公开(公告)号：US5250713A

公开(公告)日：1993-10-05

申请号：US849187

申请日：1992-03-11

申请人： Hiroyuki Tamura ,  Yasuyuki Hattori ,  Kunizo Hashiba ,  Osamu Tabata ,  Kiyoshi Tsukada ,  Noriaki Fukuoka

发明人： Hiroyuki Tamura ,  Yasuyuki Hattori ,  Kunizo Hashiba ,  Osamu Tabata ,  Kiyoshi Tsukada ,  Noriaki Fukuoka

IPC分类号： C07C29/149 ,  C11B3/02 ,  C07C51/36

CPC分类号： C11B3/02 ,  C07C29/149

摘要： A process for producing desulfurized fats and oils or fatty acid esters is disclosed, which comprises treating fats and oils or fatty acid esters under hydrogen or a mixture of hydrogen and an inert gas atmosphere at a pressure of from 0.1 to 500 kg/cm.sup.2 in the absolute pressure at a temperature of from 100.degree. to 350.degree. C. in the presence of a catalyst of the following formula (I):Cu.multidot.X.sub.x .multidot.Y.sub.y .multidot.O.sub.z (I)wherein all symbols are defined in the disclosure. A process for producing an alcohols using desulfurized fats and oils or fatty acid esters is also disclosed. According to the process for producing an alcohol of the present invention, an alcohol of a high purity and good qualities can efficiently and effectively be produced.

摘要翻译： 公开了一种生产脱硫脂肪和油或脂肪酸酯的方法，其包括在氢气或氢气和惰性气体气氛下以0.1-500kg / cm 2的压力下在脂肪和油或脂肪酸酯中的处理 在下式（I）的催化剂存在下，在100℃至350℃的温度下的绝对压力：其中所有符号在本公开中定义的CuxXxxYyxOz（I）。 还公开了使用脱硫脂肪和油或脂肪酸酯制备醇的方法。 根据本发明的醇的制造方法，可以有效且高效地制造纯度高，品质好的醇。

公开(公告)号：US4846991A

公开(公告)日：1989-07-11

申请号：US152493

申请日：1988-02-05

申请人： Shigetoshi Suzue ,  Akio Kimura ,  Kiyoshi Tsukada ,  Kozo Noda ,  Hidekazu Ogino ,  Jun Kamegai

发明人： Shigetoshi Suzue ,  Akio Kimura ,  Kiyoshi Tsukada ,  Kozo Noda ,  Hidekazu Ogino ,  Jun Kamegai

IPC分类号： A61K8/30 ,  A61K8/00 ,  A61K8/37 ,  A61K8/40 ,  A61K8/41 ,  A61Q5/02 ,  A61Q5/12 ,  B01F17/00 ,  C07C69/52 ,  C07C69/68 ,  C11C3/00 ,  C11D1/00 ,  C11D1/04 ,  C11D3/20

CPC分类号： B01F17/0028 ,  A61K8/37 ,  A61Q5/02 ,  A61Q5/12 ,  B01F17/0021

摘要： Lactic acid esters of an .alpha.-branched fatty acid possessing an excellent hair conditioning effect are disclosed. Typical example is sodium 2-heptylundecanoyl acid lactate prepared by the reaction of 2-heptylundecanoic acid and lactic acid in the presence of an alkali such as sodium hydroxide. This compound gives a shampoo composition in conjunction with an anionic surface active agent, and a hair rinse composition when a quaternary ammonium salt is formulated. The compositions have excellent conditioning effects on use such as good slipperiness and hair curling formation or retention performance.

公开(公告)号：US5642140A

公开(公告)日：1997-06-24

申请号：US337813

申请日：1994-11-08

申请人： Yukio Sawano ,  Mamoru Mizunokura ,  Kiyoshi Tsukada

发明人： Yukio Sawano ,  Mamoru Mizunokura ,  Kiyoshi Tsukada

IPC分类号： B41J25/304 ,  B41J2/315 ,  B41J2/32 ,  B41J3/54 ,  G01D15/10 ,  G01D15/24 ,  G01D15/16

CPC分类号： G01D15/24 ,  B41J2/315 ,  B41J3/54 ,  G01D15/10

摘要： A thermally sensitive recording head comprising, a two bases 2 moving with its attitude being kept along a guide shaft 5, an attachment 3 rotatably provided on the base 2 so that the base 2 extends to an right angle direction with the guide shaft 5 and contacts on or separates from a platen 8, and a heating head 4, which is rotatably provided on the attachment 3, and on front surface of which a heating body train is formed in a right angle direction with the guide shaft 5 and extends in opposite direction to an extending direction of the attachment 3 from the tip end of the attachment 3 to contact on or separate from the platen 8, whereby the attachment 3 and the heating head 4 are pressed on the thermally Sensitive paper placed on back-side of the platen 8. In this arrangement, a clear image can be obtained without generation of irregularity of photographic density because the heating head 4 presses the thermally sensitive papers while being kept always in parallel with the platen 8.

