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11.
公开(公告)号:US20170044310A1
公开(公告)日:2017-02-16
申请号:US15303676
申请日:2015-04-24
Applicant: DAICEL CORPORATION , Tokyo Institute of Technology
Inventor: Ikuyoshi TOMITA , Yoshimasa MATSUMURA , Ichiro TAKASE , Kazuhisa FUKUI
CPC classification number: H01L51/0043 , C08G61/12 , C08G2261/12 , C08G2261/1424 , C08G2261/152 , C08G2261/312 , C08G2261/3223 , C08G2261/3227 , C08G2261/91 , C09B69/109 , H01G9/2059 , H01L51/0036 , H01L51/0512 , H01L51/0558 , H01L51/42 , H01L51/50 , Y02E10/542 , Y02P70/521
Abstract: The organic heteropolymer of this invention is useful for forming an organic semiconductor and is a copolymeric heteropolymer having a constitutional unit represented by the formula (1) and a constitutional unit represented by the formula (2): wherein M1 and M2 each represent a heteroatom selected from a group 8 element, a group 9 element, a group 10 element, a group 14 element, a group 15 element, and a group 16 element of the Periodic Table, and are different in group; M1 and M2 each have a valence v of 2 to 6; R1a and R1b each represent a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, or a heteroaryl group; R2a and R2b each represent a halogen atom, an alkyl group, a cycloalkyl group, an aryl group, a heteroaryl group, a univalent or bivalent heteroatom selected from a group 16 element and a group 11 element of the Periodic Table, or a metal atom forming a complex with a ligand; m1, m2, n1, and n2 each denote 0 or 1; a ring Ar represents an aromatic ring; R3 represents a straight- or branched-chain alkyl group, a straight- or branched-chain alkoxy group, or a straight- or branched-chain alkylthio group; and p denotes 0 or an integer of 1 to 3.
Abstract translation: 其中M1和M2各自表示选自元素周期表第8族元素,第9族元素,第10族元素,第14族元素,第15族元素和第16族元素的杂原子, ; M1和M2各自具有2至6的化合价v; R1a和R1b各自表示卤素原子,烷基,环烷基,芳基或杂芳基; R2a和R2b各自表示选自元素周期表第16族元素和第11族元素中的卤素原子,烷基,环烷基,芳基,杂芳基,一价或二价杂原子,或金属原子 与配体形成络合物; m1,m2,n1和n2分别表示0或1; 环Ar表示芳香环; R3表示直链或支链烷基,直链或支链烷氧基或直链或支链烷硫基; p表示0或1〜3的整数。