nobuyoshi Sekikawa ,  Toshinao Ukai ,  Takao Masuda

IPC分类号： G03C1/06 ,  G03C1/498 ,  G03C1/02

CPC分类号： G03C1/49845 ,  Y10S430/166

摘要： A thermally developable light-sensitive material comprising a support and containing at least (a) an organic silver salt, (b) a photocatalyst, (c) a reducing agent and (d) a color toning agent in the support or in at least one layer provided on the support, wherein the color toning agent is at least one 2H-1,3-benzothiazin-2,4(3H)-dione, e.g., having the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, a hydroxy group, an acyloxy group, a nitro group, an amino group, an alkyl-substituted amino group, an aryl-substituted amino group, an acylamino group, an acyl group, a hydroxycarbonyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a sulfamoyl group, an alkyl-substituted sulfamoyl group, an aryl-substituted sulfamoyl group, an alkylsulfonyl group, an arylsulfonyl group or a sulfo group, further, R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, and/or R.sub.3 and R.sub.4, may combine and represent the atoms necessary to form a condensed aromatic ring; and, further, one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be a monovalent residue of the general formula (I), in which the color toning effect is retained even under conditions of high temperature and/or high humidity.

摘要翻译： 一种可热显影的感光材料，其包括载体并且至少包含（a）有机银盐，（b）光催化剂，（c）还原剂和（d）载体中的至少一种颜色调色剂 层，其中色调剂是至少一种2H-1,3-苯并噻嗪-2,4（3H） - 二酮，例如具有以下通式（I）：其中 R 1，R 2，R 3和R 4可以相同或不同，表示氢原子，卤素原子，烷基，环烷基，芳基，烷氧基，芳氧基，烷硫基， 羟基，酰氧基，硝基，氨基，烷基取代的氨基，芳基取代的氨基，酰氨基，酰基，羟基羰基，烷氧基羰基，芳氧基羰基， 氨磺酰基，烷基取代的氨磺酰基，芳基取代的氨磺酰基，烷基磺酰基，芳基磺酰基 p或磺基，此外，R 1和R 2，R 2和R 3和/或R 3和R 4可以组合并表示形成稠合芳环所必需的原子; 此外，R 1，R 2，R 3和R 4中的一个可以是通式（I）的一价残基，即使在高温和/或高湿度的条件下也保持着色调色效果。

公开(公告)号：US4125403A

公开(公告)日：1978-11-14

申请号：US810656

申请日：1977-06-27

申请人： Shinpei Ikenoue ,  Harumi Katsuyama ,  Takao Masuda

发明人： Shinpei Ikenoue ,  Harumi Katsuyama ,  Takao Masuda

IPC分类号： G03C1/498 ,  G03C1/02 ,  G03C1/28 ,  G03C1/34

CPC分类号： G03C1/49845

摘要： A heat developable light sensitive material which comprises a support having therein or in one or more layers thereon (a) an organic silver salt, (b) a light sensitive silver halide or a component capable of producing a light sensitive silver halide and (c) a reducing agent and additionally contains (d) at least one phthalazinone and (e) at least one compound selected from benzoxazinediones and quinazolinediones in a molar ratio of the amount of the component (e) to that of the component (d) smaller than about 1:1 (i.e. molar ratio (e)/(d) 1) in at least one of the layers containing components (a) to (c), in a specific layer additionally provided on the support other than the layers containing components (a) to (c), or in the support to result in the production of images of a pure black tone and in improvements in shelf-life under high humidity and the developing speed.

