公开(公告)号：US09815993B2

公开(公告)日：2017-11-14

申请号：US15233455

申请日：2016-08-10

申请人： Shizuka Kohzuki ,  Mie Yoshino ,  Manabu Arita ,  Hiroki Kobayashi

发明人： Shizuka Kohzuki ,  Mie Yoshino ,  Manabu Arita ,  Hiroki Kobayashi

IPC分类号： C09D11/101 ,  B41M5/50 ,  B41J2/01 ,  C09D11/30 ,  C09D11/107 ,  C09D11/322

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322

摘要： An active energy ray curable composition including a polymerizable compound is provided. When a three-layer cured product of the active energy ray composition is obtained by a specific procedure, the three-layer cured product has (1) a stretchability of 1.1 or more and (2) a glass transition temperature of 50° C. or more. The stretchability is defined by a ratio L2/L1, wherein L1 represents a first length of the cured product before a tensile test and L2 represents a second length of the cured product after the tensile test. The tensile test includes stretching the cured product along with the substrate with a tensile tester at a stretching speed of 20 mm/min and a temperature of 180° C.

公开(公告)号：US09187658B2

公开(公告)日：2015-11-17

申请号：US14310452

申请日：2014-06-20

申请人： Shizuka Kohzuki ,  Takao Hiraoka

发明人： Shizuka Kohzuki ,  Takao Hiraoka

IPC分类号： C08F2/50 ,  C08F2/46 ,  C08G61/04 ,  C09D11/101 ,  C09D11/30 ,  C09D11/38

CPC分类号： C09D11/101 ,  C09D11/30 ,  C09D11/38

摘要： To provide a photopolymerizable inkjet ink including: diethylene glycol dimethacrylate; caprolactone-modified dipentaerythritol hexaacrylate; and a photopolymerization initiator represented by the following general formula (1): where X1 is represented by the following general formula (1-1), and X2 is represented by the following general formula (1-2): where R1 to R4 are each independently a C1-C6 alkyl group, and R1 and R2 may be linked to form a ring, and R3 and R4 may be linked to form a ring; Z1 and Z2 is —NR5R6 or OR7; R5 and R6 are each independently a C1-C6 alkyl group, and R5 and R6 may be linked to form a ring; and R7 is a hydrogen atom, a methyl group, or a trimethylsilyl group.

摘要翻译： 提供一种可光聚合喷墨油墨，其包含：二甘醇二甲基丙烯酸酯; 己内酯改性二季戊四醇六丙烯酸酯; 和由以下通式（1）表示的光聚合引发剂：其中X1由以下通式（1-1）表示，X2由以下通式（1-2）表示：其中R1至R4各自为 独立地为C1-C6烷基，R1和R2可以连接形成环，R3和R4可以连接形成环; Z 1和Z 2是-NR 5 R 6或OR 7; R5和R6各自独立地为C1-C6烷基，R5和R6可以连接形成环; 并且R 7是氢原子，甲基或三甲基甲硅烷基。

公开(公告)号：US09051481B2

公开(公告)日：2015-06-09

申请号：US14474781

申请日：2014-09-02

申请人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

发明人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

IPC分类号： G01D11/00 ,  C09D11/101 ,  B41J2/01 ,  C09D11/30

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322 ,  C09D11/324

摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2): (1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.

摘要翻译： 一种活性能量射线固化型油墨，其含有：含有Tg为90℃以上的均聚物的单官能性聚合性单体的聚合性化合物，其中，将通过在平均厚度为10μm的涂膜上形成的固化物 使用该油墨的聚碳酸酯基板15秒钟后，向涂膜施加光量为1,500mJ / cm 2的活性能量射线，使其固化，满足以下（1）和（2）：（1）固化的 当拉伸试验机以拉伸速度为20mm / min，温度为180℃，伸长率=（拉伸试验后的长度）/（拉伸试验机）拉伸固化产物时，由下式表示的产物为2以上， 拉伸试验前的长度）（2）根据JIS K5400的横切试验测定的基材与固化物的粘合性为70以上。

公开(公告)号：US20150077481A1

公开(公告)日：2015-03-19

申请号：US14474781

申请日：2014-09-02

申请人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

发明人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

IPC分类号： C09D11/101 ,  C09D11/30 ,  B41J2/01

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322 ,  C09D11/324

摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2): (1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.

