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    Process for synthesis of amidoacids using a cobalt catalyst and a bidental phosphine ligand
    22.
    发明授权
    Process for synthesis of amidoacids using a cobalt catalyst and a bidental phosphine ligand 失效
    使用钴催化剂和二价膦配体合成酰胺酸的方法

    公开(公告)号：US4892687A

    公开(公告)日：1990-01-09

    申请号：US916770

    申请日：1986-10-08

    Applicant: Jiang-Jen Lin

    Inventor： Jiang-Jen Lin

    IPC: C07B61/00 ,  B01J31/00 ,  C07C67/00 ,  C07C231/00 ,  C07C231/14 ,  C07C233/00 ,  C07C233/45 ,  C07C233/47

    CPC classification number: C07C233/00 ,  C07C233/45

    Abstract: A process is disclosed for producing N-acetyl-aminoacid which comprises reacting a feedstock from the group consisting of simple olefins, acetamide and synthesis gas with a catalyst comprising a cobalt-containing compound promoted by a bidental-phosphine ligand in a solvent at a pressure of 500 psi or greater and a temperature of 50.degree. C. or greater. The presence of the ligand increases both reaction rate and cobalt catalyst stability.

    Abstract translation: 公开了一种用于生产N-乙酰基 - 氨基酸的方法，该方法包括使来自由单一烯烃，乙酰胺和合成气组成的组的原料与包含由偶氮膦配体在溶剂中以压力作用促进的含钴化合物的催化剂反应 为500psi以上，温度为50℃以上。 配体的存在增加了反应速率和钴催化剂的稳定性。

    Hydroxy-terminated amides
    23.
    发明授权
    Hydroxy-terminated amides 失效
    羟基封端的酰胺

    公开(公告)号：US4791230A

    公开(公告)日：1988-12-13

    申请号：US174580

    申请日：1988-03-30

    Applicant: Jiang-Jen Lin ,  George P. Speranza

    Inventor： Jiang-Jen Lin ,  George P. Speranza

    IPC: C08G18/38 ,  C08G69/44 ,  C07C102/00

    CPC classification number: C08G69/44 ,  C08G18/3825 ,  C08G2101/0008

    Abstract: A series of hydroxy-terminated amides has been discovered. They are of the formulae:R--[NHCO(CH.sub.2).sub.z OH].sub.2andR--[NHCO(CH.sub.2 OCH.sub.2 OCH.sub.2 CH.sub.2 OH)].sub.2wherein:R is a polyoxyethylene radical of 1 to 9 mers which is optionally capped at both ends with 1 or 2 propylene oxide mers, and z is 3 or 5.The amides are water soluble and cold acetone insoluble. They are useful in flexible polyurethane foams.

    Abstract translation: 已经发现了一系列羟基封端的酰胺。 它们具有下式：R- [NHCO（CH 2）z OH] 2和R- [NHCO（CH 2 OCH 2 CH 2 CH 2 OH）] 2其中：R是1至9个聚合物的聚氧乙烯基团，其任选地在两端用1或2个丙烯 氧化物，z为3或5.酰胺是水溶性的，冷丙酮不溶。 它们可用于柔性聚氨酯泡沫。

    Curatives of epoxy resins from dicarboxylic acids, including (1) indane or (2) tert-butylisophtalic derived acids, reacted with polyetherdiamines
    24.
    发明授权
    Curatives of epoxy resins from dicarboxylic acids, including (1) indane or (2) tert-butylisophtalic derived acids, reacted with polyetherdiamines 失效
    来自二羧酸的环氧树脂的固化剂，包括（1）二氢化茚或（2）叔丁基间苯二酸衍生的酸与聚醚二胺反应

    公开(公告)号：US4789721A

    公开(公告)日：1988-12-06

    申请号：US78310

    申请日：1987-07-27

    Applicant: Harold G. Waddill ,  Jiang-Jen Lin ,  George P. Speranza

    Inventor： Harold G. Waddill ,  Jiang-Jen Lin ,  George P. Speranza

    IPC: C08G59/54 ,  C08G59/44

    CPC classification number: C08G59/54

    Abstract: Carboxylic acid-polyetherpolyamine reaction products which contain as the principle reaction component, an amidoamine having the formula: ##STR1## where R=polyether segment as previously defined.Z=dicarboxylic acid of structure given in Examples 2 and obtained by reacting a polyoxypropylene and/or polyoxyethylene diamine with an aromatic dicarboxylic acid in molar proportions such that at least about 1.0 to 1.2 mole equivalents of amine are provided in the reaction mixture of each mole equivalent of carboxylic acid present in the reaction mixture. The amidoamines exhibit improved properties which allow for a rapid curing system even under ambient conditions and useful applications include coatings, adhesives, encapsulations, laminates and composite fabrications.