摘要翻译： 一种热敏记录头，包括：沿着导向轴5保持其姿态移动的两个基座2;可旋转地设置在基座2上的安装件3，使得基座2与导向轴5成直角的方向延伸， 与压板8分开或分离;以及可旋转地设置在附件3上的加热头4，并且其前表面上与导向轴5成直角方向形成加热体列，并沿相反方向延伸 从连接件3的前端延伸到连接件3的延伸方向上，以与台板8接触或分离，从而将附件3和加热头4按压在放置在压盘背面的热敏纸上 在这种布置中，可以获得清晰的图像而不会产生不均匀的照相密度，因为加热头4在保持总是与压板8保持平行的同时按压热敏纸。

公开(公告)号：US5481048A

公开(公告)日：1996-01-02

申请号：US357173

申请日：1994-12-13

申请人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Taku Mimura

发明人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Taku Mimura

IPC分类号： B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  B01J23/86 ,  B01J37/18 ,  C07B61/00 ,  C07C29/149 ,  C07C31/02 ,  C07C29/36 ,  C07C31/125

CPC分类号： C07C29/149 ,  B01J23/72 ,  B01J23/80

摘要： A copper-containing hydrogenation reaction catalyst is prepared by reducing a precursor of a copper-containing catalyst usable in hydrogenation reaction with hydrogen gas or a mixture of hydrogen and an inert gas by liquid phase reduction in a stream of a solvent in the temperature range of from 50.degree. to 140.degree. C. An alcohol is produced using the catalyst thus obtained in a fixed bed continuous reaction system.

公开(公告)号：US5403988A

公开(公告)日：1995-04-04

申请号：US253921

申请日：1994-06-03

申请人： Masaki Kawada ,  Takashi Shimada ,  Hideo Nakamura ,  Toshio Emori ,  Yoshihiro Egawa ,  Tomohiko Yashiro ,  Hiroyuki Enomoto ,  Hisao Hiramoto ,  Masayuki Fukumori ,  Kiyoshi Tsukada ,  Koichi Maekawa

发明人： Masaki Kawada ,  Takashi Shimada ,  Hideo Nakamura ,  Toshio Emori ,  Yoshihiro Egawa ,  Tomohiko Yashiro ,  Hiroyuki Enomoto ,  Hisao Hiramoto ,  Masayuki Fukumori ,  Kiyoshi Tsukada ,  Koichi Maekawa

IPC分类号： B23K11/00 ,  B23K11/31 ,  B23K9/20

CPC分类号： B23K11/0053 ,  B23K11/318

摘要： A stud welding apparatus has a welding jig, guide frames and a cartesian coordinate type robot. This robot has a travelling frame, a robot main body, an elevating arm and a stud welding gun. Power supply passages are provided on the travelling frame, the robot main body and the elevating arm, respectively, such that electric power can be supplied from a welding power source to the stud welding gun via these power supply passages. The power supply passage provided on the travelling frame is formed in a first power supply bar which is fixed to the travelling frame and is elongated in a horizontal direction. A pressure type first power supply joint is provided on the robot main body and urges a contact member to be connected to the power supply passage provided on the robot main body into contact and away from the first power supply bar by means of a cylinder. The power supply passage provided on the elevating arm is formed in a second power supply bar which is fixed to the elevating arm and is elongated in a vertical direction. A pressure type second power supply joint is provided on the robot main body and urges a contact member to be connected to the power supply passage provided on the robot main body into contact and away from the second power supply bar by means of a cylinder.

摘要翻译： 螺柱焊接装置具有焊接夹具，引导框架和笛卡尔坐标型机器人。 该机器人具有行走架，机器人主体，升降臂和螺柱焊枪。 供电通道分别设置在行车架，机器人主体和升降臂上，使得能够通过这些电源通道从焊接电源向螺柱焊枪供电。 设置在行走架上的供电通道形成在第一供电杆上，该第一供电杆固定在行走架上并在水平方向上伸长。 在机器人主体上设置压力型第一供电接头，并且将通过设置在机器人主体上的供电通路的接触构件推压通过气缸与第一供电杆接触和离开。 设置在升降臂上的供电通道形成在固定到升降臂上并在垂直方向上延伸的第二电源杆中。 在机器人主体上设置有压力型第二供电接头，并且将通过设置在机器人主体上的供电通路连接的接触构件通过气缸接触和远离第二供电杆。