摘要翻译： 一种可热显影的感光材料，其包括其中或其中一层或多层的支撑体（a）有机银盐，（b）感光卤化银或能够产生感光卤化银的组分，和（c） 还原剂，另外含有（d）至少一种2,3-二氮杂萘酮和（e）至少一种选自苯并恶嗪二酮和喹唑啉二酮的化合物，其组分（e）与组分（d）的量的摩尔比小于约 在包含组分（a）至（c）的至少一层中的1（1）摩尔比（即摩尔比（e）/（d）1）），在除了含有组分的层 ）到（c），或支持，以产生纯黑色调的图像，并改善高湿度和显影速度下的保质期。

公开(公告)号：US4120728A

公开(公告)日：1978-10-17

申请号：US680417

申请日：1976-04-26

申请人： Shinpei Ikenoue ,  Takao Masuda

发明人： Shinpei Ikenoue ,  Takao Masuda

IPC分类号： G03C1/498 ,  G03C1/02 ,  G03C1/38

CPC分类号： G03C1/498

摘要： A thermally developable light-sensitive material comprising a support having thereon at least one layer containing (a) an organic silver salt; (b) a catalytic amount of a light-sensitive silver halide prepared by mixing a solution of a compound capable of releasing a halide ion and a solution of a compound capable of releasing silver ion in the presence of a surface active agent; (c) a reducing agent and (d) a binder.

摘要翻译： 一种可热显影的感光材料，其包括其上具有至少一层的载体，所述层包含（a）有机银盐; （b）在表面活性剂的存在下，通过混合能够释放卤离子的化合物的溶液和能够释放银离子的化合物的溶液而制备的催化量的感光卤化银; （c）还原剂和（d）粘合剂。

公开(公告)号：US4009039A

公开(公告)日：1977-02-22

申请号：US605700

申请日：1975-08-18

申请人： Takao Masuda ,  Nobuyoshi Sekikawa

发明人： Takao Masuda ,  Nobuyoshi Sekikawa

IPC分类号： G03C1/498 ,  G03C1/02 ,  G03C1/34

CPC分类号： G03C1/49845

摘要： A heat developable light-sensitive element having reduced thermal fogging and improved light stability comprising a support having therein or in one or more layers thereon (a) an organic silver salt, (b) a light-sensitive silver halide or a compound capable of forming a light-sensitive silver halide upon reaction with the organic silver salt, (c) a reducing agent, and (d) an oxazolinone compound.

摘要翻译： 具有降低的热雾化和改善的光稳定性的可热显影的光敏元件包括其中具有一个或多个层的支撑体（a）有机银盐，（b）感光卤化银或能够形成的化合物 与有机银盐反应的感光卤化银，（c）还原剂和（d）恶唑啉酮化合物。

公开(公告)号：US08524633B2

公开(公告)日：2013-09-03

申请号：US11791622

申请日：2005-06-22

申请人： Takao Masuda

发明人： Takao Masuda

IPC分类号： B41M5/26

CPC分类号： B41M3/144 ,  B41M5/366 ,  B42D25/29 ,  B42D25/387 ,  Y10T428/24835 ,  Y10T428/24893 ,  Y10T428/249971 ,  Y10T428/249975

摘要： The invention relates to a novel security feature in the form of a luminescent marking for integration in a recording material. The security feature comprises a radiation layer (21) with luminescent components and a masking layer (2) with cavity pigments at least partly masking the radiation layer. The pigments in the masking layer (2) are fused by locally defined heal treatment into the form of a marking. The invention particularly relates to a heat-sensitive recording material comprising, in a preferred embodiment, at least one substrate (10), a heat-sensitive recording layer (30), an intermediate layer (21), between the substrate and the heat-sensitive recording layer in the form of a radiation layer with luminescent components and a masking layer with cavity pigments (2), the pigments of the masking layer (2) being fused in the form of a marking by locally defined fusion.

摘要翻译： 本发明涉及一种用于集成在记录材料中的发光标记形式的新型安全特征。 安全特征包括具有发光部件的辐射层（21）和具有至少部分地遮蔽辐射层的空腔颜料的掩模层（2）。 掩蔽层（2）中的颜料通过局部限定的愈合处理融合成标记的形式。 本发明特别涉及一种热敏记录材料，在一个优选的实施方式中，包括至少一个基底（10），热敏记录层（30），中间层（21） 具有发光成分的辐射层形式的敏感记录层和具有空腔颜料（2）的掩蔽层，掩模层（2）的颜料通过局部限定的熔合被熔合成标记的形式。