Metal complexes
    4.
    发明申请
    Metal complexes 审中-公开
    金属配合物

    公开(公告)号:US20060276651A1

    公开(公告)日:2006-12-07

    申请号:US10553776

    申请日:2004-05-05

    摘要: The present invention relates to metal complexes of formula I, compositions comprising the metal complexes, to recording media comprising the metal complexes or compositions and to the use of the compositions in the production of optical recording media: wherein the substituent are, as defined in the description. Use of the metal complexes formula (I) in combination with oxonol dyes results, surprisingly, in a comparatively weak tendency of the oxonol dyes to aggregate in the solid state so that the absorption curve remains advantageously narrow event in the solid state, as a result of which recording media having high reflectivity as well as high sensitivity and good playback characteristics in the desired spectral range are made available.

    摘要翻译: 本发明涉及式I的金属络合物,包含金属络合物的组合物,包含金属络合物或组合物的记录介质以及组合物在制备光学记录介质中的用途:其中取代基如 描述。 使用金属络合物配方(I)与氧杂菁染料组合令人惊讶地导致氧固醇染料在固体状态下聚集的相对较弱的趋势,使得吸收曲线在固体状态下仍然有利地是狭窄的事件,结果 其中具有高反射率的记录介质以及在所需光谱范围内的高灵敏度和良好的回放特性是可用的。

    Writable high-capacity optical storage media containing metal complexes
    5.
    发明申请
    Writable high-capacity optical storage media containing metal complexes 审中-公开
    包含金属络合物的可写入大容量光存储介质

    公开(公告)号:US20050008974A1

    公开(公告)日:2005-01-13

    申请号:US10495678

    申请日:2002-11-07

    CPC分类号: C07D487/22 G11B7/248

    摘要: The invention relates to an optical recording medium comprising a substrate and a recording layer, wherein the recording layer comprises a complex of formula (I), or wherein Q2 is a ligand of formula (II), or a tautomer thereof, and R1, R2, R3, R4, R5, R6, R7, and R8 are each dependently of the others H, halogen, cyano, COOR9, CONHR9, CONR9R10, R9, OR9, SR9, NHR9 or NR9R10, wherein R9 and R10 are each independently of the other C6-C10aryl, C4-C9heteroaryl or linear or branched C1-C24alkyl, C3-C24cycloallyl, C2-C24alkenyl, C3-C24cycloalkenyl, C2-C24alkynyl, C1-C12heterocycloalkyl, C1-C12heterocycloalkenyl, unsubstituted or substituted, it also being possible for R1 and R2, R3 and R4, R5 and R6, and R7 and R8, independently of one another, to be bonded by a direct bond or via a bridge O or S, Mm+ is a transition metal cation having 5 or 6 electrons in the outermost occupied d-shell, L1 is a ligand having a sub-structure N—C, P—C or As—C, L2, independently of L1, is a further ligand containing at least one hetero atom N, P, As, O, S, Se or Te, L3− is CN−, SCN−, NCS−, OCN−, NCO−, N3—, L1-O−, L1-S—, L1-CO2−, L1-S03− or L1-P03−, L4−, independently of L3−, is CN−, SCN−, NCS−, OCN−, NCO−, N3−, L3-O−, L3-S−, L3-CO2− L3-SO3− or L3-PO3−, p and q are each independently of the other a number 0 or 1 (formula III), are each a counter-ion, m is a number 1, 2, 3 or 4 equal to the positive charge in Mm+ and n is a number −2, −1, +1 or +2, so that the quotient (formula IV) is not negative. Amorphous solid layers having excellent optical properties are obtained.

    摘要翻译: 本发明涉及一种包括基材和记录层的光学记录介质,其中记录层包含式(I)的配合物,或其中Q 2是式(II)的配体或其互变异构体,和 R1,R2,R3,R4,R5,R6,R7和R8各自独立地为H,卤素,氰基,COOR9,CONHR9,CONR9R10,R9,OR9,SR9,NHR9或NR9R10,其中R9和R10各自 独立于其它C 6 -C 10芳基,C 4 -C 9杂芳基或直链或支链C 1 -C 24烷基,C 3 -C 24环烯基,C 2 -C 24烯基,C 3 -C 24环烯基,C 2 -C 24炔基,C 1 -C 12杂环烷基,未取代或取代的C 1 -C 12杂环烯基, R 1和R 2,R 3和R 4,R 5和R 6以及R 7和R 8彼此独立地可以通过直接键合或通过桥O或S键合,M m是具有5个碳原子的过渡金属阳离子 或6个电子,L1是具有子结构NC,PC或As-C,L2的配体,独立于L1,是另一个配体c 保持至少一个杂原子N,P,As,O,S,Se或Te,L3 - 是CN - ,SCN - ,NCS - ,OCN - ,NCO - , - N3-,L1-O - ,L1-S-,L

    High-performance optical storage media
    10.
    发明申请
    High-performance optical storage media 审中-公开
    高性能光存储介质

    公开(公告)号:US20050238840A1

    公开(公告)日:2005-10-27

    申请号:US10514923

    申请日:2003-04-15

    摘要: The invention relates to an optical recording medium comprising a substrate, a reflecting layer and a recording layer, wherein the recording layer comprises a compound of formula: (Formula I), (Formula II) or (Formula III); wherein R, to R, may be hydrogen or a variety of substituents, but R1 and R9 are not simultaneously hydrogen; Ym-— is an inorganic, organic or organometallic anion, or a mixture thereof; Zn+ is a proton or a metal, ammonium or phosphonium cation, or a mixture thereof; m, n and o are each independently of the others an integer from 1 to 3; and p and q are each a number from 0 to 4, the ratio of o, p and q to one another, depending on the charge of the associated sub-structures, being such that there is no excess positive or negative charge in formula (I), (II) or (III). Also claimed are the use of a xanthene perchlorate in the preparation of compounds of formula (I), (II) or (III) having organometallic anions, and the use of lactates in the application of layers of dye of compounds of formula (I), (II) or (III) to grooved substrates by spin-coating.

    摘要翻译: 本发明涉及一种包括基底,反射层和记录层的光学记录介质,其中记录层包含式(I)化合物,(式II)或(式III)化合物。 其中R 1至R 3可以是氢或各种取代基,但R 1和R 9不同时为氢; 是无机,有机或有机金属阴离子或其混合物; Z + N +是质子或金属,铵或鏻阳离子或其混合物; m,n和o各自独立地为1〜3的整数; 并且p和q各自为0至4的数,根据相关子结构的电荷,o,p和q彼此的比例使得在式(1)中不存在过量的正电荷或负电荷 I),(II)或(III)。 还要求保护的是高氯酸呫吨酯在制备具有有机金属阴离子的式(I),(II)或(III)的化合物中的用途,以及在施用式(I)化合物的染料层时使用乳酸盐, ,(II)或(III))通过旋涂进行开槽基板。