公开(公告)号：US5120700A

公开(公告)日：1992-06-09

申请号：US708709

申请日：1991-05-31

申请人： Morio Matsuda ,  Masamitsu Horio ,  Kiyoshi Tsukada

发明人： Morio Matsuda ,  Masamitsu Horio ,  Kiyoshi Tsukada

IPC分类号： B01J23/74 ,  B01J23/72 ,  B01J23/745 ,  B01J23/80 ,  C07B61/00 ,  C07C29/149 ,  C07C29/153 ,  C07C31/00 ,  C07C31/125

CPC分类号： B01J23/80 ,  B01J23/72 ,  C07C29/149

摘要： The hydrogenation catalyst comprises copper, iron, aluminum and optionally zine and a support selected from aluminum hydroxide, aluminum oxide and a mixture of aluminum hydroxide and aluminum oxide, having an atomic ratio of Cu/Fe/Al/Zn in the range of 1/(0.4 to 2.5)/(0.5 to 5.0)/(0 to 1.0). It is produced by dispersing a material for the support in an aqueous medium, depositing cupper and iron on the dispersant, further depositing thereon aluminum and sintering it. It is a catalyst for production of a higher alcohol from its methyl ester, effecting hydrogenation with an improved selectivity and activity.

摘要翻译： 氢化催化剂包括铜，铁，铝和任选的锌，以及选自氢氧化铝，氧化铝和氢氧化铝和氧化铝的混合物的载体，其原子比为Cu / Fe / Al / Zn的范围为1 / （0.4〜2.5）/（0.5〜5.0）/（0〜1.0）。 它通过将载体材料分散在水介质中，将铜和铁沉积在分散剂上，进一步在其上沉积铝并烧结。 它是从其甲酯生产高级醇的催化剂，以提高的选择性和活性进行氢化。

公开(公告)号：US5233100A

公开(公告)日：1993-08-03

申请号：US813918

申请日：1991-12-27

申请人： Osamu Tabata ,  Atsuhito Mori ,  Takahiro Kawakami ,  Kunizo Hashiba ,  Kiyoshi Tsukada

发明人： Osamu Tabata ,  Atsuhito Mori ,  Takahiro Kawakami ,  Kunizo Hashiba ,  Kiyoshi Tsukada

IPC分类号： C07C29/149 ,  C07C29/17

CPC分类号： C07C29/177 ,  C07C29/149 ,  Y02P20/132

摘要： A process for producing an alcohol from a fatty acid ester, a fatty acid triglyceride or a fatty acid by continuously catalytically reducing the starting material in the presence of a hydrogenation catalyst is disclosed. In the process of the present invention, two reactors (i.e., the main reactor located upstream and the after reactor located downstream) being located in series are employed. In the process of the present invention, two reactors are employed and the temperatures thereof are individually controlled, whereby the conversion ratio is elevated while suppressing the formation of hydrocarbon and aldehyde by-products. Thus, an alcohol of extremely high quality and high purity can be produced. Further, the process of the present invention makes it possible to omit any post-treatment for eliminating the by-products. Furthermore, the active life of the hydrogenation catalyst can be remarkably prolonged by using three reactors (i.e., the guard reactor, the main reactor and the after reactor).

摘要翻译： 公开了一种通过在氢化催化剂的存在下连续催化还原原料从脂肪酸酯，脂肪酸甘油三酯或脂肪酸制备醇的方法。 在本发明的方法中，使用两个反应器（即，位于下游的位于反应器的主反应器和位于下游的反应器）串联。 在本发明的方法中，使用两个反应器，并且单独控制其温度，由此转化率提高同时抑制烃和醛副产物的形成。 因此，可以生产出高质量和高纯度的醇。 此外，本发明的方法使得可以省略用于消除副产物的任何后处理。 此外，通过使用三个反应器（即保护反应器，主反应器和后反应器），氢化催化剂的活性寿命可以显着延长。

公开(公告)号：US5120885A

公开(公告)日：1992-06-09

申请号：US757053

申请日：1991-09-09

申请人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Hiroyuki Tamura ,  Akira Yamamuro ,  Kunizo Hashiba ,  Osamu Tabata

发明人： Kiyoshi Tsukada ,  Yasuyuki Hattori ,  Hiroyuki Tamura ,  Akira Yamamuro ,  Kunizo Hashiba ,  Osamu Tabata

IPC分类号： C07C29/149

CPC分类号： C07C29/149

摘要： A process for producing alcohols comprising catalytically reducing fats and oils or fatty acid esters with hydrogen in the presence of a catalyst for ester reduction is disclosed, wherein the starting oils are first treated at a temperature of from 50.degree. to 200.degree. C. in hydrogen gas or a mixed gas of hydrogen and an inert gas in the presence of a nickel catalyst to yield a sulfur content at not more than 0.6 ppm an acid value (KOH mg/g) of not more than 2. By use of the thus purified starting oils, the catalyst for ester reduction exhibits a prolonged duration.

