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公开(公告)号：US07151065B2
公开(公告)日：2006-12-19
申请号：US10622834
申请日：2003-07-21
申请人： Scott V. Thomsen , Richard Hulme , Leonid Landa , Ksenia A. Landa
发明人： Scott V. Thomsen , Richard Hulme , Leonid Landa , Ksenia A. Landa
IPC分类号： C03C3/087
CPC分类号： C03C4/02 , C03C3/095 , C03C4/082 , C03C4/085 , Y10S501/904 , Y10S501/905
摘要： A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cerium, cobalt and selenium is provided. The glass allows high visible transmission, and satisfactory IR and UV absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3): 0.25 to 0.70% cerium oxide: 0.01 to 1.0% selenium:0.0001 to 0.05% cobalt oxide:0.0001 to 0.05% titanium oxide: 0 to 1.0% glass redox:>=0.30.
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公开(公告)号：US07144837B2
公开(公告)日：2006-12-05
申请号：US10336859
申请日：2003-01-06
申请人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
发明人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
摘要： A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably
摘要翻译： 提供高透光率相当清晰/中性的有色玻璃组合物。 为了实现非常氧化的条件（即，显着降低所得到的氧化还原反应），向玻璃批料中加入氧化铈（例如，CeO 2/2）等氧化剂 玻璃）。 作为批料中使用的氧化剂的结果，铁被氧化成非常低的FeO（亚铁态）含量。 例如，这可能导致玻璃氧化还原值不大于0.12（更优选<= 0.10;甚至更优选<= 0.08，最优选<= 0.05）和％FeO（即含铁含量）的玻璃， 为0.0001〜0.05％。 在某些示例性实施例中，为了补偿黄色或黄绿色，可以在玻璃中提供少量的钴（Co），以使其能够实现更中立的颜色。
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公开(公告)号：US06610622B1
公开(公告)日：2003-08-26
申请号：US10056051
申请日：2002-01-28
申请人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
发明人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
IPC分类号： C03C3087
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe2O3): 0.01 to 0.30% erbium oxide (e.g., Er2O3): 0.01 to 0.30% cerium oxide (e.g., CeO2): 0.005 to 0.30%. Optionally, neodymium oxide (e.g., Nd2O3) may also be provided in the glass in certain example embodiments. In other embodiments, the cerium oxide may be replaced with or supplemented by NaNO3 or some other nitrate(s) as an oxidizer.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在根据本发明实施例制造玻璃的某些示例性实施方案中，玻璃批料可以包括基础玻璃（例如，钠钙硅胶基础玻璃），并且还包括按重量百分比：任选地，氧化钕（例如，Nd 2 O 3）可以 也可以在某些示例性实施例中在玻璃中提供。 在其它实施方案中，氧化铈可以被NaNO 3或一些其它硝酸盐替代或补充，作为氧化剂。
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公开(公告)号：US07858545B2
公开(公告)日：2010-12-28
申请号：US12656582
申请日：2010-02-04
申请人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
发明人： Ksenia A. Landa , Leonid Landa , Richard Hulme , Scott V. Thomsen
IPC分类号： C03C3/087
摘要： A high transmittance fairly clear/neutral colored glass composition is provided. An oxidizing agent(s) such as cerium oxide (e.g., CeO2) or the like is added to the glass batch in order to realize very oxidized conditions (i.e., to significantly lower the redox of the resulting glass). As a result of the oxidizing agent(s) used in the batch, the iron is oxidized to a very low FeO (ferrous state) content. For example, this may result in a glass having a glass redox value of no greater than 0.12 (more preferably
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公开(公告)号：US07601660B2
公开(公告)日：2009-10-13
申请号：US10800015
申请日：2004-03-15
申请人： Don Tullman , Scott V. Thomsen , Richard Hulme , Leonid Landa , Ksenia A. Landa
发明人： Don Tullman , Scott V. Thomsen , Richard Hulme , Leonid Landa , Ksenia A. Landa
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage, from 0.01 to 0.30% total iron (expressed as Fe2O3). The glass may be made using a batch redox of at least +7.5.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施方案中，玻璃可以包括基础玻璃（例如钠钙二氧化硅基底玻璃），并且还包括按重量百分比计，总铁含量为0.01至0.30％（以Fe 2 O 3表示）。 玻璃可以使用至少+7.5的批式氧化还原。
