公开(公告)号：US4877908A

公开(公告)日：1989-10-31

申请号：US107919

申请日：1987-10-13

申请人： Michele Petit ,  Andre Mortreux ,  Francis Petit ,  Gerard Buono

发明人： Michele Petit ,  Andre Mortreux ,  Francis Petit ,  Gerard Buono

IPC分类号： B01J31/18 ,  B01J31/00 ,  B01J31/24 ,  C07B31/00 ,  C07B53/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/32 ,  C07C2/42 ,  C07C2/46 ,  C07C2/52 ,  C07C11/02 ,  C07C13/20 ,  C07C29/136 ,  C07C29/88 ,  C07C33/22 ,  C07C45/49 ,  C07C45/50 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C231/20 ,  C07C233/47 ,  C07F7/18 ,  C07F9/46 ,  C07F9/50 ,  C07F9/53 ,  C07F9/572 ,  C07F15/00

CPC分类号： C07F15/0073 ,  C07C2/465 ,  C07C2/52 ,  C07C45/505 ,  C07F7/188 ,  C07F9/46 ,  C07F9/572 ,  C07C2101/16 ,  C07C2531/22

摘要： Chiral phosphorus-containing ligands comprising at least one amine radical and at least one dihydrocarbylphosphinoxy radical of the formula W=OP (R).sub.2, in which R is a hydrocarbon radical selected from the group consisting of alkyl, aryl, and cycloalkyl radicals, wherein the ligand is selected from the group consisting of:those of the formula ##STR1## those of the formula ##STR2## those of the formula ##STR3## those of the formula ##STR4## in which formulae: R.sub.1 and R.sub.2 are selected from the group consisting of a hydrogen atom and hydrocarbon radicals;R.sub.3 and R.sub.4, which must be different from one another, are selected from the group consisting of a hydrogen atom and hydrocarbon radicals that may or may not carry at least one functional group selected from the group consisting of the alcohol, thiol, thioether, amine, imine, acid, ester, amide, and ether functional groups; andR.sub.5 and R.sub.6 are selected from the group consisting of hydrogen atoms and hydrocarbon radicals that may or may not contain functional groups.A process for their manufacture comprises reacting an optically active amino alcohol, in a hydrocarbon solvent at a temperature between -50.degree. and 80.degree. C. and under an inert gas atmosphere, with at least one compound of the formula P(R).sub.2 Y in which Y is chosen from among the halogen atoms and amine radicals, the compound being present in a molar ratio, relative to the amino alcohol, greater than or equal to the number of P(R).sub.2 groups to be introduced into the chiral molecule.The chiral phosphorous-containing ligands are used by reacting at least one organic compound that does not possess a center of asymmetry with (A), on the one hand, at least one transition metal complex of formula MZq in which M is a metal in group VIII of the Periodic Classification, q is the coordination number of the metal M, and Z is an atom or molecule capable of complexing the metal M and (B), on the other hand, at least one ligand L.

公开(公告)号：US4593140A

公开(公告)日：1986-06-03

申请号：US732544

申请日：1985-05-10

申请人： Andre Mortreux ,  Francis Petit ,  Philippe Denis ,  Gerard Buono ,  Gilbert Peiffer

发明人： Andre Mortreux ,  Francis Petit ,  Philippe Denis ,  Gerard Buono ,  Gilbert Peiffer

IPC分类号： C07C2/40 ,  C07C2/46 ,  C07C2/52 ,  C07C2/02

CPC分类号： C07C2/52 ,  C07C2/403 ,  C07C2/406 ,  C07C2/465 ,  C07C2531/22 ,  C07C2531/24

摘要： The process according to the invention consists in dimerizing a conjugated diene in the presence of a catalyst obtained by bringing together (A) at least one nickel complex of formula NiZ.sub.q in which q is the coordination number of the nickel and Z is at least one ligand capable of complexing nickel and (B) at least one phosphorus-containing ligand of general formula ##STR1## in which: R.sub.1 is chosen from a hydrogen atom and hydrocarbon radicals,R.sub.2 and R.sub.3, which may be identical or different, are chosen from a hydrogen atom and hydrocarbon radicals optionally bearing at least one group chosen from alcohol, thiol, thioether, amine, imine, acid, ester, amide and ether groups, andm is greater than or equal to 1.

