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公开(公告)号:US5660965A
公开(公告)日:1997-08-26
申请号:US663416
申请日:1996-06-17
CPC分类号: G03G9/08704 , G03G9/0804 , G03G9/08755 , G03G9/08791
摘要: A process for the preparation of toner compositions, or toner particles comprising generating a latex comprised of a sulfonated polyester and olefinic resin in water; generating a pigment mixture comprised of said pigment dispersed in water; shearing said latex and said pigment mixture; adding an alkali (II) halide; stirring and heating to enable coalescence; followed by filtration and drying.
摘要翻译: 一种制备调色剂组合物或调色剂颗粒的方法,包括在水中产生由磺化聚酯和烯属树脂组成的胶乳; 产生由分散在水中的所述颜料组成的颜料混合物; 剪切胶乳和颜料混合物; 加入卤化碱(II); 搅拌和加热以使聚结; 然后过滤和干燥。
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公开(公告)号:US5645968A
公开(公告)日:1997-07-08
申请号:US726600
申请日:1996-10-07
CPC分类号: G03G9/0804
摘要: A process for the preparation of toner comprising(i) preparing, or providing a cationic emulsion resin latex comprised of a resin derived from at least one olefinic nonpolar monomer, a cationic olefinic monomer, a cationic free radical initiator, and optionally a chain transfer agent in an aqueous mixture comprised of a nonionic surfactant and a cationic surfactant, and which mixture is heated at a temperature of from about 60.degree. C. to about 95.degree. C.;(ii) adjusting the pH of said cationic latex to from about 10 to about 14 by the addition of a base;(iii) preparing, or providing a pigment dispersion, which dispersion is comprised of a pigment and an anionic surfactant, and optionally a charge control agent;(iv) shearing said pigment dispersion with the pH adjusted latex of (ii) and heating below about the resin Tg to form electrostatically bound toner size aggregates, and optionally adding a cationic surfactant to stabilize the size of the toner aggregates; and(v) heating said electrostatically bound toner size aggregates above about the Tg of the resin to form coalesced toner particles; followed by optionally filtering, washing and drying the toner obtained.
摘要翻译: 一种制备调色剂的方法,包括(i)制备或提供由至少一种烯属非极性单体衍生的树脂,阳离子烯烃单体,阳离子自由基引发剂和任选的链转移剂组成的阳离子乳液树脂胶乳 在由非离子表面活性剂和阳离子表面活性剂组成的含水混合物中,将混合物在约60℃至约95℃的温度下加热; (ii)通过加入碱将所述阳离子胶乳的pH调节至约10至约14; (iii)制备或提供颜料分散体,该分散体由颜料和阴离子表面活性剂以及任选的电荷控制剂组成; (iv)用(ii)的pH调节的胶乳剪切所述颜料分散体,并加热到树脂Tg附近,以形成静电结合的调色剂尺寸聚集体,以及任选地加入阳离子表面活性剂以稳定调色剂聚集体的尺寸; 和(v)在所述树脂的Tg附近加热所述静电结合的调色剂尺寸聚集体以形成聚结的调色剂颗粒; 然后任选地过滤,洗涤和干燥获得的调色剂。
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公开(公告)号:US5223370A
公开(公告)日:1993-06-29
申请号:US802976
申请日:1991-12-06
申请人: Guerino G. Sacripante , Raj D. Patel , Grazyna Kmiecik-Lawrynowicz , Hock S. Tan , Walter Mychajlowskij
发明人: Guerino G. Sacripante , Raj D. Patel , Grazyna Kmiecik-Lawrynowicz , Hock S. Tan , Walter Mychajlowskij
CPC分类号: G03G9/09307 , G03G9/09328
摘要: An encapsulated toner composition and process thereof, which toner is comprised of a core comprised of a polymer resin or resins, color pigment, dye, or mixtures thereof, and thereover an inner shell resin comprised, for example, of a polyurea, and thereover an outer shell coating comprised of an alkyl cellulose. The colored encapsulated toners are useful in reprographic processes wherein, for example, low gloss is desired.