摘要翻译： 一种活性能量射线固化型油墨，其含有：含有Tg为90℃以上的均聚物的单官能性聚合性单体的聚合性化合物，其中，将通过在平均厚度为10μm的涂膜上形成的固化物 使用该油墨的聚碳酸酯基板15秒钟后，向涂膜施加光量为1,500mJ / cm 2的活性能量射线，使其固化，满足以下（1）和（2）：（1）固化的 当拉伸试验机以拉伸速度为20mm / min，温度为180℃，伸长率=（拉伸试验后的长度）/（拉伸试验机）拉伸固化产物时，由下式表示的产物为2以上， 拉伸试验前的长度）（2）根据JIS K5400的横切试验测定的基材与固化物的粘合性为70以上。

公开(公告)号：US10138387B2

公开(公告)日：2018-11-27

申请号：US15615570

申请日：2017-06-06

申请人： Shizuka Kohzuki ,  Teruki Kusahara ,  Hiroki Nakane

发明人： Shizuka Kohzuki ,  Teruki Kusahara ,  Hiroki Nakane

IPC分类号： C09D11/10 ,  C09D11/30 ,  C09D11/101 ,  C09D11/322

摘要： An active energy ray image forming apparatus containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond. An active energy ray image forming apparatus, containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond, where the heating mechanism is heated to 60° C. when ink is discharged.

公开(公告)号：US10100211B2

公开(公告)日：2018-10-16

申请号：US15202858

申请日：2016-07-06

申请人： Mie Yoshino ,  Manabu Arita ,  Shizuka Kohzuki ,  Hiroki Kobayashi

发明人： Mie Yoshino ,  Manabu Arita ,  Shizuka Kohzuki ,  Hiroki Kobayashi

IPC分类号： B41J11/00 ,  C09D11/30 ,  C09D11/101 ,  C09D11/107 ,  C09D11/324 ,  B33Y70/00 ,  C08F222/14 ,  C08F222/38 ,  B33Y10/00 ,  B33Y30/00

摘要： In accordance with sonic embodiments of the present invention, an active energy ray curable composition including a polymerizable compound composition is provided. When the active energy ray curable composition is formed into a film having an average thickness of 10 μm on a substrate and, after a lapse of 15 seconds, the film is irradiated with an active energy ray having a light quantity of 1,500 mJ/cm2 to become a cured product, the cured product satisfies the following conditions (1) and (2): (1) when the substrate is a polypropylene substrate, the cured product has a glass transition temperature of 60° C. or more; and (2) when the substrate is a polycarbonate substrate, an adhesion between the polycarbonate substrate and the cured product is 70 or more, the adhesion being measured according to a cross-cut adhesion test defined in Japanese industrial Standards K5400.

公开(公告)号：US09695325B2

公开(公告)日：2017-07-04

申请号：US14853141

申请日：2015-09-14

申请人： Shizuka Kohzuki ,  Teruki Kusahara ,  Hiroki Nakane

发明人： Shizuka Kohzuki ,  Teruki Kusahara ,  Hiroki Nakane

IPC分类号： C09D11/10 ,  C09D11/101 ,  C09D11/322

CPC分类号： C09D11/10 ,  C09D11/101 ,  C09D11/322

摘要： An active energy ray curable composition includes a non-polymerizable resin; and polymerizable compounds comprising a mono-functional monomer having a single polymerizable unsaturated ethylene double bond, wherein the following relations are satisfied: ΔTg=|Tgp−Tgm}≧19 degrees C., where Tgp represents a glass transition temperature of the non-polymerizable resin and Tgm represents a glass transition temperature of a homopolymer of the mono-functional monomer, TgH≧10 degrees C., where TgH represents the higher of Tgp and Tgm, and TgL≦40 degrees C., where TgL represents the lower of Tgp and Tgm.

公开(公告)号：US09303173B2

公开(公告)日：2016-04-05

申请号：US14704205

申请日：2015-05-05

申请人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

发明人： Mie Yoshino ,  Takao Hiraoka ,  Shizuka Kohzuki

IPC分类号： G01D11/00 ,  B41J2/01 ,  C09D11/101 ,  C09D11/30

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322 ,  C09D11/324

摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2):(1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.