-
11.发明授权Process for the production of a catalyst component for use in the polymerization of alpha olefins 失效用于生产用于α-烯烃聚合的催化剂组分的方法
公开(公告)号：US4062804A
公开(公告)日：1977-12-13
申请号：US703562
申请日：1976-07-08
申请人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
摘要： The invention relates to a method for preparing a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity in narrow particle size distribution, which comprises:1. reducing TiCl.sub.4 by a mixture of diethylaluminum chloride (DEAC) and ethylaluminum dichloride (EADC), thereby forming a reduced solid (TiCl.sub.3),2. removing the aluminum compound from the reduced solid;3. treating the said reduced solid with a mixture or complex of TiCl.sub.4 and diisoamylether (IAE), and4. separating the solid catalyst from the solution.Preferably step 2 is performed by washing with a complexing agent for the aluminum compound.
摘要翻译： 本发明涉及一种制备聚合丙烯的催化剂组合物的方法，该催化剂组合物具有高活性并产生窄的粒度分布具有高立构规整性的聚丙烯，其包括：
-
公开(公告)号：US4711940A
公开(公告)日：1987-12-08
申请号：US925843
申请日：1986-10-29
CPC分类号： C08F10/00
摘要： A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
-
13.发明授权
公开(公告)号：US4348507A
公开(公告)日：1982-09-07
申请号：US173214
申请日：1980-07-28
申请人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
CPC分类号： C08F10/00 , Y10S526/906
摘要： A supported titanium catalyst is produced by cogrinding, in combination, a magnesium halide, tetravalent titanium halide, organic acid ester, and an organic halogen compound. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.
-
14.发明授权Process for the stereoregular polymerization of .alpha.-olefins in the presence of a supported titanium catalyst 失效在负载型钛催化剂存在下α-烯烃的立构规整聚合方法
公开(公告)号：US4314046A
公开(公告)日：1982-02-02
申请号：US172797
申请日：1980-07-28
申请人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
CPC分类号： C08F10/00 , Y10S526/903 , Y10S526/906
摘要： A supported titanium catalyst, adaptable for use in the stereoregular polymerization of .alpha.-olefins, is produced by treating a supported titanium-containing solid, obtained by cogrinding a magnesium halide, tetravalent titanium halide and organic acid ester, with a hydrocarbon, organo halogen compound or mixture thereof with heating. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.
-
公开(公告)号：US4240928A
公开(公告)日：1980-12-23
申请号：US927803
申请日：1978-07-25
申请人： Hiroshi Ueno , Naomi Inaba , Tukuo Makishima , Koh Watanabe , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tukuo Makishima , Koh Watanabe , Shozo Wada
摘要： A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an alkylaluminum halide composition at low temperature and then treating the resulting reduced solids product by contacting it at elevated temperature with a dialkyl ether having alkyl groups of 4 to 5 carbon atoms and with hexachloroethane, the proportion of dialkyl ether being at least 1 mol per 1 mol of hexachloroethane and the proportion of hexachloroethane being at least greater than about 0.5 mol per 1 gram atom of titanium in the reduced solids product. The resulting titanium trichloride complex composition, when employed as co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.
摘要翻译： 通过在低温下用烷基卤化铝组合物还原四氯化钛，然后在升高的温度下将其与具有4至5个碳原子的烷基的二烷基醚和六氯乙烷接触来处理所得的还原固体产物，从而生产三氯化钛催化络合物， 每1摩尔六氯乙烷中二烷基醚的比例至少为1摩尔，并且六氯乙烷的比例在还原固体产物中至少大于约0.5摩尔/克原子钛。 所得到的三氯化钛复合物组合物当用作α-烯烃聚合中的齐格勒型催化剂的有机金属化合物作为助催化剂时，导致均匀的聚合物颗粒具有出乎预料的高聚合活性和高立体规则聚合物产率。
-
16.发明授权Process for the production of a catalyst component for use in the polymerization of .alpha.-olefins 失效制备用于聚合{60-烯烃的催化剂组分的方法
公开(公告)号：US4127505A
公开(公告)日：1978-11-28
申请号：US744236
申请日：1976-11-23
申请人： Hiroshi Ueno , Naomi Inaba , Tokyo Makishima , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tokyo Makishima , Shozo Wada
CPC分类号： C08F10/00
摘要： The invention relates to a process for the production of a catalyst component for use in the polymerization of .alpha.-olefins, which comprises reacting titanium tetrachloride with a dialkylaluminum monohalide and monoalkylaluminum dihalide, said dialkylaluminum monohalide being in a proportion of at least equimolar to said titanium tetrachloride, to thus obtain a violet reduced solid, then removing aluminum compounds contained in said reduced solid and further activating with a mixture or complex of titanium tetrachloride and a dialkyl ether of the general formula ROR' wherein R and R' are the same or different and are (a) alkyl groups having 1-4 carbon atoms, (b) normal alkyl groups having 5 carbon atoms or (c) alkyl groups having 6-20 carbon atoms and to a catalyst component prepared by the process of the invention.