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公开(公告)号：US07037869B2
公开(公告)日：2006-05-02
申请号：US10785716
申请日：2004-02-25
申请人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
发明人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
IPC分类号： C03C3/095
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe2O3):0.01 to 0.30% erbium oxide (e.g., Er2O3):0.01 to 0.30%.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，玻璃可以包括基础玻璃（例如，钠钙石灰基底玻璃），并且还包括重量百分比：
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0.01〜0.30％ 0.01〜0.30％。 -
公开(公告)号：US07030047B2
公开(公告)日：2006-04-18
申请号：US10810897
申请日：2004-03-29
申请人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
发明人： Leonid Landa , Ksenia A. Landa , Scott V. Thomsen , Richard Hulme
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments of making glass according to examples of the invention, the glass batch may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe2O3):0.01 to 0.30% erbium oxide (e.g., Er2O3):0.01 to 0.30% cerium oxide (e.g., CeO2): 0.005 to 0.30%. Optionally, neodymium oxide (e.g., Nd2O3) may also be provided in the glass in certain example embodiments. In other embodiments, the cerium oxide may be replaced with or supplemented by NaNO3 or some other nitrate(s) as an oxidizer.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在根据本发明的实施例制造玻璃的某些示例性实施方案中，玻璃批料可以包括基础玻璃（例如，钠钙硅胶基础玻璃），并且还包括按重量百分比：
总铁（表示为Fe 2 3 ）： 0.01〜0.30 ％ 氧化铒（例如，呃呃O O 3 3）： 0.01〜0.30％ 氧化铈（例如CeO 2 2）： 0.005〜0.30％ 。 -
公开(公告)号：US07700869B2
公开(公告)日：2010-04-20
申请号：US11049292
申请日：2005-02-03
申请人： Scott V. Thomsen , Ksenia A. Landa , Leonid Landa , Richard Hulme
发明人： Scott V. Thomsen , Ksenia A. Landa , Leonid Landa , Richard Hulme
IPC分类号： H01L25/00 , H01L31/042 , C03C3/00
CPC分类号： H01L31/0392 , C03C3/087 , C03C3/095 , C03C2204/08 , H01L31/02366 , Y02E10/50
摘要： A patterned glass substrate is provided for use in a solar cell. The glass substrate is both patterned on at least one surface thereof and has a low iron content. The combination of low iron content, optional oxidizing agent, and the patterning of the glass substrate results in a substrate with high visible transmission and excellent light refracting characteristics.
摘要翻译： 提供了用于太阳能电池的图案化玻璃基板。 玻璃基板在其至少一个表面上都被图案化，并且具有低的铁含量。 低铁含量，任选的氧化剂和玻璃基板的图案化的组合导致具有高可见透射率和优异的光折射特性的基板。
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公开(公告)号：US07560403B2
公开(公告)日：2009-07-14
申请号：US11581779
申请日：2006-10-17
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，玻璃包括与设计成提供中性和高透射率的铒（Er，包括其氧化物）结合的少量铁。 在某些示例性实施方案中，增加了玻璃组合物中的SO 3的量，以提供增加的可见透射率，而不牺牲中性色。 在某些示例中，玻璃可以任选地包括少量的钴（Co，包括其氧化物）。
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公开(公告)号：US20080090718A1
公开(公告)日：2008-04-17
申请号：US11581779
申请日：2006-10-17
IPC分类号： C03C3/095
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass includes a low amount of iron coupled with erbium (Er, including an oxide thereof) designed to provide a neutral color and high transmittance. In certain example embodiments, the amount of SO3 in the glass composition is increased in order to provide increased visible transmission, without sacrificing neutral color. The glass may optionally include a small amount of cobalt (Co, including an oxide thereof) in certain example instances.
摘要翻译： 提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。 在某些示例性实施例中，玻璃包括与设计成提供中性和高透射率的铒（Er，包括其氧化物）结合的少量铁。 在某些示例性实施方案中，玻璃组合物中SO 3的量增加，以提供增加的可见透射率，而不牺牲中性色。 在某些示例中，玻璃可以任选地包括少量的钴（Co，包括其氧化物）。
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