公开(公告)号：US4454024A

公开(公告)日：1984-06-12

申请号：US438407

申请日：1982-11-01

Applicant: Gopal H. Singhal ,  Gordon F. Stuntz

Inventor： Gopal H. Singhal ,  Gordon F. Stuntz

IPC: C10G47/16 ,  C10G47/32 ,  C10G45/30 ,  C10G47/34

CPC classification number: C10G47/16 ,  C10G47/32

Abstract: A slurry hydroconversion process is provided wherein a heavy hydrocarbonaceous oil, in which is dispersed a metal-contaminated, partially deactivated zeolitic cracking catalyst, is converted to lower boiling products in the presence of a molecular hydrogen-containing gas, and a hydrogen donor diluent.

Abstract translation: 提供了一种浆料加氢转化方法，其中分散有金属污染的部分失活的沸石裂化催化剂的重质烃油在分子含氢气体和氢供体稀释剂的存在下转化为较低沸点产物。

公开(公告)号：US4272400A

公开(公告)日：1981-06-09

申请号：US59070

申请日：1979-07-19

Applicant: Bernard G. Silbernagel ,  Raam R. Mohan ,  Gopal H. Singhal

Inventor： Bernard G. Silbernagel ,  Raam R. Mohan ,  Gopal H. Singhal

IPC: B01J23/90 ,  B01J23/94 ,  B01J37/20 ,  C10G45/08 ,  B01J21/20 ,  B01J23/92 ,  C10G23/02

CPC classification number: B01J37/20 ,  B01J23/90 ,  B01J23/94 ,  C10G45/08 ,  Y10S502/516

Abstract: The removal of metals, especially vanadium, from spent hydrofining catalyst is accomplished by a two-step process. Treatment with a gaseous sulfur-containing reagent brings the metals to the surface of the catalyst and converts them to sulfides, which are then efficiently removed by contact with a heteropoly acid such as molybdophosphoric acid. Treatment of deactivated hydrodesulfurization catalysts such as Co-Mo supported on alumina by this process results in substantially complete regeneration of catalytic activity.

Abstract translation: 从二次加氢精制催化剂中除去金属，特别是钒是通过两步法实现的。 用气态含硫试剂处理将金属转移到催化剂的表面，并将其转化为硫化物，然后通过与杂多酸如钼磷酸接触有效地除去。 通过该方法处理负载在氧化铝上的失活的加氢脱硫催化剂如Co-Mo导致催化活性的基本上完全的再生。