摘要翻译： 根据本发明的方法包括在通过将（A）至少一种式NiZq的镍络合物（其中q为镍的配位数，Z为至少一个配体）的催化剂存在下将共轭二烯二聚化 能够络合镍和（B）至少一种通式为“IMAGE”的含磷配体，其中：R 1选自氢原子和烃基，R 2和R 3可以相同或不同，选自 氢原子和烃基任选具有至少一个选自醇，硫醇，硫醚，胺，亚胺，酸，酯，酰胺和醚基团的基团，m大于或等于1。

公开(公告)号：US4145358A

公开(公告)日：1979-03-20

申请号：US858595

申请日：1977-12-08

申请人： Darryl R. Fahey ,  Mahan, John E

发明人： Darryl R. Fahey ,  Mahan, John E

IPC分类号： C07C2/36 ,  C07C2/46 ,  C07F9/02 ,  C07F15/04

CPC分类号： C07F9/02 ,  C07C2/36 ,  C07C2/465 ,  C07F15/045 ,  C07C2531/24

摘要： The preparation and use of bis(.mu.-diphenylphosphido)tris(triethylphosphine)dinickel and tris(triethylphosphine)(triphenylphosphine)nickel is disclosed.

公开(公告)号：US4120907A

公开(公告)日：1978-10-17

申请号：US858598

申请日：1977-12-08

申请人： Darryl R. Fahey ,  John E. Mahan

发明人： Darryl R. Fahey ,  John E. Mahan

IPC分类号： C07C2/36 ,  C07C2/46 ,  C07F9/02 ,  C07F15/04 ,  C07C13/26 ,  C07C13/27

CPC分类号： C07F9/02 ,  C07C2/36 ,  C07C2/465 ,  C07F15/045 ,  C07C2531/24

摘要： The preparation and use of bis(.mu.-diphenylphosphido)tris(triethylphosphine)dinickel and tris(triethylphosphine)(triphenylphosphine)nickel is disclosed.

摘要翻译： 公开了双（μ-二苯基膦基）三（三乙基膦）二锡和三（三乙基膦）（三苯基膦）镍的制备和使用。

公开(公告)号：US4111972A

公开(公告)日：1978-09-05

申请号：US858600

申请日：1977-12-08

申请人： Darryl R. Fahey ,  John E. Mahan

发明人： Darryl R. Fahey ,  John E. Mahan

IPC分类号： C07C2/36 ,  C07C2/46 ,  C07F9/02 ,  C07F15/04

CPC分类号： C07F9/02 ,  C07C2/36 ,  C07C2/465 ,  C07F15/045 ,  C07C2531/24

摘要： The preparation and use of bis(.mu.-diphenylphosphido)tris(triethylphosphine)dinickel and tris(triethylphosphine)(triphenylphosphine)nickel is disclosed.

公开(公告)号：US3848015A

公开(公告)日：1974-11-12

申请号：US37352573

申请日：1973-06-25

申请人： MULLER E ,  WILKE G

发明人： WILKE G ,  MULLER E

IPC分类号： B01J31/14 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  C07C2/46 ,  C07C2/52 ,  C07C11/21 ,  C07F15/04 ,  C07C11/00

CPC分类号： C07F15/04 ,  B01J31/143 ,  B01J31/1805 ,  B01J31/185 ,  B01J31/1895 ,  B01J31/22 ,  B01J31/2404 ,  B01J2531/847 ,  C07C2/465 ,  C07C2/52 ,  C07C11/21 ,  C07C2531/02 ,  C07C2531/12 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  Y10S585/906 ,  C07C13/20

摘要： 1. 5-METHYL-HEPTARI-1,3,6-ENE.

公开(公告)号：US3723553A

公开(公告)日：1973-03-27

申请号：US3723553D

申请日：1971-12-27

申请人： GOODRICH CO B F

发明人： WU C ,  SWIFT H

IPC分类号： C07C2/46 ,  C07C3/10

CPC分类号： C07C2/465 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2601/20 ,  C07C13/277

摘要： Butadiene is cyclotrimerized to 1,5,9-cyclododecatriene in the presence of a catalyst consisting of a trialkyl aluminum, nickel (II) acetylacetonate, and a Schiff base prepared by the condensation of the aldehyde or ketone of a heterocyclic compound with an aniline or toluidine compound.

