Pressure-sensitive adhesive dispersion comprising polymers with ureido groups or with ureido-analogous groups and prepared by stage polymerization
    15.
    发明授权
    Pressure-sensitive adhesive dispersion comprising polymers with ureido groups or with ureido-analogous groups and prepared by stage polymerization 有权
    压敏粘合剂分散体包含具有脲基或脲基 - 类似基团并通过阶段聚合制备的聚合物

    公开(公告)号:US09365745B2

    公开(公告)日:2016-06-14

    申请号:US13443044

    申请日:2012-04-10

    摘要: A description is given of a pressure-sensitive adhesive dispersion comprising a water-dispersed polymer P1 formed by emulsion polymerization. The polymer P1 is formed from a monomer mixture comprising (a) at least 40% by weight of C4 to C20 alkyl (meth)acrylates which when polymerized as homopolymers have a glass transition temperature of −30° C. or less, (b) at least 0.05% by weight of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR and R is a C1 to C4 alkyl group, (c) at least 0.1% by weight of acid monomers. The polymer P1 is prepared by polymerization in at least 2 stages, the glass transition temperature of a polymer from monomers of the first stage being lower by at least 20° C. than the glass transition temperature of a polymer from monomers of a later, second stage.

    摘要翻译: 给出了包含通过乳液聚合形成的水分散聚合物P1的压敏粘合剂分散体的描述。 聚合物P1由包含(a)至少40重量%的(甲基)丙烯酸C 4至C 20烷基酯的单体混合物形成,当聚均为均聚物的玻璃化转变温度为-30℃或更低时,(b) 至少0.05重量%的具有下式的取代基的(甲基)丙烯酸酯单体,其中X是CH 2,O,NH或NR,R是C 1至C 4烷基,(c)至少0.1重量%的酸单体 。 聚合物P1通过至少两个阶段的聚合制备,聚合物的玻璃化转变温度从第一阶段的单体的玻璃化转变温度比聚合物的玻璃化转变温度低至少20℃,后者的第二阶段的单体 阶段。

    Process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds
    16.
    发明授权
    Process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds 有权
    制备辐射敏感的可自由基聚合的有机化合物的方法

    公开(公告)号:US08648212B2

    公开(公告)日:2014-02-11

    申请号:US13258899

    申请日:2010-03-30

    IPC分类号: C08F220/10 C08K5/07 C08F2/06

    摘要: A description is given of a process for preparing solutions of radiation-sensitive, free-radically polymerizable organic compounds, where a first starting compound, which has an acid halide group, and a second starting compound, which has an alcoholic hydroxyl group, are esterified with one another in a solvent or in a solvent mixture. The solvent comprises one or more ketones having a boiling point of below 150° C. under atmospheric pressure (1 bar), or the solvent mixture is composed to an extent of at least 50% by weight of said ketones. One of the two starting compounds has at least one radiation-sensitive group and the other of the two starting compounds has at least one ethylenically unsaturated, free-radically polymerizable group. A description is also given of corresponding solutions of radiation-sensitive, free-radically polymerizable organic compounds and of their use for preparing radiation-crosslinkable, free-radically copolymerized copolymers, more particularly for hotmelt pressure-sensitive adhesives or aqueous polymer dispersions.

    摘要翻译: 描述了制备具有卤化物基团的第一起始化合物和具有醇羟基的第二起始化合物的辐射敏感的可自由基聚合的有机化合物的溶液的方法,所述方法被酯化 彼此在溶剂或溶剂混合物中。 溶剂包含一种或多种在大气压(1巴)下沸点低于150℃的酮,或溶剂混合物的组成为所述酮的至少50重量%。 两种起始化合物中的一种具有至少一个辐射敏感性基团,并且两种起始化合物中的另一种具有至少一个烯键式不饱和的可自由基聚合的基团。 还给出了对辐射敏感的可自由基聚合的有机化合物的相应解决方案的描述,以及它们用于制备辐射可交联的自由基共聚共聚物的用途,更特别地用于热熔粘合剂或水性聚合物分散体。

    SOUND DEADENER COMPOSITION WITH EMULSION POLYMER STABILIZED BY PROTECTIVE COLLOIDS
    17.
    发明申请
    SOUND DEADENER COMPOSITION WITH EMULSION POLYMER STABILIZED BY PROTECTIVE COLLOIDS 有权
    具有由保护胶体稳定的乳液聚合物的声衰减剂组合物

    公开(公告)号:US20120027941A1

    公开(公告)日:2012-02-02

    申请号:US13186637

    申请日:2011-07-20

    IPC分类号: E04B1/82 B05D3/02

    摘要: A description is given of the use of a polymer dispersion for preparing sound deadener compositions, the polymer dispersion being obtainable by emulsion polymerization of free-radically polymerizable monomers in the presence of at least one protective colloid which is an amphiphilic graft copolymer. Preferred protective colloids have a polyalkylene oxide main chain and vinyl ester-comprising side chains. A description is also given of corresponding sound deadener compositions which comprise the polymer dispersion, and of a method for damping oscillations or vibrations of vehicle components.

