摘要:
A composite material includes a first phase which is present in the form of a plurality of particles comprised of a material having the general formula LixMy(PO4)z wherein M is at least one metal, x is equal to or greater than zero, and y and z are each, independently, greater than zero. The material includes a second phase which is at least partially present in the form of a plurality of elongated filaments which extend between and establish electrical contact with at least two particles of the first phase. The filaments are comprised of a material which includes phosphorus and at least one of the at least one metal M. The material of the second phase has an electrical conductivity which is greater than the electrical conductivity of the material of the first phase. Also disclosed are methods for manufacturing the material. The material has utility as an electrode material for devices such as lithium batteries.
摘要翻译:复合材料包括第一相,其以多个颗粒的形式存在,所述多个颗粒由具有通式为Li x M(PO 4)(PO 4) 其中M是至少一种金属,x等于或大于零,y和z各自独立地大于零。 该材料包括第二相,该第二相至少部分地以多个细长丝的形式存在,其在第一相的至少两个颗粒之间延伸并与之建立电接触。 长丝由包括磷和至少一种金属M中的至少一种的材料组成。第二相的材料具有大于第一相的材料的电导率的导电性。 还公开了用于制造材料的方法。 该材料可用作诸如锂电池的装置的电极材料。
摘要:
A composite material which may be used as an electrode for a battery or other electrochemical device, or as a catalyst, has a matrix which is one or more metal carbide, metal nitride, metal boride, metal silicide or intermetallic compound. A metallic component is dispersed in the matrix. The metallic component comprises a metal and an agent which increases the melting point of the metal. The metallic component may be nanodispersed in the matrix. A specific material comprises a nanodispersion of tin, alloyed with an element which increases its melting point to at least 600° C., disposed in a matrix of a transition metal carbide or nitride. This material has very good utility as an anode material for lithium batteries. Also disclosed are other compositions as well as methods for manufacturing the compositions.