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148 条记录 (耗时 0.041 秒)

    Anthraquinone-azo dyes
    92.
    发明授权
    Anthraquinone-azo dyes 失效
    蒽醌偶氮染料

    公开(公告)号：US07030229B2

    公开(公告)日：2006-04-18

    申请号：US10516440

    申请日：2003-05-27

    申请人： Athanassios Tzikas ,  Antoine Clément ,  Urs Lauk

    发明人： Athanassios Tzikas ,  Antoine Clément ,  Urs Lauk

    IPC分类号： C09B56/12 ,  G02B5/20 ,  C08K5/23

    CPC分类号： C09B35/031 ,  C09B29/0022 ,  C09B35/039 ,  C09B69/106

    摘要： The present invention relates to an azo dye of formula I, II or III: (formula I, II or III); wherein R1 and R2 are each independently of the other one or more divalent groups selected from alkylene, arylene, aralkylene and cycloalkylene, which may be interrupted by —O—, —S—, —NH—, —NR8—, —COO—, —CONH— or —CONR9—, wherein R8 and R9 are alkyl or aryl, X is —O— or —NH—, R3 is —CN or —CONH2, R4 is methyl or trifluoromethyl and R5, R6, R7 and R8 are each independently of the others hydrogen, halogen or —CN, to a process for the preparation thereof and to the use thereof in a method of producing mass-colored plastics or polymeric color particles.

    摘要翻译： 本发明涉及式I，II或III的偶氮染料：（式I，II或III）; 其中R 1和R 2各自独立地选自亚烷基，亚芳基，亚芳基和亚环烷基的另一个或多个二价基团，其可以被-O-， -S - ， - NH - ， - NR 8 - ， - COO - ， - CONH-或-CONR 9 - ，其中R 8 - R 9是烷基或芳基，X是-O-或-NH-，R 3是-CN或-CONH 2，R R 4是甲基或三氟甲基，R 5，R 6，R 7和R 8， 其各自独立地为氢，卤素或-CN，其制备方法及其在制备大量着色的塑料或聚合物着色颗粒的方法中的用途。

    Pyridone dyes, a process for their preparation and their use in the production of colored plastics or polymeric color particles
    93.
    发明授权
    Pyridone dyes, a process for their preparation and their use in the production of colored plastics or polymeric color particles 有权
    吡啶酮染料，其制备方法及其在生产有色塑料或聚合物着色颗粒中的应用

    公开(公告)号：US06953846B2

    公开(公告)日：2005-10-11

    申请号：US10469889

    申请日：2002-02-28

    申请人： Athanassios Tzikas ,  Urs Lauk ,  Romeo Dreier ,  Antoine Clément

    发明人： Athanassios Tzikas ,  Urs Lauk ,  Romeo Dreier ,  Antoine Clément

    IPC分类号： C07D213/77 ,  C07D213/85 ,  C08K5/3432 ,  C08L101/00 ,  C09B29/42 ,  C09B33/12 ,  C09B35/031 ,  D06P3/00

    CPC分类号： C07D213/77 ,  C07D213/85 ,  C09B29/363 ,  C09B33/12

    摘要： The present invention relates to pyrifone azo dyes of formula (1), wherein A is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzoisothiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphttholic acid imide, chromone, phthalimide or diphenylene oxide series, R1 is hydrogen, unsubstituted or hydroxyl- or phenyl-substituted C1-C6alkyl, it being possible for the alkyl chain to be interrupted from C3 upwards by one or more oxygen atoms, or has the meanings of R2, R2 is a radical of formulae (2), (3), (4), (5), (6), or (7), wherein B is a bridging member, R4 is alkyl or aryl, R5 and R6 are each independently of the other alkyl, aryl or heteroaryl and A is as defined for formula (1), or R1 and R2 toghether with the nitrogen atom in NR1R2 form a heterocyclic ring, Y is cyano, —CONH2 or CH2SO3H, and n is an integer from 2 to 6, to a process for their preparation and to their use in the production coloured plastics or polymeric color particles.

