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122 条记录 (耗时 0.015 秒)

    Water-soluble, ultra-filtrable polyurethane anionomers and the use thereof as sizes in the textile industry
    12.
    发明授权
    Water-soluble, ultra-filtrable polyurethane anionomers and the use thereof as sizes in the textile industry 失效
    水溶性，超可过滤的聚氨酯阴离子聚合物及其在纺织工业中的用途

    公开(公告)号：US4276044A

    公开(公告)日：1981-06-30

    申请号：US89682

    申请日：1979-10-30

    申请人： Dieter Dieterich

    发明人： Dieter Dieterich

    IPC分类号： C08G18/00 ,  C08G18/08 ,  C08G18/32 ,  D06M15/564 ,  D06L1/12 ,  C08G18/50 ,  C08G18/82 ,  C08J3/06

    CPC分类号： D06M15/564 ,  C08G18/0819 ,  C08G18/3206 ,  Y10S528/904 ,  Y10S528/905

    摘要： There is described a polyurethane anionomer which is particularly suitable as a textile sizing agent because it is water-soluble and sufficiently hydrolysis-resistant to be recoverable by ultra-filtration. It is superior to previously known ionomers in being hard, tough and having a smooth surface.This anionomer is produced by reacting organic diisocyanates with tri- or tetra-ethylene glycol and optionally other aliphatic glycols as well as glycols bearing carboxyl, carboxylate, sulphonic acid or sulphonate groups in selected ratios which render the anionomer water-soluble after neutralization of an appropriate amount of the carboxyl or sulphonic acid groups. Aqueous solutions can be formed by dissolving the solid anionomer in water and these solutions can be used to size textile fibers with the recovery of excess anionomer by ulra-filtration.

    摘要翻译： 描述了一种特别适合作为纺织上浆剂的聚氨酯阴离子聚合物，因为它是水溶性且足够耐水解的，可通过超滤回收。 它比先前已知的离聚物优于硬，韧性并具有光滑表面。 该阴离子异构体通过有机二异氰酸酯与三乙醇或四乙二醇和任选的其它脂族二醇以及含有羧基，羧酸酯，磺酸或磺酸酯基团的二醇以选择的比例反应制得，其使阴离子交换体在中和后具有可溶性 羧基或磺酸基团的量。 水溶液可以通过将固体阴离子混合物溶解在水中形成，并且这些溶液可用于通过微量过滤回收过量阴离子交换剂来纺织纤维的尺寸。

    Polyurethane hydrogels having enhanced wetting rates
    14.
    发明授权
    Polyurethane hydrogels having enhanced wetting rates 失效
    具有增强润湿速率的聚氨酯水凝胶

    公开(公告)号：US4182827A

    公开(公告)日：1980-01-08

    申请号：US938702

    申请日：1978-08-31

    申请人： Allen P. Jones ,  Robert J. Knopf

    发明人： Allen P. Jones ,  Robert J. Knopf

    IPC分类号： C08J3/12 ,  C08J7/00 ,  C08G18/10

    CPC分类号： C08J3/12 ,  C08J7/047 ,  C08J2375/04 ,  Y10S521/905 ,  Y10S528/904

    摘要： The wetting rates of polyurethane hydrogels comprising lightly crosslinked polymers of isocyanate terminated prepolymers which are the reaction product of (i) poly(alkyleneoxy) polyols with (ii) organic diisocyanates that has been lightly crosslinked with (iii) water or an organic polyamine are enhanced by treating the surface of the solid hydrogel with certain ketones, alcohols, organic amines, aromatic hydrocarbons or aqueous alkali metal hydroxide solutions.

    摘要翻译： 包含与（iii）水或有机多胺轻度交联的（ⅱ）有机二异氰酸酯的（ⅰ）聚（亚烷氧基）多元醇与（ⅱ）有机二异氰酸酯的反应产物的异氰酸酯封端的预聚物的轻交联聚合物的聚氨酯水凝胶的润湿速率得到增强 通过用某些酮，醇，有机胺，芳族烃或碱金属氢氧化物水溶液处理固体水凝胶的表面。

    Water soluble, high solids urethane coating compositions
    15.
    发明授权
    Water soluble, high solids urethane coating compositions 失效
    水溶性高固体聚氨酯涂料组合物

    公开(公告)号：US4124552A

    公开(公告)日：1978-11-07

    申请号：US690277

    申请日：1976-05-26

    申请人： Joseph V. Koleske ,  Oliver W. Smith

    发明人： Joseph V. Koleske ,  Oliver W. Smith

    IPC分类号： C08G18/08 ,  C08G18/42 ,  C08L67/02 ,  C08L75/06 ,  C08L75/12

    CPC分类号： C08G18/4277 ,  C08G18/0823 ,  Y10S528/904

    摘要： Water soluble, high solids urethane coating compositions comprising a polycaprolactone derivative, an aliphatic polyisocyanate and water. The polycaprolactone derivative is a water soluble, carboxyl modified oligomer addition reaction product mixture obtained by the reaction of polycaprolactone polyol and an anhydride of a polycarboxylic acid to produce a water insoluble adduct that on reaction with an inorganic or organic base produces the water soluble, carboxyl modified oligomer addition reaction product mixtures which are eminently suitable for the production of urethane coating compositions of this invention. The polycaprolactone polyol reacted with the polycarboxylic acid has an average at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride has at least one intramolecular carboxylic anhydride group.