摘要翻译: 包封的调色剂组合物及其方法,调色剂由聚合物树脂或树脂构成的芯,彩色颜料,染料或其混合物,以及由例如聚脲组成的内壳树脂组成, 外壳涂层由烷基纤维素组成。 着色的胶体调色剂可用于其中例如需要低光泽的再现过程中。
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公开(公告)号:US06348561B1
公开(公告)日:2002-02-19
申请号:US09838407
申请日:2001-04-19
IPC分类号: C08G6344
CPC分类号: C08G63/6886 , C08G63/6856
摘要: An alkali sulfonated polyester-amine resin generated from the reaction of an organic diol, and a mixture of an organic diacid, an alkali sulfonated diacid and an amino-organic diacid.
摘要翻译: 由有机二醇与有机二元酸,碱金属磺化二酸和氨基有机二酸的混合物反应生成的碱金属磺化聚酯 - 胺树脂。
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公开(公告)号:US5853944A
公开(公告)日:1998-12-29
申请号:US6612
申请日:1998-01-13
CPC分类号: G03G9/0804 , G03G9/08755
摘要: A process for the preparation of toner with a first aggregation of sulfonated polyester, and thereafter a second aggregation with a colorant dispersion and an alkali halide.
摘要翻译: 一种用磺化聚酯的第一聚集制备调色剂的方法,然后用着色剂分散体和碱金属卤化物进行第二聚集。
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公开(公告)号:US5698223A
公开(公告)日:1997-12-16
申请号:US829551
申请日:1997-03-28
CPC分类号: G03G9/0804 , G03G9/08768
摘要: A process for the preparation of toner comprising (i) solubilizing an imide based resin in water at pH of from about 10 to about 13 and which solubilizing is accomplished in the presence of nonionic surfactants and anionic surfactants; followed by precipitating the resulting dissolved imide resin into colloidal particles with a size diameter of from about 20 nanometers to about 500 nanometers, and which precipitating is accomplished with a high shearing device operating at a speed of from about 500 to about 2,000 revolutions per minute; acidifying the resulting mixture to a pH of from about 2 to about 4; (ii) preparing a pigment dispersion in water, which dispersion is comprised of a pigment, an oppositely charged ionic surfactant and optionally charge control agent; (iii) shearing (i) and (ii), thereby causing a flocculation of the resin, pigment, surfactants, and optional charge control agent; (iv) heating the resulting flocculent mixture of (iii) with stirring at a temperature of from about 25.degree. C. to about 1.degree. C. below the glass transition temperature (Tg) of the imide resin to effect formation of electrostatically bounded toner sized aggregates, and wherein the imide resin has a Tg of from about 45.degree. C. to about 65.degree. C.; (v) heating the resulting aggregate suspension of (iv) in the presence of additional anionic surfactant selected in an amount of from about 0.01 to about 5 weight percent based on the weight percent of the total reaction mixture solids, and which heating is at a temperature of from about 10.degree. C. to about 55.degree. C. above the Tg of the imide resin; and optionally cooling, and optionally (vi) separating said toner by washing, and thereafter drying said toner.
