摘要:
A layered microporous polymeric membrane includes a first blend region having a thickness T1, a third blend region having a thickness T3, and a second blend region located between the first and third blend regions and having a thickness T2, wherein [(T1−T2)/T1]≧0.05 and [(T3−T2)/T3]≧0.05.
摘要:
A microporous polyethylene membrane made of a polyethylene resin having a ratio (mass-average molecular weight/number-average molecular weight) of 5 to 300 and comprising 1% or more by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 7×105 or more, the microporous polyethylene membrane comprising (a) a coarse-structure layer having an average pore diameter of more than 0.04 μm, which is formed on at least one surface, and (b) a dense-structure layer having an average pore diameter of 0.04 μm or less, an area ratio of the coarse-structure layer to the dense-structure layer in a membrane cross section being 0.1 to 0.8.
摘要:
A coextrusion die for producing a multilayer film or sheet of thermoplastic materials. The coextrusion die includes a die outlet through which a layered melt stream of the thermoplastic materials is extruded as a multilayer film or sheet, a first die section for producing a core layer, the first die section having a flat manifold, the flat manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet, a second die section for producing a first skin layer, the second die section having a cross flow manifold, the cross flow manifold having a flow path wherein a portion of a melt stream of the thermoplastic material traverses the second die section's length more than once, the cross flow manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet, and a third die section for producing a second skin layer, the third die section having a cross flow manifold, the cross flow manifold having a flow path wherein a portion of a melt stream of the thermoplastic material traverses the third die section's length more than once, the cross flow manifold having a feed entrance and a pressure manifold in communication with the slotted die outlet. A process for making a multilayer extrudate of thermoplastic materials is also provided.
摘要:
The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.
摘要:
A microporous polyolefin membrane is formed by fine fibrils, comprising (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing component (A), connected to each other, and has micropores of 0.05 to 5 &mgr;m in average pore size and crystal lamellas of component (A) or (B) being in a specific orientation state. The membrane is produced by extruding a solution of component (A) or (B) in a solvent, into a gel-like formed article; thermally setting the article, with or without stretching, at least at the crystal dispersion temperature of component (A) or (B), but at melting point of component (A) or (B) plus 30° C. or lower; and removing the solvent.
摘要:
The thin film of non-protonic electrolyte comprises the microporous polyolefin film impregnated with an immobilized non-protonic electrolytic solution, where the film is treated to have improved affinity for the non-protonic solution by graft polymerization of the film with a monomer which can dissolve the non-protonic electrolytic solution, coating of the film with terminal-modified polypropylene which can dissolve the non-protonic electrolytic solution or coating of the film with wax which can dissolve the non-protonic electrolytic solution. The electrolyte-immobilized liquid-film conductor comprises the microporous polyolefin film impregnated with an immobilized non-protonic electrolytic solution, where the film contains an electron-conductive substance and is treated to have improved affinity for the non-protonic solution. The thin film of non-protonic electrolyte comprising the microporous polyolefin film gives a polymer battery, such as lithium battery, when combined with an anode and cathode. The polymer battery comprising the thin film of non-protonic electrolyte and the electrolyte-immobilized liquid-film conductor which is used at least one of the anode and cathode is advantageous over the conventional lithium battery of polymer electrolyte in various aspects, such as higher discharging function at low temperature, lesser self-discharge at high temperature, and higher charge/discharge characteristics over extended periods.
摘要:
A method of producing a microporous thermoplastic resin membrane of excellent permeability having uniform and fine micropores without filling stress concentrators to the thermoplastic resin is provided. Namely, there is provided a method of producing a microporous thermoplastic resin membrane, in which a thermoplastic resin foam incorporating fine cells having a ratio B/A between a cell size (A) and a wall thickness (B) of the cells of less than 0.5 and having a void ratio of not less than about 50% is subjected to plastic deformation of the boundaries of the cells themselves sufficient to cause shape deformation of the cells, thereby breaking the boundaries of the cells. Also there is provided a microporous thermoplastic resin membrane of excellent permeability having uniform and fine micropores produced by the method as described above.
摘要:
A microporous polyethylene membrane made of a polyethylene resin having a ratio (mass-average molecular weight/number-average molecular weight) of 5 to 300 and comprising 1% or more by mass of ultra-high-molecular-weight polyethylene having a mass-average molecular weight of 7×105 or more, the microporous polyethylene membrane comprising (a) a coarse-structure layer having an average pore diameter of more than 0.04 μm, which is formed on at least one surface, and (b) a dense-structure layer having an average pore diameter of 0.04 μm or less, an area ratio of the coarse-structure layer to the dense-structure layer in a membrane cross section being 0.1 to 0.8.
摘要:
A thermoplastic film including a microporous polymeric membrane; and a non-woven web bonded to the polymeric microporous membrane, wherein the web comprises a plurality of fibers comprising polyolefin having a Tm≧85.0° C. and a Te-Tm≦10.0° C.
摘要:
The present invention provides a microporous polyolefin membrane of high permeability and novel structure, and also provides a method of producing the same, wherein its average pore size is gradually decreases from at least one membrane surface towards its center. The method of producing the microporous polyolefin membrane comprises the steps of extruding the solution, composed of 10 to 50 weight % of (A) a polyolefin having a weight-average molecular weight of 5×105 or more or (B) a composition containing this polyolefin and 50 to 90 weight % of a solvent, into a gel-like formed article and removing the solvent therefrom, wherein a treatment step with a hot solvent is incorporated.