摘要翻译： 在由三烷基铝，乙酰丙酮镍（II）和通过杂环化合物的醛或酮与苯胺缩合制备的席夫碱的催化剂存在下，将丁二烯环化至1,5,9-环十二碳三烯，或 甲苯胺化合物。

公开(公告)号：US3676474A

公开(公告)日：1972-07-11

申请号：US3676474D

申请日：1969-11-24

申请人： DOW CHEMICAL CO

发明人： TSAI JAMES H ,  ANDERSON GLENN H

IPC分类号： C07C2/46 ,  C07F7/00 ,  C07F7/30 ,  C07F15/06 ,  C07F7/24

CPC分类号： C07F15/06 ,  C07C2/465 ,  C07F7/00 ,  C07F7/30 ,  C07C13/64

摘要： Multinuclear cobalt carbonyl pi -Complexes having metal-cobalt bonds and which are useful as catalysts for the dimerization of norbornadiene are represented by the general formula: Z4 mMCom(CO)4m 2nYn WHEREIN M is a Group 4a metal, Z is a halo, nitrato, alkyl, aryl or similar ligand, Y is a pi -bonded diolefin ligand, m is 2, 3, or 4, and n is 1, 2, 3, or 4, but not greater than m.

摘要翻译： 具有金属钴键的金属钴键复合物可用作降冰片二烯二聚体的催化剂，由通式表示：Z4-mMCom（CO）4m-2nYn WHEREIN M为第4a族金属，Z为卤素 ，硝基，烷基，芳基或类似的配体，Y是π键二烯属配体，m为2,3或4，n为1,2,3或4，但不大于m。

公开(公告)号：US3658926A

公开(公告)日：1972-04-25

申请号：US3658926D

申请日：1970-12-14

申请人： MITSUBISHI PETROCHEMICAL CO

发明人： MORIKAWA HIROYUKI

IPC分类号： C07C2/46 ,  C07C13/277 ,  C07C3/00

CPC分类号： C07C13/277 ,  C07C2/465 ,  C07C2527/135 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2531/24 ,  C07C2601/20

摘要： BUTADIENE-1,3 AND A SPECIFIC CHAIN DIMER THEREOF ARE CAUSED TO UNDERGO CYCLIC COTRIMERIZATION IN CONTACT WITH A ZIEGLER CATALYST COMPRISING, IN COMBINATION, A SPECIFIC TITANIUM COMPOUND (E.G., TITANIUM TETRABUTOXIDE), A SPECIFIC ELECTRON-DONOR COMPOUND (E.G., TRIPHENYL PHOSPHINE) AND A SPECIFIC ORGANIC ALUMINUM COMPOUND (E.G., DIETHYLALUMMINUM). ALTERNATIVELY, BUTADIENE IS CAUSED TO CONTACT A CATALYST COMPRISING, IN COMBINATION, A COBALT OR IRON COMPOUND, A CHROMIUM OR NICKEL COMPOUND, AND A TRIALKYLALUMINUM. BY THIS PROCESS, NEW COMPOUNDS 3-(1-METHYL-2-PROPENYL)-CYCLODODECATRIENE, 3 - (3-BUTENYL)-CYCLODODECATRIENE, AND 3-(1-METHYL-2-PROPENYL)-CYCLOOCTADIENE ARE PRODUCED.

公开(公告)号：US3644548A

公开(公告)日：1972-02-22

申请号：US3644548D

申请日：1970-03-17

申请人： ASAHI CHEMICAL IND

发明人： TAKAHASI HIROSI ,  TANABE MASANORI ,  YAMAGUCHI MUNEAKI ,  SHIIHARA ISAO

IPC分类号： B01J31/00 ,  B01J31/02 ,  B01J31/14 ,  C07B61/00 ,  C07C1/00 ,  C07C2/46 ,  C07C13/277 ,  C07C67/00 ,  C08F4/64 ,  C07C3/10

CPC分类号： B01J31/143 ,  B01J31/0212 ,  B01J31/0214 ,  B01J31/14 ,  B01J2231/328 ,  C07C2/465 ,  C07C2531/02 ,  C07C2531/14 ,  C07C2601/20 ,  C07C13/277

摘要： PROCESS FOR PREPARING CYCLODODECATRIENE-1,5.9 WHICH COMPRISING TRIMERIZING BUTADIENE-1,3 BY THE USE OF A TERNARY CATALYST CONSISTING OF A TITANIUM COMPOUND REPRESENTED BY THE GENERAL FORMULA

WHEREIN X IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF CHLORINE, BROMINE AND IODINE ATOM, R IS A MEMBER SELECTED FROM THE GROUP CONSISTING OF HYDROGEN ATOM AND ALKYL RADICAL CONTAINING FROM 1 TO 5 CARBON ATOMS. AR IS ARYL RADICAL AND N IS 0 OR AN INTEGER FROM 1 TO 3, AN ORGANIC ALUMINUM HALIDE AND A MEMBER SELECTED FROM THE GROUP CONSISTING OF ACID AMIDES, SULFOXIDES, AMINOXIDES AND NITRONS.
RIXN(OCH2R)4-N OR TIXN(OAR)F-N