    摘要翻译: 给出了聚合物分散体用于制备声音消音组合物的用途,聚合物分散体可通过在至少一种作为两亲性接枝共聚物的保护胶体存在下的可自由基聚合单体的乳液聚合获得。 优选的保护胶体具有聚环氧烷主链和含乙烯基酯的侧链。 还给出了包含聚合物分散体的对应的消声器组合物的描述,以及用于阻止车辆部件的振荡或振动的方法。

    Method for producing an aqueous polymer dispersion
    18.
    发明授权
    Method for producing an aqueous polymer dispersion 失效
    聚合物水分散体的制造方法

    公开(公告)号:US07632902B2

    公开(公告)日:2009-12-15

    申请号:US10513335

    申请日:2003-05-21

    摘要: The invention relates to a method for producing an aqueous polymer dispersion having a polymer solids content of ≧50% by weight by carrying out the radically initiated aqueous emulsion polymerization of ethylenically unsaturated compounds (monomers). The inventive method is characterized in that: a) a mixture is provided in a polymerization vessel and contains a partial quantity 1 consisting of: deionized water, 0.001 to 0.5 parts by weight of a polymer with a weighted average particle diameter of ≦100 nm; 0.0001 to 0.1 parts by weight of dispersants, and 0.5 to 10 parts by weight of monomers, and the monomers are polymerized with a conversion of ≧80% [polymerization step A], and; b) afterwards, a monomer emulsion containing partial quantity 2, which consists of deionized water, 0.1 to 5 parts by weight of dispersants and 90 to 99.5 parts by weight of monomers, is fed under polymerization conditions to the obtained reaction mixture [polymerization step B], whereby; c) the total amount of the monomers used for the polymerization is equal to 100 parts by weight, and the total amount of deionized water is ≦100 parts by weight.

    摘要翻译: 本发明涉及通过进行烯键式不饱和化合物(单体)的自由引发的水乳液聚合来制备聚合物固体含量≥50重量%的聚合物水分散体的制备方法。 本发明的方法的特征在于:a)在聚合容器中提供混合物,并含有部分量1,其组成为:去离子水,0.001至0.5重量份的加权平均粒径<= 100nm的聚合物 ; 0.0001〜0.1重量份分散剂和0.5〜10重量份单体,单体以≥80%的转化率[聚合步骤A]进行聚合, b)之后,在聚合条件下将得自部分量2的由去离子水,0.1至5重量份分散剂和90至99.5重量份单体组成的单体乳液加入到所得反应混合物中[聚合步骤B ], c)用于聚合的单体的总量等于100重量份,去离子水的总量<100重量份。

    Hotmelt adhesive comprising radiation-crosslinkable poly(meth)acrylate and oligo(meth)acrylate with nonacrylic C-C double bonds
    20.
    发明授权
    Hotmelt adhesive comprising radiation-crosslinkable poly(meth)acrylate and oligo(meth)acrylate with nonacrylic C-C double bonds 有权
    包含可辐射交联的聚(甲基)丙烯酸酯和具有非丙烯酸C-C双键的低聚(甲基)丙烯酸酯)的热熔粘合剂

    公开(公告)号:US08871827B2

    公开(公告)日:2014-10-28

    申请号:US13487550

    申请日:2012-06-04

    摘要: Described is a radiation-crosslinkable hotmelt adhesive comprising at least one radiation-crosslinkable poly(meth)acrylate formed to an extent of at least 60% by weight of C1 to C10 alkyl(meth)acrylates and at least one oligo(meth)acrylate which comprises nonacrylic C C double bonds and has a K value of less than or equal to 20. The hotmelt adhesive comprises a photoinitiator which may be present in the form of an additive not attached to the poly(meth)acrylate and/or not attached to the oligo(meth)acrylate, may be incorporated by copolymerization into the poly(meth)acrylate, and/or may be attached to the oligo(meth)acrylate. The hotmelt adhesive can be used for producing adhesive tapes.

    摘要翻译: 描述了一种辐射可交联的热熔粘合剂,其包含至少一种以至少60重量%的C 1 -C 10烷基(甲基)丙烯酸酯和至少一种低聚(甲基)丙烯酸酯的至少一种可辐射交联的聚(甲基)丙烯酸酯的程度形成的至少一种低聚(甲基)丙烯酸酯, 包括非丙烯酸CC双键,并且具有小于或等于20的K值。热熔粘合剂包括光引发剂,其可以不附着于聚(甲基)丙烯酸酯的添加剂形式存在和/或不附着于聚 低级(甲基)丙烯酸酯可以通过共聚合引入聚(甲基)丙烯酸酯中,和/或可以连接到低聚(甲基)丙烯酸酯上。 热熔粘合剂可用于生产胶带。