    摘要翻译： 本发明涉及式（1）的焦磷酸偶氮染料，其中A是苯，萘，二苯基，偶氮苯，噻吩，苯并噻唑，苯并异噻唑，噻二唑，吲唑，苯并三唑，吡唑，蒽醌，萘的重氮组分的基团 酰亚胺，色酮，邻苯二甲酰亚胺或二苯醚系列，R 1是氢，未取代或羟基或苯基取代的C 1 -C 6 - 烷基，可以使烷基链从C 3上向上被一个或多个氧原子中断，或具有R 2，R 2的含义 式（2），（3），（4），（5），（6）或（7）的基团，其中B是桥连构件，R 4 是烷基或芳基，R 5和R 6各自独立地为其它烷基，芳基或杂芳基，A如式（1）所定义，或R

    Method for printing cellulosic fiber materials without an additional fixing process step
    95.
    发明授权
    Method for printing cellulosic fiber materials without an additional fixing process step 失效
    无需附加固定工艺步骤的纤维素纤维材料的印刷方法

    公开(公告)号：US06623533B2

    公开(公告)日：2003-09-23

    申请号：US09899439

    申请日：2001-07-05

    申请人： Athanassios Tzikas ,  Hans Reichert ,  Herbert Klier

    发明人： Athanassios Tzikas ,  Hans Reichert ,  Herbert Klier

    IPC分类号： D06P138

    CPC分类号： D06P1/382 ,  C09B62/4401 ,  D06P1/38 ,  D06P3/66 ,  D06P3/663 ,  Y10S8/918

    摘要： A method of printing cellulosic fiber materials in which the fiber material is brought into contact with reactive dyes of formula: wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, R1, R2 and R3 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, X1 and X2 are halogen, B is an organic bridging member, T is a reactive radical of formula: R4 is hydrogen, C1-C4alkyl unsubstituted or substituted by hydroxy, sulfo, sulfato, carboxy or by cyano, or a radical  wherein R5 is as defined hereinbelow, R5 is hydrogen, hydroxy, sulfo, sulfato, carboxy, cyano, halogen, C1-C4alkoxycarbonyl, C1-C4alkanoyloxy, carbamoyl or a group —SO2—Y, R6 is hydrogen or C1-C4alkyl, alk and alk1 are each independently of the other linear or branched C1-C6alkylene, arylene is an unsubstituted or sulfo-, carboxy-, hydroxy-, C1-C4alkyl-, C1-C4alkoxy- or halo-substituted phenylene or naphthylene radical, Y is vinyl or a radical —CH2—CH2—U and U is a leaving group, Y1 is a group —CH(Hal)-CH2(Hal) or —C(Hal)═CH2, wherein Hal is chlorine or bromine, W is a group —SO2—NR6—, —CONR6— or —NR6CO—, wherein R6 is as defined hereinabove, Q is a radical —O— or —NR6—, wherein R6 is as defined hereinabove, n is the number 0 or 1, and V1 and V2 are each independently of the other N, C—H, C—Cl or C—F, and the fixing of the printed fiber material is carried out without an additional fixing process step. The prints obtained are distinguished by brilliant colour shades and good allround properties.

    摘要翻译： 一种印刷纤维素纤维材料的方法，其中纤维材料与下式的活性染料接触：其中A是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团的基团，R1，R2和R3 各自独立地为氢或未取代的或取代的C 1 -C 4烷基，X 1和X 2为卤素，B为有机桥连构件，T为下式的反应性基团：R 4为氢，未被取代或被羟基取代的C 1 -C 4烷基，磺基 羧基，氰基，卤素，C 1 -C 4烷氧基羰基，C 1 -C 4烷酰氧基，氨基甲酰基或-SO 2 -Y基，其中R 5为氢，羟基，磺基， R 6是氢或C 1 -C 4烷基，alk和alk 1各自独立地为其它直链或支链C 1 -C 6亚烷基，亚芳基是未取代的或磺基，羧基，羟基，C 1 -C 4烷基 - ，C 1 -C 4烷氧基或卤素 - 取代的亚苯基或亚萘基，Y是乙烯基 基团-CH 2 -CH 2 -U和U是离去基团，Y 1是基团-CH（Hal）-CH 2（Hal）或-C（Hal）= CH 2，其中Hal是氯或溴，W是基团 - SO 2 -NR 6 - ， - CONR 6 - 或-NR 6 CO-，其中R 6如上所定义，Q为-O-或-NR 6 - 基团，其中R 6如上所定义，n为数字0或1，V 1和V 2 各自独立于另一个N，CH，C-Cl或CF，并且印刷的纤维材料的固定在没有额外的定影处理步骤的情况下进行。所获得的印刷品通过明亮的色调和良好的全面性质来区分。

