摘要:
A nonaqueous lithium secondary battery includes a positive electrode and a negative electrode capable of intercalating and releasing lithium ions and a separator. The negative electrode includes a collector and a negative electrode mixture layer formed on the collector. The negative electrode mixture layer includes at least a negative electrode active material and a binder. Nonconductive particles are buried in a top layer of the negative electrode mixture layer. The nonconductive particles and the negative electrode active material exist as a mixture in the top layer with a depth ranging from 1 to 20 μm. A volume ratio of nonconductive particles having a diameter equal to or less than 20 μm to a total volume of all the nonconductive particles and the negative electrode active material existing in the top layer of the negative electrode mixture layer ranges from 20 to 80%.
摘要:
A long-life electric energy storage device with superior high-input/output load resistance includes a cathode including a region having a faradic reaction mechanism and a region having a non-faradic reaction mechanism, and an anode including a region having a faradic reaction mechanism. When carbon material contained in the anode is represented by a diffraction line according to X-ray diffraction method, mainly the (001) plane is substantially detected.
摘要:
To provide a lithium secondary battery which suppresses a decrease in the charge and discharge efficiency during a battery storage test and which is excellent in maintaining the battery capacity after the storage test. There are disclosed a nonaqueous lithium battery, comprising: a positive electrode active material comprising a lithium-containing oxide capable of inserting and detaching lithium ions; a negative electrode active material comprising a carbon material capable of inserting and detaching lithium ions; and an electrolytic solution containing a lithium ion, wherein the surface of the negative electrode active material after initializing charging is coated with a compound derived from vinylene carbonate, and wherein a weight power density of the lithium battery is no less than 100 Wh/kg, and a method of producing a nonaqueous lithium battery comprising a step of sealing a positive electrode active material, a negative electrode active material, and a nonaqueous electrolytic solution using a sealed container, wherein a predetermined amount of vinylene carbonate is added into the nonaqueous electrolytic solution, and the initializing charging is carried out to form a coating on the surface of the negative electrode active material, the coating being derived from the vinylene carbonate.
摘要:
A nonaqueous lithium secondary battery includes a positive electrode and a negative electrode capable of intercalating and releasing lithium ions and a separator. The negative electrode includes a collector and a negative electrode mixture layer formed on the collector. The negative electrode mixture layer includes at least a negative electrode active material and a binder. Nonconductive particles are buried in a top layer of the negative electrode mixture layer. The nonconductive particles and the negative electrode active material exist as a mixture in the top layer with a depth ranging from 1 to 20 μm. A volume ratio of nonconductive particles having a diameter equal to or less than 20 μm to a total volume of all the nonconductive particles and the negative electrode active material existing in the top layer of the negative electrode mixture layer ranges from 20 to 80%.
摘要:
An object of the present invention is to provide an energy device excellent in input/output characteristics at a low temperature and various applications using the same. The present invention consists in an energy device comprising a positive electrode having a region where a faradic reaction occurs, and a negative electrode having a region where a faradic reaction occurs, wherein at least one of the positive and negative electrodes has a region where a faradic reaction having a reaction rate higher than that of the faradic reaction occurs or a region where a non-faradic reaction occurs.
摘要:
An object of the present invention is to provide an energy storage device excellent in input/output characteristics at low temperatures, a module thereof and a vehicle using the module. The present invention provides an energy storage device comprising: a positive electrode having a region where a reaction accompanied by charge exchange occurs; a negative electrode having a region where a reaction accompanied by charge exchange occurs; a separator electrically separating the positive and negative electrodes and allowing mobile ions to pass therethrough; an electrolytic solution having an aprotic nonaqueous solvent comprising the mobile ions; and a region in at least one of the positive and negative electrodes where a charge adsorbing/desorbing reaction occurs.
摘要:
In a charging/discharging unit provided with: a lithium secondary battery, a voltage detecting sensor for detecting a voltage and a current detecting sensor; the charging/discharging control unit is further provided with a controller, and a discharging element for performing a constant voltage discharging operation of 3 V. A voltage, V0, of the battery when a discharging operation is terminated (t=0) is measured by the voltage detecting sensor. If V0≦3.6 V, within a rest time during which the battery is not charged/discharged until a next charging operation, a voltage, V1, of the battery when a time, t1, has elapsed is measured by the voltage detecting sensor. If this voltage charge is in a range of V1−V0≧0.2 V, then the constant voltage discharging operation of 3 V is carried out for a time duration longer than or equal to 1 hour.
摘要:
An energy storage device of excellent input/output characteristics and having high density of stored energy, the device having a cathode comprising a material conducting faradic reaction and a material conducting non-faradic reaction, and an anode comprising a material conducting faradic reaction, in which the faradic reaction is desorption/intercalation reaction of lithium ions, higher input/output characteristics being obtainable by providing a mix layer comprising a material conducting faradic reaction on a cathode collector and providing a material layer conducting non-faradic reaction further to the surface layer thereof.
摘要:
An energy storage device comprising a negative electrode plate having a negative electrode active material layer of a carbonaceous composite material formed on a negative electrode collector, a positive electrode plate having a positive electrode active material layer capable of inserting and releasing lithium ions and a non-faradic reaction layer capable of accumulating and releasing electric charges upon physical adsorption-desorption of ions on the surface layer of the positive electrode active material layer and an insulator layer for electrically insulating the positive electrode plate from the negative electrode plate, the insulator layer being capable of permeating only mobile ions. The carbonaceous composite material comprises particles of graphite and/or amorphous carbon and activated charcoal, and the particles of the graphite and/or amorphous carbon and particles of the activated charcoal are united.
摘要:
To acquire a high-output electrochemical energy storage device the range of operating voltage of which is large, a positive electrode provided with a positive electrode collector and positive electrode active material which is held by the positive electrode collector and can occlude/emit a metal ion, a negative electrode provided with a negative electrode collector and negative electrode active material which is held by the negative electrode collector and can occlude/emit the metal ion, a minutely porous separator held between the positive electrode and the negative electrode and an organic electrolyte are provided, and a range of operating voltage is equivalent to a range from below 2 V to 4 V or more.