摘要:
A method for producing a non-aqueous electrolyte secondary battery comprising the steps of: (i) mixing a positive electrode active material, a first binder A and a dispersion medium to prepare a paste A, the active material comprising a lithium-containing transition metal oxide; (ii) mixing a conductive agent, a second binder B and a dispersion medium to prepare a paste B, the conductive agent comprising carbon black; (iii) mixing the paste A and the paste B to prepare a positive electrode material paste C; (iv) applying the positive electrode material paste C onto a positive electrode core member and rolling and drying the resultant member to prepare a positive electrode; and (v) fabricating a battery using the positive electrode, a negative electrode and a non-aqueous electrolyte, wherein contact angle θA between the non-aqueous electrolyte and the binder A and contact angle θB between the non-aqueous electrolyte and the binder B satisfy the formula (1): θB−θA≧15°.
摘要:
A non-aqueous electrolyte secondary battery comprises: a positive electrode sheet comprising a positive electrode mixture containing a lithium-containing transition metal oxide as an active material and a particulate binder; a negative electrode sheet comprising a negative electrode mixture containing a carbon material; a separator interposed between the positive electrode sheet and the negative electrode sheet; and a non-aqueous electrolyte containing a lithium salt, wherein the positive electrode sheet and the negative electrode sheet are wound with the separator interposed therebetween to form an electrode assembly, and the positive electrode mixture has an active material density of 3.0 to 4.0 g/ml. The battery has a long life, high energy density and high output.
摘要:
Disclosed is a positive electrode for a non-aqueous electrolyte secondary battery, comprising: a positive electrode mixture layer; and a positive electrode current collector which carries the positive electrode mixture layer, with the positive electrode mixture layer comprising: at least one positive electrode active material; at least one conductive agent; at least one binder; and at least one thickening agent, and the thickening agent comprising a polymer containing at least one acrylonitrile unit and at least one —(CH2)n— structure portion where 6≦n.
摘要:
A non-aqueous electrolyte battery is provided, which exhibits good high-rate discharge characteristics and low-temperature characteristics and ensures high safety when the negative electrode contains 0.6 to 1.7 parts by weight of a particulate modified styrene-butadiene rubber as a binder and 0.7 to 1.2 parts by weight of a thickening agent so that the total amount of the binder and thickening agent is 1.3 to 2.4 parts by weight per 100 parts by weight of a carbon material as an active material, and the concentration of LiPF6 in the non-aqueous electrolyte is 0.6 to 1.05 mole/liter. The surface area of the active material effectively contributable to charging and discharging reaction is sufficient when the surface area of the carbon material per 1 g of the binder contained in the negative electrode is 300 to 600 m2.
摘要:
A non-aqueous electrolyte battery is provided, which exhibits good high-rate discharge characteristics and low-temperature characteristics and ensures high safety when the negative electrode contains 0.6 to 1.7 parts by weight of a particulate modified styrene-butadiene rubber as a binder and 0.7 to 1.2 parts by weight of a thickening agent so that the total amount of the binder and thickening agent is 1.3 to 2.4 parts by weight per 100 parts by weight of a carbon material as an active material, and the concentration of LiPF6 in the non-aqueous electrolyte is 0.6 to 1.05 mole/liter. The surface area of the active material effectively contributable to charging and discharging reaction is sufficient when the surface area of the carbon material per 1 g of the binder contained in the negative electrode is 300 to 600 m2.
摘要:
A non-aqueous electrolyte battery is provided, which exhibits good high-rate discharge characteristics and low-temperature characteristics and ensures high safety when the negative electrode contains 0.6 to 1.7 parts by weight of a particulate modified styrene-butadiene rubber as a binder and 0.7 to 1.2 parts by weight of a thickening agent so that the total amount of the binder and thickening agent is 1.3 to 2.4 parts by weight per 100 parts by weight of a carbon material as an active material, and the concentration of LiPF6 in the non-aqueous electrolyte is 0.6 to 1.05 mole/liter. The surface area of the active material effectively contributable to charging and discharging reaction is sufficient when the surface area of the carbon material per 1 g of the binder contained in the negative electrode is 300 to 600 m2.
摘要:
A method for producing a non-aqueous electrolyte secondary battery comprising the steps of: (i) mixing a positive electrode active material, a first binder A and a dispersion medium to prepare a paste A, the active material comprising a lithium-containing transition metal oxide; (ii) mixing a conductive agent, a second binder B and a dispersion medium to prepare a paste B, the conductive agent comprising carbon black; (iii) mixing the paste A and the paste B to prepare a positive electrode material paste C; (iv) applying the positive electrode material paste C onto a positive electrode core member and rolling and drying the resultant member to prepare a positive electrode; and (v) fabricating a battery using the positive electrode, a negative electrode and a non-aqueous electrolyte, wherein contact angle θA between the non-aqueous electrolyte and the binder A and contact angle θB between the non-aqueous electrolyte and the binder B satisfy the formula (1): θB−θA≧15°.
摘要:
A method for manufacturing a positive electrode plate for a non-aqueous secondary battery including: preparing an active material A, a conductive material B, a binder C, a thickener D, and a liquid component E, the thickener D being in a powder state, the conductive material B including a carbon material, the thickener D including a water-soluble polymer, and the liquid component E including water; preparing a slurry including the component E and an electrode material mixture, the material mixture including the active material A, the conductive material B, the binder C, and the thickener D; and applying the slurry on a current collector. In preparing the slurry, the thickener D in a powder state, the active material A and the conductive material B are kneaded together with the liquid component E, and then the primary kneaded matter, the binder C, and an additional liquid component are kneaded.
摘要:
A method for manufacturing a positive electrode plate for a non-aqueous secondary battery including: preparing an active material A, a conductive material B, a binder C, a thickener D, and a liquid component E, the thickener D being in a powder state, the conductive material B including a carbon material, the thickener D including a water-soluble polymer, and the liquid component E including water; preparing a slurry including the component E and an electrode material mixture, the material mixture including the active material A, the conductive material B, the binder C, and the thickener D; and applying the slurry on a current collector. In preparing the slurry, the thickener D in a powder state, the active material A and the conductive material B are kneaded together with the liquid component E, and then the primary kneaded matter, the binder C, and an additional liquid component are kneaded.
摘要:
An electrode in sheet form includes a current collector and an electrode mixture layer carried on each side thereof. The electrode is bent in the longitudinal direction thereof, to cause a large number of cracks in at least the electrode mixture layer to be positioned on the inner side of the current collector when wound, such that the cracks extend from the surface of the electrode mixture layer to the current collector in the direction intersecting with the longitudinal direction of the electrode. This bending process includes the steps of: bending the electrode at a curvature that is smaller than that of the winding core at least once; and thereafter bending the electrode at a curvature that is equal to or larger than that of the winding core. For example, this process is performed by arranging rollers such that their diameters decrease gradually and pressing the electrode against these rollers. This invention provides an electrode that does not break when wound to form an electrode assembly.