    Reactive colorants, mixtures of reactive colorants and production and use thereof
    96.
    发明授权
    Reactive colorants, mixtures of reactive colorants and production and use thereof 失效
    反应性着色剂，反应性着色剂的混合物及其生产和用途

    公开(公告)号：US06537332B1

    公开(公告)日：2003-03-25

    申请号：US09744487

    申请日：2001-01-24

    申请人： Athanassios Tzikas ,  Herbert Klier

    发明人： Athanassios Tzikas ,  Herbert Klier

    IPC分类号： C09B62475

    CPC分类号： C09B62/513 ,  C09B62/09 ,  C09B62/4415 ,  C09B62/453 ,  C09B62/475 ,  Y10S8/918 ,  Y10S8/924

    摘要： Dyes of formula (1) wherein R1 and R2 are each independently of the other hydrogen or C1-C4alkyl, and D1 and D2 are each independently of the other a radical of formula (2)  wherein (R3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy, nitro and sulfo, and X1 is a radical of formula (3a), (3b), (3c), (3d), (3e) or (3f) —SO2—Z  (3a), —NH—CO—(CH2)m—SO2—Z  (3b), —CONH—(CH2)n—SO2—Z  (3c), —NH—CO—CH(Hal)-CH2-Hal  (3d), —NH—CO—C(Hal)=CH2  (3e) or  wherein Y is halogen, T independently thereof has a meaning given for Y or is a non-fiber-reactive substituent or is a fiber-reactive radical of formula (4a), (4b), (4c), (4d) or (4e) —NH—(CH2)2-3—SO2—Z  (4a), —NH—(CH2)2-3—O—(CH2)2-3—SO2—Z  (4b),  wherein Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Z′ is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing a wide variety of fiber materials, especially cellulosic fiber materials, and yield dyeings having good allround properties.

    摘要翻译： 式（1）的染料其中R 1和R 2各自独立地为氢或C 1 -C 4烷基，D 1和D 2各自独立地为式（2）的基团，其中（R3）0-3表示0-3相同 或选自卤素，C 1 -C 4烷基，C 1 -C 4烷氧基，羧基，硝基和磺基的不同取代基，X 1为式（3a），（3b），（3c），（3d），（3e）或（ 3f）或其中Y是卤素，T独立地具有对Y给出的含义或者是非纤维反应性取代基，或者是式（4a），（4b），（4c），（4d）或 （4e）其中Z是乙烯基或基团-CH 2 -CH 2 -U，U是在碱性条件下可除去的基团，Z'是基团-CH（Hal）-CH 2 - Hal或-C（Hal）= CH 2，m和 n各自独立于另一个数字2,3或4，并且Hal是卤素，适用于染色各种纤维材料，特别是纤维素纤维材料，并且产生具有良好全面性能的染色。

    Reactive dyes, processes for their preparation and their use
    97.
    发明授权
    Reactive dyes, processes for their preparation and their use 失效
    活性染料，其制备方法及其用途

