Coupling of anionic polymers with trialkoxysilanes having
silicon-hydrogen bonds
    21.
    发明授权
    Coupling of anionic polymers with trialkoxysilanes having silicon-hydrogen bonds 失效
    阴离子聚合物与具有硅 - 氢键的三烷氧基硅烷的偶联

    公开(公告)号:US5681895A

    公开(公告)日:1997-10-28

    申请号:US705032

    申请日:1996-08-29

    CPC分类号: C08C19/44

    摘要: A high yield of three armed radial anionic polymers is produced by the process of coupling metal terminated anionic polymers with a trialkoxysilane having a silicon-hydrogen bond, preferably trimethoxysilane. The metal terminated anionic polymer is preferably produced by initiating polymerization with a protected functional initiator which is readily converted to terminal hydroxyl groups or derivatives thereof for use in adhesives, sealants, and coatings.

    摘要翻译: 通过将金属封端的阴离子聚合物与具有硅 - 氢键的三烷氧基硅烷,优选三甲氧基硅烷偶联的方法制备出三臂式放射状阴离子聚合物的高产率。 金属封端的阴离子聚合物优选通过用易于转化为末端羟基的保护的官能引发剂或其衍生物引发聚合来制备,以用于粘合剂,密封剂和涂料。