摘要:
Phosphonomethylated poly-vinylamines which contain as characteristic structural elements units of the formula where R1 is hydrogen, C1-C6-alkyl or and X is hydrogen, an alkali metal, ammonium or one equivalent of an alkaline earth metal, are obtainable by phosphonomethylation of polymers which contain N-vinyl-amide or vinylamine groups and are useful as detergent additives and water treatment agents.
摘要:
Graft copolymers obtainable by free radical-initiated copolymerization of(A) a monomer mixture comprising(a) a monoethylenically unsaturated C.sub.4 - to C.sub.8 -dicarboxylic acid, or an anhydride, alkali metal salt or ammonium salt thereof,(b) a monoethylenically unsaturated C.sub.3 - to C.sub.10 -carboxylic acid, or an alkali metal salt or ammonium salt thereof,(c) if desired another monoethylenically unsaturated monomer which can be copolymerized with monomer (a) and (b), and(d) a monomer containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) a monosaccharide, oligosaccharide, polysaccharide, oxidatively, hydrolytically or enzymatically degraded polysaccharide, oxidized, hydrolytically or enzymatically degraded polysaccharide, or chemically modified monosaccharide, oligosaccharide or polysaccharide,in the weight ratio (A):(B) of (95 to 20):(5 to 80), a process for the preparation of the graft copolymers, and detergents and cleaners containing the graft copolymers in amounts of from 0.1 to 20% by weight, are described.
摘要:
Water-soluble or water-dispersible polyesters obtainable by condensation of tartaric acid or derivatives thereof alone or by condensation of mixtures of tartaric acid or derivatives thereof and citric acid with or without alcohols, water-soluble polyalkylene glycols or water-soluble polyaddition products of alkylene oxides with alcohols, fatty acids, alkylphenols or alkylamines and with or without at least dibasic carboxylic acids are suitable for use as detergent additives.
摘要:
A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) polyalkylene oxides which have a number average molecular weight of from 300 to 100,000 and are based on ethylene oxide, propylene oxide and/or butylene oxide, with(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 3 to 6 carbon atoms, a methyl or ethyl ester of (meth)acrylic acid and optionally mixtures of at least one of the monomers mentioned and up to 95% by weight of vinyl acetate in a weight ratio (a):(b) of from 1:02 to 1:10.
摘要:
Polyesters obtainable by condensation of(a) an at least dicarboxylic acid, or an ester or anhydride or a mixture thereof,(b) an at least dihydric alcohol or an addition product of from 1 to 5 mol of at least one alkylene oxide of 2 or 3 carbon atoms with 1 mol of an at least dihydric alcohol, or a mixture thereof, and(c) a water-soluble addition product of from 5 to 80 mol of at least one alkylene oxide with 1 mol of a C.sub.8 -C.sub.24 -alcohol, a C.sub.8 -C.sub.18 -alkylphenol or a C.sub.8 -C.sub.24 -alkylaminein a molar ratio of (a):(b):(c) of 100:(25-2500):(5-110) at not less than 120.degree. C. up to a weight average molecular weight of from 2000 to 50000, are used in amounts of from 0.05 to 15% by weight as grayness inhibitors and soil release promoters in detergents.
摘要:
Detergents contain graft polymers obtainable by grafting(a) polycondensates based on polyesters, polyester urethanes and polyester amides and having in each case a number average molecular weight from 500 to 100,000 with(b) from 0.2 to 10 parts by weight, based on 1 part by weight of the polycondensates, of vinyl esters of saturated C.sub.1 - to C.sub.6 -carboxylic acids, acrylic and/or methacrylic esters of saturated monohydric alcohols containing 1 to 4 carbon atoms.
摘要:
Detergents contain added graft copolymers which have an antiredeposition action and are obtainable by grafting polyalkylene oxides having a number average molecular weight of from 2000 to 100,000 with vinyl acetate in a weight ratio of from 1:0.2 to 1:10, and up to 15% of whose acetate groups may be hydrolyzed.
摘要:
A process for preparing aqueous polyurethane dispersions has been discovered which comprises(a) forming a polyurethane solution by reacting an organic polyisocyanate in the presence of a solvent with(i) an acrylic ester diol having a molecular weight of between 146 and 3,000;(ii) an organic polyhydroxyl compound other than (i) having a molecular weight between 400 and 5,000 selected from the group consisting of polyester polyols, polyether polyols, polycarbonates, polylactones, and mixtures thereof; and(iii) a chain extender having a molecular weight between 62 and 400 selected from the group consisting of diols, triols, diamines, aminoalcohols, and mixtures thereof;(b) forming an anionic polyurethane addition product by reacting said polyurethane solution with a mercaptocarboxylic acid salt in the presence of a solvent;(c) adding water; and(d) removing the solvent.The dispersions can be used in a variety of applications. For instance, they can be used to prepare films, coating, and binders.
摘要:
A detergent contains as a grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers a graft polymer obtainable by grafting(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000 and is based on ethylene oxide, propylene oxide and/or butylene oxide with(b) N-vinlypyrrolidone and(c) a vinyl ester derived from a saturated monocarboxylic acid containing from 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acid in a weight ratio (a):(b):(c) of from 1:0.3:1 to 1:5:30, the order of the addition of (b) and (c) in the graft copolymerization being immaterial and it being possible for up to 1 mole % of the grafted-on monomers (c) to be hydrolyzed.
摘要:
A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000, is based on ethylene oxide, propylene oxide and/or butylene oxide, and is end group capped at at least one end, with(b) at least on vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acid in a weight ratio (a):(b) of from 1:0.2 to 1:10.