摘要:
A process for crosslinking polyamides by reacting a compound of the general formula R1R2C═CR3—X in which R1, R2 and R3 are each independently hydrogen or an organic radical with a lactam A at a temperature of (−30) to 150° C., and then reacting with a lactam B, a catalyst and an activator at a temperature of 40 to 240° C.
摘要翻译:通过使通式为R 1 R 2 C = CR 3 -X的化合物(其中R 1,R 2和R 3各自独立地为氢或有机基团)与内酰胺A在(-30)至150℃的温度下反应来交联聚酰胺的方法。 然后在40〜240℃的温度下与内酰胺B,催化剂和活化剂反应。
摘要:
The present invention relates to copolymers obtainable by free-radical polymerization of i) 10% to 90% by weight, based on the total weight of components i to iv, of at least one monomer selected from the group consisting of a C8-C30 alkyl (meth)acrylate, C8-C30 vinyl ester, C8-C30 vinyl ether, C8-C30 olefin, and triglyceride of unsaturated C8-C30 carboxylic acids; ii) 0.5% to 70% by weight, based on the total weight of components i to iv, of a double-bond-containing monomer having at least one epoxide, isocyanate, carbodiimide, silane, β-dicarbonyl, oxazoline, or anhydride group; iii) 0% to 75% by weight, based on the total weight of components i to iv, of one or more monomers selected from the group consisting of vinylaromatic, C1-C7-alkyl (meth)acrylate, ethylenically unsaturated acetophenone derivative or benzophenone derivative, C1-C7 vinyl ester, C1-C7 vinyl ether, ethylenically unsaturated nitrile, ethylenically unsaturated amide, vinyl halide, C2-C7 olefin, cyclic lactam, and mixtures of these monomers; and iv) 0% to 10% by weight, based on the total weight of components i to iv, of a free-radically polymerizable monomer with carboxylic acid, sulfonic acid or phosphonic acid groups or salts thereof. The invention further relates to polymer mixtures comprising these copolymers and also to the use of the copolymers as chain extenders, compatibilizers and/or hydrolysis stabilizers, to produce paper and cardboard, for surface finishing in the paper, textile, and leather industries, and in adhesives.
摘要:
Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译:热塑性模塑组合物,其包含A)10至98重量%的至少一种热塑性聚合物,B)0.01至50重量%的B1)至少一种高度支化或超支化聚碳酸酯,其OH值为1至600 mg KOH / g聚碳酸酯(根据DIN 53240第2部分)或B2)至少一种高度支化或超支化的A x B B y Y y型聚酯,其中x为 至少1.1和y为至少2.1,或这些的混合物,C)1至40重量%的无卤阻燃剂,选自含磷或含氮化合物,或 PN缩合物,或它们的混合物,D)0至60重量%的其它添加剂,其中组分A)至D)的重量百分比的总和为100%。
摘要:
Process for production of foam webs or foam sheets, these webs or sheets being based on a polymer selected from polysulfones, polyetherimides, polyether ketones, and styrene polymers, via extrusion of a melt which comprises the polymer and a blowing agent, and then foaming of this melt, which comprises a process in which the melt also comprises from 1 to 50% by weight, based on the polymer, of a filler selected from A) a fibrous filler A, B) a particulate, non-graphite filler B, and mixtures of these.
摘要:
Sheet-like polyurethane moldings are produced by impregnation of porous sheets with a prepolymer containing free isocyanate groups and reversibly blocked isocyanate-reactive groups or containing free isocyanate-reactive groups and reversibly blocked isocyanate groups, and subsequent reaction of the prepolymers in a heated mold.
摘要:
The invention relates to a process for the preparation of CFC-free, flexible polyurethane foams or molded foams by reactingA) liquid polyisocyanate mixtures containing bonded urethane groups and having a content of NCO groups of from 20 to 30% by weight, these mixtures themselves being prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl-polymethylene polyisocyanates (crude diphenylmethane diisocyanate) with a polyether-polyol mixture, having a hydroxyl number of from 120 to 25, of at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene-polyoxyethylene glycol having a content of ethylene oxide units of from 90 to 10% by weight or by reacting 4,4'-diphenylmethane diisocyanate (diphenylmethyl diisocyanate) or an diphenylmethane diisocyanate isomer mixture with said polyether-polyol mixture to give an NCO-containing quasi-prepolymer and diluting this quasi-prepolymer with crude diphenylmethane diisocyanate, withB) relatively high-molecular-weight polyhydroxyl compounds.
摘要:
Mixtures of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates (crude MDI) of reduced iodine color number are prepared by reacting the corresponding mixtures of diphenylmethanediamines and polyphenylpolymethylenepolyamines with phosgene in the presence of at least one inert organic solvent at elevated temperature, at least one monohydric or polyhydric polyoxyalkylene alcohol, preferably having a functionality of from 2 to 3, and advantageously having a hydroxyl number of from 20 to 1800, or mixtures thereof in an effective amount, expediently in an amount of from 0.1 to 10% by weight, based on the weight of the crude MDI, being introduced into the reaction mixture when the phosgenation is complete, the phosgene and the inert organic solvent then being removed, up to 5% by weight, based on the weight of crude MDI, of at least one phenol-based antioxidant and/or aryl phosphite being added, if desired to the reaction product, and the reaction mixture being heated.
摘要:
A process for producing an activated monomer composition comprising at least one lactam and/or lactone, one catalyst, and one activator permits storage of the resultant monomer composition, since this is stable with respect to polymerization. Said monomer composition is used inter alia in producing a polyamide molding via ring-opening, anionic polymerization.
摘要:
The present invention relates to a method for producing fiber-reinforced composite materials, in which a multiplicity of continuous filaments or woven fabric is impregnated optionally together with reinforcing materials, comprising caprolactam and other starting materials for polyamide 6 or other starting materials for copolymers of caprolactam, passed through at temperatures of 70 to 100° C., and anionically polymerized at temperatures of 100 to 190° C., and optionally repolymerized at temperatures of 90 to 170° C.
摘要:
Thermoplastic molding compositions comprising A) from 10 to 99.99% by weight of at least one thermoplastic polyester, B) from 0.01 to 50% by weight of a hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
摘要翻译:热塑性模塑组合物,其包含A)10至99.99重量%的至少一种热塑性聚酯,B)0.01至50重量%的具有OH值为1至600mg KOH / g聚碳酸酯的超支化聚碳酸酯(至 DIN 53240,Part 2),C)0至60重量%的其它添加剂,其中组分A)至C)的重量百分比的总和为100%。