    Abstract translation: 含有作为主要反应组分的羧酸 - 聚醚多胺反应产物，具有下式的酰氨基胺：其中R =如前所定义的聚醚链段。 Z =实施例2中给出的结构的二羧酸，其通过使聚氧丙烯和/或聚氧乙烯二胺与芳族二羧酸反应得到的摩尔比例使得在每摩尔的反应混合物中提供至少约1.0至1.2摩尔当量的胺 相当于反应混合物中存在的羧酸。 酰氨基胺表现出改进的性能，即使在环境条件下也能快速固化，并且有用的应用包括涂料，粘合剂，包封物，层压材料和复合制品。

    Process for synthesis of glutamic acid from acrylate, amide and synthesis gas
    25.
    发明授权
    Process for synthesis of glutamic acid from acrylate, amide and synthesis gas 失效
    从丙烯酸酯，酰胺和合成气合成谷氨酸的方法

    公开(公告)号：US4720573A

    公开(公告)日：1988-01-19

    申请号：US891094

    申请日：1986-07-31

    Applicant: Jiang-Jen Lin

    Inventor： Jiang-Jen Lin

    IPC: C07C237/00 ,  C07C103/66

    CPC classification number: C07C237/00

    Abstract: A process for the synthesis of glutamic acid intermediate from an acrylate, amide and syngas by reacting them in the presence of a catalyst comprising a cobalt-containing compound, a bis-phosphine ligand and a solvent at a pressure of at least 500 psi and a temperature of at least 50.degree. C. and thereafter extracting the glutamic acid.

    Abstract translation: 通过使它们在包含含钴化合物，双膦配体和溶剂的催化剂存在下，在至少500psi的压力下反应从丙烯酸酯，酰胺和合成气中合成谷氨酸中间体的方法， 温度至少为50℃，然后提取谷氨酸。

    Process for amidocarbonylation of cyclic amides
    26.
    发明授权
    Process for amidocarbonylation of cyclic amides 失效
    环酰胺酰化羰基化方法

    公开(公告)号：US4620949A

    公开(公告)日：1986-11-04

    申请号：US720229

    申请日：1985-04-05

    Applicant: Jiang-Jen Lin

    Inventor： Jiang-Jen Lin

    IPC: C07D207/26 ,  C07D207/263 ,  C07D207/27 ,  C07D223/10 ,  C08G69/02 ,  C07D401/06 ,  C07D403/06

    CPC classification number: C07D207/263 ,  C07D207/27 ,  C07D223/10 ,  C08G69/02

    Abstract: Amino acid derivatives are synthesized by reacting paraformaldehyde, cyclic amides and synthesis gas with a bimetallic catalyst comprising a rhodium-containing compound and a cobalt-containing compound, optionally in the presence of a solvent at a pressure of at least 500 psi and a temperature of at least 50.degree. C. The novel amino acid products may be hydrolyzed to amino dicarboxylic acids or used as monomers to polyamides.

    Abstract translation: 氨基酸衍生物通过使多聚甲醛，环状酰胺和合成气与包含含铑化合物和含钴化合物的双金属催化剂反应，任选在溶剂存在下，在至少500psi的压力和 至少50℃。新的氨基酸产物可以水解成氨基二羧酸或用作聚酰胺的单体。

    Preparation of 2-hydroxytetrahydrofuran by hydroformylation of allyl alcohol using ketone solvents
    27.
    发明授权
    Preparation of 2-hydroxytetrahydrofuran by hydroformylation of allyl alcohol using ketone solvents 失效
    使用酮溶剂通过烯丙醇的羰基化来制备2-羟基四氢呋喃

    公开(公告)号：US4533742A

    公开(公告)日：1985-08-06

    申请号：US576509

    申请日：1984-02-02

    Applicant: Jiang-Jen Lin ,  John F. Knifton

    Inventor： Jiang-Jen Lin ,  John F. Knifton

    IPC: B01J31/00 ,  B01J31/20 ,  B01J31/24 ,  C07B61/00 ,  C07D307/20

    CPC classification number: C07D307/20

    Abstract: A process is disclosed for preparing products such as 2-hydroxytetrahydrofuran which comprises contacting unsaturated compounds such as allyl alcohol with carbon monoxide and hydrogen in the presence of a rhodium carbonyl catalyst and a ketone solvent system. Allyl alcohol conversions of 100% and selectivities to 2-hydroxytetrahydrofuran of 96% are achievable under certain conditions. Preferred ketone solvents are acetophenone and 2-undecanone. 2-Hydroxytetrahydrofuran is an important precursor to manufacture of 1,4-butanediol.

    Abstract translation: 公开了一种制备诸如2-羟基四氢呋喃的产物的方法，该方法包括在羰基铑催化剂和酮溶剂体系的存在下使不饱和化合物如烯丙醇与一氧化碳和氢气接触。 100％的烯丙醇转化率和96％的2-羟基四氢呋喃的选择性在某些条件下是可以实现的。 优选的酮溶剂是苯乙酮和2-十一烷酮。 2-羟基四氢呋喃是制备1,4-丁二醇的重要前体。

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