    摘要翻译： 包含聚己内酯衍生物，脂肪族多异氰酸酯和水的水溶性高固体聚氨酯涂料组合物。 聚己内酯衍生物是通过聚己内酯多元醇与多元羧酸的酸酐反应获得的水溶性羧基改性低聚物加成反应产物混合物，以产生水不溶性加合物，其与无机或有机碱反应产生水溶性羧基 改进的低聚物加成反应产物混合物，其特别适用于生产本发明的聚氨酯涂料组合物。 与多元羧酸反应的聚己内酯多元醇在分子中具有平均至少两个羟基，羟基数为约15至约600，平均分子量为约290至约6,000。 羧酸酐具有至少一个分子内羧酸酐基团。

    Hydrophilic and thermoreactive urethane compositions with improved properties
    17.
    发明授权
    Hydrophilic and thermoreactive urethane compositions with improved properties 失效
    具有改进性能的亲水和热反应性氨基甲酸酯组合物

    公开(公告)号：US4039517A

    公开(公告)日：1977-08-02

    申请号：US582003

    申请日：1975-05-29

    申请人： Tamotu Hamamura ,  Sumio Goto ,  Kazuhiko Ishihara

    发明人： Tamotu Hamamura ,  Sumio Goto ,  Kazuhiko Ishihara

    IPC分类号： C08G18/08 ,  C08G18/10 ,  C08G18/12 ,  C08G18/48 ,  C09J175/08 ,  C08G18/06

    CPC分类号： C09J175/08 ,  C08G18/0819 ,  C08G18/10 ,  C08G18/12 ,  C08G18/4833 ,  C08G18/4837 ,  C08G2170/80 ,  Y10S528/904 ,  Y10S528/905

    摘要： A hydrophilic and thermoreactive urethane composition having improved properties such as stability in solution, non-tackiness, water resistance and strength and useful in treating and finishing fibrous products prepared by forming a urethane prepolymer containing free isocyanate groups from (a) (1) a compound containing at least 2 active hydrogen atoms, containing an oxyethylene chain, and having a molecular weight of about 200 to 20,000, or (2) a compound containing at least 2 active hydrogen atoms, not containing an oxyethylene chain, and having a molecular weight of about 200 to 20,000 and a compound containing at least 2 active hydrogen atoms, containing an oxyethylene chain and having a molecular weight of about 200 to 200,000; and (b) an excess of a polyisocyanate; and if desired, (c) a chain extender containing at least 2 active hydrogen atoms; whereby the prepolymer has an oxyethylene chain content of 10 to 40% by weight, and then reacting the prepolymer or a solution thereof with not more than 3 times the equivalent of the free isocyanate groups in the prepolymer of an aqueous solution of a bisulfite salt having a concentration of at least 15% by weight. Where the urethane prepolymer contains at least 1% by weight ester groups, the hydrophilic and thermoreactive urethane composition is particularly valuable as a high strength adhesive composition and is useful as an adhesive in bonding a sheet-like material as a top-coat to a fabric as a base in producing an artificial leather.

    摘要翻译： 一种亲水和热反应性氨基甲酸酯组合物，其具有改进的性能，例如溶液的稳定性，非粘性，耐水性和强度，并且可用于处理和整理由（a）形成含有游离异氰酸酯基团的氨基甲酸酯预聚物制备的纤维制品（1） 含有至少2个含有氧化乙烯链的活性氢原子，分子量约为200〜20000的活性氢原子，或（2）含有至少2个不含有氧化乙烯链的活性氢原子的化合物，分子量为 约200至20,000个含有至少2个活性氢原子的化合物，其含有氧化乙烯链且分子量为约200至200,000; 和（b）过量的多异氰酸酯; 并且如果需要，（c）含有至少2个活性氢原子的扩链剂; 由此所述预聚物的氧化乙烯链含量为10至40重量％，然后使预聚物或其溶液的反应速率不超过预聚物中游离异氰酸酯基团当量的3倍，该预聚物具有 至少15重量％的浓度。 在氨基甲酸酯预聚物含有至少1重量％酯基的情况下，亲水和热反应性氨基甲酸酯组合物作为高强度粘合剂组合物是特别有价值的，并且可用作将作为顶涂层的片状材料粘合到织物上的粘合剂 作为生产人造革的基地。