Oxidation of organic compounds having benzylic carbon atoms in water
    9.
    发明授权
    Oxidation of organic compounds having benzylic carbon atoms in water 失效
    在水中氧化具有苄基碳原子的有机化合物

    公开(公告)号:US5171880A

    公开(公告)日:1992-12-15

    申请号:US669719

    申请日:1991-03-15

    IPC分类号: C07C45/28 C07C51/305

    CPC分类号: C07C51/305 C07C45/28

    摘要: The present invention is directed to a process of oxidizing organic compounds having benzylic carbon atoms. The process of this invention comprises reacting an organic compound having one or more benzylic carbon atoms with an effective amount of an effective oxidizing agent in water at a temperature equal to or greater than about 350.degree. C. and at a pressure equal to or greater than about 175 atmospheres, wherein said agent is selected from the group consisting of a combination of one or more bases and one or more of elemental sulfur, an oxidized form of elemental sulfur and/or an organic or inorganic sulfur containing compounds capable of forming elemental sulfur, said oxidized forms or a combination thereof in situ under process conditions, and organic or inorganic compounds which form one or more bases and elemental sulfur, oxidized forms of sulfur or a combination thereof in situ under process conditions.

    摘要翻译: 本发明涉及氧化具有苄基碳原子的有机化合物的方法。 本发明的方法包括使具有一个或多个苄基碳原子的有机化合物与有效量的有效氧化剂在水中等于或大于约350℃的温度和等于或大于 约175个大气压,其中所述试剂选自一种或多种碱和一种或多种元素硫,氧化形式的元素硫和/或能够形成元素硫的有机或无机含硫化合物的组合 ,在工艺条件下原位地表示氧化形式或其组合,以及在工艺条件下原位形成一种或多种碱和元素硫,氧化形式的硫或其组合的有机或无机化合物。