摘要翻译： 本发明涉及用于生产用于α-烯烃聚合的催化剂组分的方法，该方法包括使四氯化钛与二烷基铝一卤化物和一烷基铝二卤化物反应，所述二烷基铝一卤化物与所述钛的至少等摩尔比例 从而获得紫色还原固体，然后除去所述还原固体中所含的铝化合物，并进一步用四氯化钛和通式ROR'的二烷基醚的混合物或络合物活化，其中R和R'相同或不同 并且是（a）具有1-4个碳原子的烷基，（b）具有5个碳原子的正烷基或（c）具有6-20个碳原子的烷基和通过本发明的方法制备的催化剂组分。
-
公开(公告)号：US4590325A
公开(公告)日：1986-05-20
申请号：US765765
申请日：1985-08-15
CPC分类号： C08F10/00
摘要： A titanium halide containing catalyst component for polymerization of olefins which is prepared by reacting a magnesium hydrocarbyloxide with a silicon compound having a hydrogen-silicon bond, contacting the reaction product with an electron donor compound, contacting the resulting contact product two or more times with a titanium halide and between one of the multiple titanium halide contacts, contacting the titanium halide contacted solid with a halogenated hydrocarbon.
-
公开(公告)号：US4552858A
公开(公告)日：1985-11-12
申请号：US642022
申请日：1984-08-20
CPC分类号： C08F10/00
摘要： A titanium halide containing catalyst component for polymerization of olefins which is prepared by reacting a magnesium hydrocarbyloxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with an electron donor compound, contacting the resulting contact product two or more times with a titanium halide and between one of the multiple titanium halide contacts, contacting the titanium halide contacted solid with a halide of an element selected from the group consisting of elements of Groups IIIa, IVa, and Va of the Periodic Table of elements.
摘要翻译： 一种含卤化钛的烯烃聚合催化剂组分，其通过镁烃氧化物与具有至少一个氢 - 硅键的硅化合物反应制备，使反应产物与电子给体化合物接触，使所得的接触产物接触两次或更多次 与钛卤化物和多个卤化钛触点之间的一个之间，使卤化钛接触固体与选自元素周期表第IIIa，IVa和Va族元素的元素的卤化物接触。
-
19.发明授权Catalyst component for polymerization of alpha-olefins and method of using it 失效用于α-烯烃聚合的催化剂组分及其使用方法
公开(公告)号：US4335015A
公开(公告)日：1982-06-15
申请号：US161978
申请日：1980-06-23
申请人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba
发明人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba
CPC分类号： C08F10/00
摘要： A supported titanium catalyst, adaptable for use in the polymerization of alpha-olefins, is produced by treating a supported titanium-containing solid obtained by co-pulverization of a magnesium halide, a tetravalent titanium halide which may also comprise an electron donor compound and/or a halogen compound with an organohalogen compound. The component is thereafter treated with an organoaluminum compound and an electron donor compound. The resulting supported titanium catalyst, one employed as a titanium component with an organoaluminum catalyst component results in a catalyst system useful for the polymerization of alpha-olefins and particularly alpha-olefins.
摘要翻译： 适用于α-烯烃聚合的载体钛催化剂是通过处理通过卤化镁共混粉碎得到的负载的含钛固体，还可以包含电子给体化合物的四价卤化钛和/ 或具有有机卤素化合物的卤素化合物。 然后用有机铝化合物和电子给体化合物处理组分。 所得到的负载型钛催化剂，一种用作钛组分的有机铝催化剂组分，形成了可用于α-烯烃，特别是α-烯烃聚合的催化剂体系。
-
20.发明授权
公开(公告)号：US4253984A
公开(公告)日：1981-03-03
申请号：US59791
申请日：1979-07-23
申请人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba , Makoto Yoda , Shozo Wada
CPC分类号： C08F10/00 , Y10S526/903 , Y10S526/904 , Y10S526/906
摘要： A supported titanium catalyst component is produced by cogrinding in the presence of an ethylenically unsaturated hydrocarbon an organo aluminum catalyst component with a supported titanium (IV) halide on a magnesium halide until the intensity of the 14.8.degree. and 30.2.degree. x-ray diffraction peak of magnesium halide are reduced in intensity. The resulting supported titanium halide catalyst component, when employed with an organo aluminum catalyst component to form a catalyst system is highly useful for the stereoregular polymerization of .alpha.- olefins as well as the copolymerization of .alpha.-olefins.
摘要翻译： 负载的钛催化剂组分通过在烯属不饱和烃和有机铝催化剂组分与负载的卤化钛（IV）卤化物的存在下共研磨而产生，直到强度为14.8°和30.2°X射线衍射峰 卤化镁的强度降低。 当与有机铝催化剂组分一起使用以形成催化剂体系时，得到的负载型卤化钛催化剂组分对于α-烯烃的立构规整聚合以及α-烯烃的共聚是非常有用的。
-
-
-
-
-
-
-
-
-
搜索结果
38 条记录 (耗时 0.026 秒)
