公开(公告)号：US08436156B2

公开(公告)日：2013-05-07

申请号：US12345998

申请日：2008-12-30

申请人： John Kerr ,  Robert Jansen ,  Duane A. Leinhos ,  James Edwin Wiley, Jr. ,  Sebastien Camborieux ,  Anthony Baiada ,  Gordon Walker ,  Carlo Maffezzoni

发明人： John Kerr ,  Robert Jansen ,  Duane A. Leinhos ,  James Edwin Wiley, Jr. ,  Sebastien Camborieux ,  Anthony Baiada ,  Gordon Walker ,  Carlo Maffezzoni

IPC分类号： C07H15/00

CPC分类号： C07H1/06 ,  C07H5/02

摘要： The present invention provides a method for producing sucralose from a feed stream resulting from the chlorination of a sucrose-6-acylate in a reaction vehicle. The feed stream includes a sucralose-6-acylate, the reaction vehicle, water, and salts. The salts include one or more selected from the group consisting of alkali metal chlorides, alkaline earth metal chlorides and ammonium chloride. The method includes: (i) deacylation of the sucralose-6-acylate by treatment with a base to afford a product stream comprising sucralose; (ii) partial removal of water and, optionally, reaction vehicle from the product stream of (i) in order to cause precipitation of the salts from the product stream; (iii) removal of the precipitated salts from the product stream of (ii); and (iv) isolation of sucralose from the product stream of (iii).

摘要翻译： 本发明提供了由反应载体中蔗糖-6-酰化物的氯化得到的进料流中生产三氯蔗糖的方法。 进料流包括三氯蔗糖-6-酰化物，反应载体，水和盐。 所述盐包括选自碱金属氯化物，碱土金属氯化物和氯化铵中的一种或多种。 该方法包括：（i）用碱处理三氯半乳蔗糖-6-酰化物脱酰基，得到包含三氯蔗糖的产物流; （ii）从（i）的产物流中部分除去水和任选的反应载体，以便使产物流中的盐沉淀; （iii）从（ii）的产物流中除去沉淀的盐; 和（iv）从（iii）的产物流中分离三氯半乳蔗糖。

公开(公告)号：US20120279497A1

公开(公告)日：2012-11-08

申请号：US13491485

申请日：2012-06-07

申请人： Robert Jansen ,  Aharon Eyal

发明人： Robert Jansen ,  Aharon Eyal

IPC分类号： C13K13/00

CPC分类号： C13K13/007 ,  C13K1/02 ,  C13K13/002

摘要： A viscous fluid comprising 2% wt to 25% wt water, at least 75% wt carbohydrate (calculated by 100×[carbohydrate/(carbohydrate weight+water weight)]), between 0% wt and 25% wt of a second organic solvent and between 10% wt and 55% wt HCl (calculated by 100×[HCl weight/HCl weight+water weight]), which second organic solvent is characterized by at least one of: (a2) having a polarity related component of Hoy's cohesion parameter between 0 and 15 MPa1/2; (b2) having a Hydrogen bonding related component of Hoy's cohesion parameter between 0 and 20 MPa1/2; and (c2) having a solubility in water of less than 15% and forming a heterogeneous azeotrope with water, wherein the weight/weight ratio of said second organic solvent to water is in the range of between 50 and 0.02, and wherein the solubility of water in said organic solvent is less than 20%.

摘要翻译： 包含2重量％至25重量％水，至少75重量％碳水化合物（由100克碳水化合物/（碳水化合物重量+水重量）计算））的粘性流体），0重量％至25重量％的第二有机溶剂 和10重量％至55重量％HCl（通过100×[HCl重量/ HCl重量+水重量]计算）计算），该第二有机溶剂的特征在于以下至少一个：（a2）具有Hoy的内聚力的极性相关成分 参数介于0和15 MPa1 / 2之间; （b2）具有0〜20MPa1 / 2的Hoy粘附参数的氢键相关成分; 和（c2）在水中的溶解度小于15％并与水形成非均相共沸物，其中所述第二有机溶剂与水的重量/重量比在50和0.02之间，其中溶解度 所述有机溶剂中的水不足20％。