摘要翻译： 公开了一种制备醇的方法，其包括在用于酯还原的催化剂的存在下用氢气催化降低脂肪和油或脂肪酸酯，其中起始油首先在50℃至200℃的温度下在氢气 气体或氢气和惰性气体的混合气体，在镍催化剂的存在下得到不大于0.6ppm的硫含量，酸值（KOH mg / g）不大于2.通过使用如此纯化的 起始油，用于酯还原的催化剂表现出延长的持续时间。

公开(公告)号：US5022456A

公开(公告)日：1991-06-11

申请号：US497890

申请日：1990-03-23

申请人： Yoshikazu Kanzawa ,  Yasushi Fujikake ,  Osami Ito ,  Shuho Ito ,  Hironobu Oikawa ,  Makoto Otsubo ,  Iwao Morikawa ,  Yuichi Shiratori ,  Kiyoshi Tsukada

发明人： Yoshikazu Kanzawa ,  Yasushi Fujikake ,  Osami Ito ,  Shuho Ito ,  Hironobu Oikawa ,  Makoto Otsubo ,  Iwao Morikawa ,  Yuichi Shiratori ,  Kiyoshi Tsukada

IPC分类号： B62K19/12

CPC分类号： B62K19/12

摘要： A body frame for a motor bicycle includes a main frame, a head tube provided at a front end of the main frame and down tubes extending rearward from the main frame. The main frame, head tube and down tubes are cast with a light alloy into an integral form of a hollow and thin-wall structure. A production process of the body frame, wherein an integrally-formed core, which is formed into a shape similar to that of the body frame, is hollow and has good permability. A molten metal is charged into the mold and a vacuum is applied to the interior of the core. The molten metal is charged into a cavity defined between the core and the molding surface of the mold by a low-pressure casting method, and the molten metal is solidified so as to cast the body frame. A production apparatus of the body frame includes a liftable cope fitted to a vertical casting machine, a fixed drag, and slidable molds disposed in combination with the cope and being capable of horizontally sliding in a state that the cope is released from the drag. A body frame having both properties of light weight and high stiffness, and a production process and apparatus thereof is provided wherein casting defects and to provide a high-precision cast article, is provided.

摘要翻译： 一种用于摩托车的车身框架包括主框架，设置在主框架前端的头管和从主框架向后延伸的下拉管。 主框架，头管和下管以轻合金铸造成中空和薄壁结构的整体形式。 主体框架的制造方法，其中形成为与主体框架类似的形状的整体形成的芯部是中空的并且具有良好的可容许性。 将熔融金属装入模具中，并将真空施加到芯部的内部。 将熔融金属通过低压铸造法加入到芯体和模具的成形表面之间的空腔中，并使熔融金属固化，从而铸造主体框架。 主体框架的制造装置包括安装在垂直铸造机上的可升降的上座板，固定的拖曳和可滑动的模具，与所述上座组合配置，并且能够在所述上钩从所述拖曳中释放的状态下水平滑动。 提供了具有轻质量和高刚度的两种特性的车体框架及其制造方法和装置，其中提供铸造缺陷并提供高精度铸造件。

公开(公告)号：US4918248A

公开(公告)日：1990-04-17

申请号：US355292

申请日：1989-05-22

申请人： Yasuyuki Hattori ,  Noriaki Fukuoka ,  Shigeru Tamura ,  Kunizo Hashiba ,  Kiyoshi Tsukada ,  Makoto Misono

发明人： Yasuyuki Hattori ,  Noriaki Fukuoka ,  Shigeru Tamura ,  Kunizo Hashiba ,  Kiyoshi Tsukada ,  Makoto Misono

IPC分类号： B01J23/72 ,  B01J23/80 ,  C07B61/00 ,  C07C27/00 ,  C07C29/136 ,  C07C29/149 ,  C07C67/00

CPC分类号： C07C29/149

摘要： An alcohol is effective produced by catalytically reducing an organic carboxylic acid ester with hydrogen in the presence of a catalyst obtained by reducing a catalyst precursor comprising (A) copper oxide and (B) titanium oxide and/or titanium hydroxide at a weight ratio of (A) to (B) in the range between 15/85 and 65/35. The component (A) may be alternatively a composite metal oxide comprises copper oxide and up to 20 wt. % of zinc oxide.

摘要翻译： 在通过将包含（A）氧化铜和（B）氧化钛和/或氢氧化钛的催化剂前体以（A）氧化铜和/或氢氧化钛的重量比为（A））催化还原的催化剂存在下，通过催化还原有机羧酸酯而产生的醇是有效的， A）到（B）在15/85和65/35之间的范围内。 组分（A）可以是复合金属氧化物，其包含氧化铜和至多20wt。 ％的氧化锌。