    公开(公告)号：US06323327B1

    公开(公告)日：2001-11-27

    申请号：US09704354

    申请日：2000-11-02

    申请人： Athanassios Tzikas ,  Rolf Deitz ,  Herbert Klier

    发明人： Athanassios Tzikas ,  Rolf Deitz ,  Herbert Klier

    IPC分类号： C09B62513

    CPC分类号： C09B62/513 ,  C09B62/4415 ,  Y10S8/918

    摘要： Reactive dyes of formula (1) wherein b is the number 1 or 2, A is the radical of formula (2) or (3) D1 is a radical off formula  or the radical of an azo dye when b is the number 1 or the radical of an aromatic tetraazo component when b is the number 2, D2 is the radical of a diazo component, of the benzene or naphthalene series, R1 and R2 are each independently of the other hydrogen or C1-C4alkyl, (R3)0-2 denotes from 0 to 2 substituents selected from the group C1-C4alkyl, C1-C4alkoxy, halogen and sulfo, X1 is fluorine or chlorine, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, l is the number 2, 3, 4, 5 or 6, and m and n are each independently of the other the number 0 or 1, wherein when A is a radical of formula (3) and D1 is the radical of an azo dye, at least one of the radicals D1 and D2 contains a fibre-reactive radical of formula (2) with the proviso that A is a radical of formula (2) when D1 is the radical of an aromatic tetraazo component, and A is a radical of formula (3) when D1 is a radical of formula (4), are especially suitable for dyeing cotton and wool and yield dyeings having good all round properties.

    摘要翻译： 式（1）的活性染料其中b为数1或2，A为式（2）或（3）的基团，当b为数1或基团时，D1为自由基式或偶氮染料基团 的芳香族四偶氮组分，当b为数2时，D 2为苯或萘系的重氮组分的基团，R 1和R 2各自独立地为氢或C 1 -C 4烷基，（R 3）0-2表示 0-2个选自C1-C4烷基，C1-C4烷氧基，卤素和磺基的取代基，X1是氟或氯，Y是乙烯基或基团-CH2-CH2-U，U是在碱性条件下可除去的基团，l 是2,3,4,5或6号，m和n分别独立为数字0或1，其中当A是式（3）的基团且D1是偶氮染料的基团时，至少 自由基D1和D2之一含有式（2）的纤维反应性基团，条件是当D1是芳族四偶氮组分的基团时，A是式（2）的基团，A是 当D1是式（4）的基团时，式（3）的基团特别适用于染色棉和羊毛并产生具有良好全面性能的染色。

    Azo dyes
    100.
    发明授权
    Azo dyes 失效
    偶氮染料

    公开(公告)号：US5723587A

    公开(公告)日：1998-03-03

    申请号：US694142

    申请日：1996-08-08

    申请人： Antoine Clement ,  Athanassios Tzikas

    发明人： Antoine Clement ,  Athanassios Tzikas

    IPC分类号： B41M5/26 ,  B41M5/388 ,  C09B29/00 ,  C09B29/01 ,  C09B29/033 ,  C09B29/08 ,  C09B29/085 ,  C09B29/09 ,  C09B67/22 ,  D06P3/54 ,  D06P1/18

    CPC分类号： B41M5/388 ,  C09B29/0033 ,  C09B29/0077 ,  C09B29/0816 ,  C09B67/0051

    摘要： Disperse dyes of formula ##STR1## wherein D is the radical of a diazo component of the benzene, naphthalene, diphenyl, azobenzene, thiophene, benzothiazole, benzisothiazole, thiazole, thiadiazole, indazole, benzotriazole, pyrazole, anthraquinone, naphtholimide, chromone or diphenylene oxid series; X is hydrogen, methyl, halogen or --NH--CO--R, wherein R is methyl, ethyl, propyl, isopropyl, ethoxy or amino; Y is hydrogen, halogen, methoxy or --O--(CH.sub.2).sub.n --OR', wherein R' is hydrogen, CH.sub.3 or CH.sub.2 CH.sub.2 CN, and n is an integer from 1 to 6; R.sub.3 is C.sub.1 -C.sub.6 alkyl, and R.sub.4 is hydrogen, C.sub.1 -C.sub.6 alkyl or alkyl. The dyes are particularly suitable for dyeing polyester textile material and are distinguished in particular by very good lightfastness.

    摘要翻译： 式（1）的分散染料其中D是苯，萘，二苯基，偶氮苯，噻吩，苯并噻唑，苯并异噻唑，噻唑，噻二唑，吲唑，苯并三唑，吡唑，蒽醌，萘磺酰，色酮的重氮组分 或二亚苯基氧化物系列; 乙基，丙基，异丙基，乙氧基或氨基; X是氢，甲基，卤素或-NH-CO-R， Y是氢，卤素，甲氧基或-O-（CH 2）n -OR'，其中R'是氢，CH 3或CH 2 CH 2 CN，n是1至6的整数; R3是C1-C6烷基，R4是氢，C1-C6烷基或烷基。 染料特别适用于染色聚酯纺织材料，特别是具有非常好的耐光性。