摘要翻译: 一种制备调色剂的方法,包括(i)将酰亚胺基树脂溶解在约10至约13的pH下,并且在非离子表面活性剂和阴离子表面活性剂存在下进行增溶; 然后将所得溶解的酰亚胺树脂沉淀成尺寸直径为约20纳米至约500纳米的胶体颗粒,并且以约500至约2000转/分钟的速度运行的高剪切装置完成沉淀; 将所得混合物酸化至约2至约4的pH; (ii)在水中制备颜料分散体,该分散体由颜料,相反电荷的离子表面活性剂和任选的电荷控制剂组成; (iii)剪切(i)和(ii),从而引起树脂,颜料,表面活性剂和任选的电荷控制剂的絮凝; (iv)在低于酰亚胺树脂的玻璃化转变温度(Tg)的约25℃至约1℃的温度下搅拌加热得到的(ⅲ)絮状混合物,以形成静电有界调色剂尺寸 聚集体,并且其中所述酰亚胺树脂的Tg为约45℃至约65℃。 (v)在所选择的另外的阴离子表面活性剂存在下加热得到的(iv)聚集体悬浮液,其量为总反应混合物固体的重量百分比为约0.01至约5重量%,加热为 温度高于酰亚胺树脂的Tg约10℃至约55℃; 并任选地冷却,并且任选地(vi)通过洗涤分离所述调色剂,然后干燥所述调色剂。
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公开(公告)号:US5604076A
公开(公告)日:1997-02-18
申请号:US595143
申请日:1996-02-01
申请人: Raj D. Patel , Guerino G. Sacripante , Grazyna E. Kmiecik-Lawrynowicz , Michael A. Hopper , Francisco E. Torres
发明人: Raj D. Patel , Guerino G. Sacripante , Grazyna E. Kmiecik-Lawrynowicz , Michael A. Hopper , Francisco E. Torres
CPC分类号: G03G9/0806
摘要: A process for the preparation of toner compositions comprising:(i) preparing a latex or emulsion resin comprised of a polyester core encapsulated within a styrene based resin shell by heating said polyester emulsion containing an anionic surfactant with a mixture of monomers of styrene and acrylic acid, and with potassium persulfate, ammonium persulfate, sodium bisulfite, or mixtures thereof;(ii) adding a pigment dispersion, which dispersion is comprised of a pigment, a cationic surfactant, and optionally a charge control agent, followed by the sharing of the resulting blend;(iii) heating the above sheared blend below about the glass transition temperature (Tg) of the resin to form electrostatically bound toner size aggregates with a narrow particle size distribution; and(iv) heating said electrostatically bound aggregates above about the Tg of the resin.
摘要翻译: 一种制备调色剂组合物的方法,包括:(i)通过将含有阴离子表面活性剂的聚酯乳液与苯乙烯和丙烯酸的单体混合物加热,制备由包封在苯乙烯基树脂壳内的聚酯芯构成的胶乳或乳液树脂 和过硫酸钾,过硫酸铵,亚硫酸氢钠或其混合物; (ii)添加颜料分散体,该分散体由颜料,阳离子表面活性剂和任选的电荷控制剂组成,然后共享所得共混物; (iii)将上述剪切混合物加热至低于树脂的玻璃化转变温度(Tg),以形成具有窄粒度分布的静电结合的调色剂尺寸聚集体; 和(iv)将所述静电结合的聚集体加热到高于树脂的Tg的高度。
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公开(公告)号:US06210853B1
公开(公告)日:2001-04-03
申请号:US09657340
申请日:2000-09-07
IPC分类号: G03G9087
CPC分类号: G03G9/08708 , G03G9/0806 , G03G9/0819 , G03G9/08711 , G03G9/08755
摘要: A process for the preparation of toner including (i) gerating by emulsion polymerization in the presence of an initiator a first resin latex emulsion; (ii) generating by polycondensation a second resin latex optionally in the presence of a catalyst; (iib) dispersing the resin of (ii) in water; (iii) mixing (iib) with a colorant thereby providing a colorant dispersion; (iiib) mixing the resin latex emulsion of (i) with the resin/colorant mixture of (iii) to provide a blend of a resin and colorant; (iv) adding an aqueous inorganic cationic coagulant solution of a polymeric metal salt and optionally an organic cationic coagulant to the resin/colorant blend of (iiib); (v) heating at a temperature of from about 5 to about 10 degrees Centigrade below the resin Tg of (i), to thereby form aggregate particles and which particles are optionally at a pH of from about 2 to about 3.5; (vi) adjusting the pH of (v) to about 6.5 to about 9 by the addition of a base; (vii) heating the aggregate particles of (v) at a temperature of from about 5 to about 50 degrees Centigrade above the Tg of the resin of (i), followed by a reduction of the pH to from about 2.5 to about 5 by the addition of an acid resulting in coalesced toner; (viii) optionally isolating the toner.
