摘要:
An adhesive sheet with a base for flexible printed wiring boards is provided, which has advantages of easiness of machining, excellent moldability, high rigidity and preventing the fall of resin dust particles during machining of a multilayer flexible printed wiring board or a flex-rigid printed wiring board. This adhesive sheet is used for bonding of a flexible printed wiring board made of a polyimide resin, and comprises a woven or nonwoven fabric as the base and a resin composition. The resin composition contains, as essential components, (a) an epoxy resin having two or more of epoxy groups in one molecule; (b) a polycarbodiimide resin dispersible in a solvent, in which the epoxy resin (a) is also dispersible, and having a number average molecular weight of 2000 or more and less than 10000; and (c) an imidazole curing agent. A weight ratio of the component (a) and the component (b) is in a range of 80:20 to 20:80.
摘要:
It is an object of the present invention to provide a composition for an acoustically matching layer, having sufficient mechanical strength to allow itself to be easily formed, and capable of giving an acoustically matching layer highly stable in characteristics over extended periods even under high temperature and high humidity conditions. The present invention provides a composition containing a carbodiimide resin for an acoustically matching layer, where the composition may further contain inorganic hollow bodies or inorganic hollow bodies and another reactive resin; a process for producing a formed article of an acoustically matching layer by curing and forming under heating the composition in a mold for the acoustically matching layer; and an ultrasonic transducer using the same composition and ultrasonic transducer using the same formed article.
摘要:
A thermosetting polycarbodiimide copolymer of the present invention comprises in a molecule thereof, a soft segment containing at least one residue formed by removing opposite functional end groups of polytetramethylene ether glycol, polyether block amide and polyalkylene carbonate diol having at least two mixed alkylene chains selected from the group consisting of hexamethylene, pentamethylene and tetramethylene; and a hard segment made of polycarbodiimide bonded to the soft segment through at least one bond selected from the group consisting of an urethane bond, a urea bond and an amide bond. The thermosetting polycarbodiimide copolymer can exhibit not only a high heat resistance and a good flexibility, but also an excellent flexing resistance (resistance to 180° bending),and can be, therefore, suitably used in applications of various electronic parts, for example, as materials of base films or cover-lay films for flexible wiring boards, or adhesive films.
摘要:
A binder composition suitable for electronic parts applications and adapted for lamination treatments, which has particularly superior storage stability and adhesive strength as well as a high elastic modulus even at high temperatures, and an adhesive film using the same. More concretely, a binder composition for lamination to be used for such as adhesion of copper foil onto a glass fiber reinforced epoxy resin substrate, characterized by containing a carbodiimide resin (a) and a high molecular weight epoxy resin (b) having average molecular weight of not lower than 500, and the ratio of the components being 30 to 200 parts by weight of (b) based on 100 parts by weight of (a), as well as an adhesive film using the same, and the like.
摘要:
A method for bonding LCPs mutually or an LCP and another material comprising the step of bonding LCPs mutually or an LCP and another material using an adhesive prepared by adding a polycarbodiimide resin with an epoxy resin composition comprising an epoxy resin and a curing agent, thereby providing excellent adhesion and heat resistance.
摘要:
The present invention provides a film-shaped encapsulating agent for electronic parts which is composed essentially of a polycarbodiimide resin and an epoxy resin or of a polycarbodiimide resin, an epoxy resin and colorant, wherein the polycarbodiimide resin has a polystyrene-reduced number-average molecular weight of 3,000 to 50,000 as determined by gel permeation chromatography and the epoxy resin is contained in a proportion of 20 to 150 parts by weight per 100 parts by weight of the polycarbodiimide resin. The film-shaped encapsulating agent enables, for its good processability, the continuous encapsulation of electronic parts without requiring any expensive apparatus (therefore, no cost increase is incurred) and is excellent in heat resistance and electrical insulation after the encapsulation.
摘要:
An epoxy resin composition consisting essentially of an epoxy resin, a thixotropy-imparting agent, a filler used as necessary, water and a polycarbodiimide resin; and an epoxy resin-based adhesive comprising the above epoxy resin composition and a curing agent. The above epoxy resin composition has excellent thixotropy and low stringiness; and the above epoxy resin-based adhesive, when cured, shows neither metal corrosion nor reduction in moisture resistance despite the presence of water in the adhesive, and has excellent heat resistance and adhesivity.
摘要:
A process for producing a polycarbodiimide resin powder, which includes reacting an organic diisocyanate in the presence of a carbodiimidization catalyst in a solvent to produce a polycarbodiimide resin and obtaining the resin in a powder form, where the organic diisocyanate is represented by the following formula ##STR1## where R.sub.1 is a lower alkyl group or a lower alkoxyl group, or ##STR2## where R.sub.2 and R.sub.3 are independently a hydrogen atom, a lower alkyl group or a lower alkoxyl group, and X is an oxygen atom or a methylene group, or ##STR3## where R.sub.4 and R.sub.5 are independently a hydrogen atom, a lower alkyl group or a lower alkoxyl group; the solvent is a mixed solvent of a good solvent to polycarbodiimide resin and a poor solvent to the resin, having a precipitation number of 30-80; and when the reaction has reached a certain stage, the reaction system is cooled to make the system a slurry of a polycarbodiimide, and then the polycarbodiimide is obtained in a powder form.
摘要:
A modified carbodiimide resin obtainable by reacting a carbodiimide resin comprising a repeating unit represented by the general formula: —(NCN—R1)— wherein R1 represents a divalent organic group, with an aromatic diamine represented by the general formula: H2N—R2—NH2 wherein R2 represents a divalent organic group having a benzene ring, and a thermosetting resin composition comprising the modified carbodiimide resin and an epoxy resin.
摘要:
The present invention provides a one-pack type epoxy resin composition comprising an epoxy resin having at least two epoxy groups in the molecule and a polyguanidine. The one-pack type epoxy resin composition has high storage stability, can be made into a film, is curable at relatively low temperatures, and has high adhesivity.