公开(公告)号：US4024123A

公开(公告)日：1977-05-17

申请号：US449205

申请日：1974-03-07

申请人： Paul Dussy ,  Hans Ackermann

发明人： Paul Dussy ,  Hans Ackermann

IPC分类号： C09B62/018 ,  C09B62/20 ,  C09B62/44 ,  C09B62/08 ,  C09B62/16 ,  C09B62/24 ,  C09B62/50

CPC分类号： C09B62/205 ,  C09B62/018 ,  C09B62/4422

摘要： Fiber-reactive, heavy metal-containing formazane dyestuffs are disclosed which are tricyclic and wherein the heavy metal is a metal of an atomic number ranging from 24 to 30 and is bonded via a --COO-- and --O-- substituent to different diazo components and to the terminal nitrogen atoms of the central formazane bridge portion ##STR1## wherein R represents an optionally substituted aliphatic hydrocarbon radical, a cycloaliphatic radical or a carbo- or heterocyclic-aromatic radical, one of the aforesaid diazo components or the radical R bearing the fiber-reactive substituent. These dyestuffs are useful for the dyeing and printing of textile materials, and also of synthetic materials for other then textile uses. The dyestuffs may contain or may be free from watersolubilizing groups the former being especially useful for the dyeing of leather, paper, and natural or synthetic polypeptide fiber materials, as well as for the dyeing and printing of material or regenerated cellulosic fiber materials, especially cotton. Dyestuffs in which this fiber-reactive substituent is a pyrimidyl amino radical containing at least one fluorine atom are distinguished by their high reactivity; dyeings or prints obtained therewith are very stable vis-a-vis acid or alkaline hydrolysis and exhibit very good fastness to light, milling and wet treatments.

摘要翻译： 公开了具有三环的纤维反应性重金属的甲ane染料，其中重金属是原子序数范围为24-30的金属，并通过-COO-和-O-取代基与不同的重氮组分键合， 其中R表示任选取代的脂族烃基，脂环族基团或碳 - 杂环芳族基团，前述重氮组分之一或带有纤维的基团R - 反应性取代基。 这些染料可用于纺织材料的染色和印花，以及用于纺织品用途的合成材料。 染料可能含有或可能没有水溶性基团，前者特别适用于皮革，纸张和天然或合成多肽纤维材料的染色，以及用于染色和印刷材料或再生纤维素纤维材料，特别是棉花 。 其纤维反应性取代基是含有至少一个氟原子的嘧啶基氨基的染料的特征在于其高反应性; 由此获得的染色或印花相对于酸或碱性水解非常稳定，并且显示出非常好的耐光牢度，研磨和湿处理。