摘要翻译: 一种制备调色剂的方法,包括(i)在引发剂存在下通过乳液聚合第一树脂胶乳乳液; (ii)任选地在催化剂存在下通过缩聚产生第二树脂胶乳; (iib)将(ii)的树脂分散在水中; (iii)将混合(iib)与着色剂混合,从而提供着色剂分散体; (iiib)将(i)的树脂胶乳乳液与(iii)的树脂/着色剂混合物混合以提供树脂和着色剂的共混物; (iv)将聚合金属盐和任选的有机阳离子凝结剂的无机阳离子凝结剂水溶液加入到(iiib)的树脂/着色剂混合物中; (v)在(i)的树脂Tg以下约5至约10摄氏度的温度下加热,从而形成聚集体颗粒,并且哪些颗粒任选处于约2至约3.5的pH值; (vi)通过添加碱将(v)的pH调节至约6.5至约9; (vii)在(i)的树脂的Tg以上约5至约50摄氏度的温度下加热(ⅴ)的聚集体颗粒,随后将pH降低至约2.5至约5 加入导致聚结的调色剂的酸; (viii)任选地分离调色剂。
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公开(公告)号:US5679724A
公开(公告)日:1997-10-21
申请号:US536235
申请日:1995-09-29
申请人: Guerino G. Sacripante , Raj D. Patel , Marcel P. Breton , Michael A. Hopper , Grazyna E. Kmiecik-Lawrynowicz , Beng S. Ong
发明人: Guerino G. Sacripante , Raj D. Patel , Marcel P. Breton , Michael A. Hopper , Grazyna E. Kmiecik-Lawrynowicz , Beng S. Ong
摘要: An ink for ink jet printing includes an emulsifiable polymer resin and a pigment, and may be made by: (a) combining (1) an emulsion of an emulsifiable polymer resin in an anionic medium with (2) a pigment and a cationic surfactant; and (b) aggregating particles in the mixture of step (a) to a desired particle size, thereby producing a solution of aggregated particles. The particles can optionally be coalesced to alter the particle size of the particles.
摘要翻译: 用于喷墨印刷的油墨包括可乳化聚合物树脂和颜料,并且可以通过以下制备:(a)将(1)阴离子介质中的可乳化聚合物树脂的乳液与(2)颜料和阳离子表面活性剂组合; 和(b)将步骤(a)的混合物中的颗粒聚集成所需的粒径,从而产生凝集颗粒的溶液。 颗粒可以任选地聚结以改变颗粒的粒度。
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公开(公告)号:US06190820B1
公开(公告)日:2001-02-20
申请号:US09657273
申请日:2000-09-07
IPC分类号: G03G9087
CPC分类号: G03G9/0804 , G03G9/0806
摘要: A process for the preparation of toner by, for example (i) generating by emulsion polymerization in the presence of an initiator a first resin latex emulsion; (ii) generating in the presence of an oil soluble initiator by solution polymerization a second resin latex; (iii) mixing (ii) with a colorant; (iiib) mixing the resin latex emulsion of (i) with the resin/colorant mixture of (iii) to provide a blend of a resin and colorant; (iv) adding an aqueous inorganic cationic coagulant solution of a metal salt and optionally an organic cationic coagulant to the resin/colorant blend of (iiib); (v) heating at a temperature of from about 5° C. to about 10° C. below the resin Tg of (i), to form aggregate particles; (vi) adjusting the pH of (v) by the addition of a base; (vii) heating the aggregate particles of (v) at temperatures of from about 5° C. to about 50° C. above the Tg of the resin of (i), followed by the addition of an acid.
摘要翻译: 通过例如(i)在引发剂存在下通过乳液聚合产生第一树脂胶乳乳液来制备调色剂的方法;(ii)通过溶解聚合在油溶性引发剂的存在下产生第二树脂胶乳; (iii)将(ii)与着色剂混合;(iiib)将(i)的树脂胶乳乳液与(iii)的树脂/着色剂混合物混合以提供树脂和着色剂的共混物;(iv) (iiib)的树脂/着色剂共混物中的金属盐和任选的有机阳离子凝结剂的阳离子凝结剂溶液;(v)在温度为约5℃至约10℃的温度下加热至( i),以形成聚集体颗粒;(vi)通过加入碱来调节(v)的pH;(vii)在约5℃至约50℃的温度下加热(v)的聚集体颗粒 高于(i)的树脂的Tg,然后加入酸。
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