公开(公告)号：US20120058526A1

公开(公告)日：2012-03-08

申请号：US13225346

申请日：2011-09-02

申请人： Robert Jansen ,  Aharon Eyal

发明人： Robert Jansen ,  Aharon Eyal

IPC分类号： C12P1/00 ,  C07K1/14 ,  C12N1/16 ,  C07H1/00 ,  C12P7/02 ,  C12P7/40 ,  C12P5/02 ,  C12P7/62 ,  C12N9/00 ,  C08F110/02 ,  C08F110/06 ,  C08F110/00 ,  C08G63/08 ,  C08F120/06 ,  C09D133/02 ,  C09J133/02 ,  C12P7/64 ,  C07C47/00 ,  C07C49/00 ,  C07K14/00 ,  C07K2/00 ,  C12M1/00 ,  D04H11/00 ,  B32B1/00 ,  B32B1/08 ,  D04H13/00 ,  C07C29/74

CPC分类号： C13K13/002 ,  A23K20/163 ,  A23K50/10 ,  C07H1/00 ,  C07H3/00 ,  C12P7/10 ,  C12P7/14 ,  C13K1/00 ,  C13K1/02 ,  C13K13/007 ,  Y02E50/16 ,  Y02E50/343 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/139 ,  Y10T442/60

摘要： A method including: (a) selectively reacting a first sugar in a mixture which includes at least one second sugar to form a product mixture comprising a product of said first sugar; (b) separating said product of said first sugar from said product mixture; and (c) separating at least one of said at least one second sugar from said product mixture.

摘要翻译： 一种方法，包括：（a）选择性地使包含至少一种第二糖的混合物中的第一糖反应以形成包含所述第一糖的产物的产物混合物; （b）将所述第一糖的所述产物与所述产物混合物分离; 和（c）从所述产物混合物中分离出所述至少一种第二糖中的至少一种。

公开(公告)号：US08092609B2

公开(公告)日：2012-01-10

申请号：US12025153

申请日：2008-02-04

申请人： Robert Jansen ,  John Kerr ,  Anthony Baiada

发明人： Robert Jansen ,  John Kerr ,  Anthony Baiada

IPC分类号： C13K1/08

CPC分类号： C13K3/00 ,  C13B20/14

摘要： We disclose a method of inverting sucrose, including (i) determining an initial solids concentration of an aqueous sucrose solution (solidsi), an initial bed volume (BVi) of a sucrose inversion resin system, a minimum target inversion percentage (invert %min), a maximum target inversion percentage (invert %max), a target maximum hydroxymethylfuran (HMF) concentration (HMFmax), a minimum target pH (pHmin), or a maximum target pH (pHmax); (ii) contacting the sucrose inversion resin system with the aqueous sucrose solution under conditions of aqueous solution flow rate in BVi/hr (ratep) and aqueous solution temperature in ° C. (temperaturep) to produce an inverted sucrose solution having an inversion percentage (invert %product), an HMF concentration (HMFproduct), and a pH (pHproduct); (iii) observing an instantaneous inversion percentage (invert %inst), an instantaneous HMF concentration (HMFinst), or an instantaneous pH (pHinst) of the inverted sucrose solution; and, if invert %inst invert %max, HMFinst>HMFmax, pHinst pHmax; (iv) changing at least one of the aqueous solution flow rate or the aqueous solution temperature such that invert %min≦invert %product≦invert %max, HMFproduct≦HMFmax, or pHmin≦pHproduct≦pHmax. We also disclose a computing apparatus capable of use in performing a method of inverting sucrose.

摘要翻译： 我们公开了一种蔗糖翻转方法，包括（i）测定蔗糖反应树脂体系的初始固体浓度，蔗糖反转树脂体系的初始床体积（BVi），最小目标反转百分比（反转百分比） ，最大目标反转百分比（反转百分比最大值），目标最大羟甲基呋喃（HMF）浓度（HMFmax），最小目标pH（pHmin）或最大目标pH（pHmax））; （ii）在水溶液流速（BVi / hr（速率））和水溶液温度（℃）（℃）下的条件下，将蔗糖反转树脂体系与蔗糖溶液的蔗糖溶液接触，得到反转百分比的倒转蔗糖溶液 转化％产物），HMF浓度（HMF产物）和pH（pH值产物）; （iii）观察反转蔗糖溶液的瞬时反转百分率（反转％inst），瞬时HMF浓度（HMFinst）或瞬时pH（pHinst）; 并且，如果反转％inst invert％max，HMFinst> HMFmax，pHinst pHmax; （iv）改变水溶液流速或水溶液温度中的至少一个，使得反相％min和nlE反相％max，HMFproduct＆NlE; HMFmax或pHmin＆amp; NlE; pH值＆amp; NlE; pHmax。 我们还公开了一种能够用于执行蔗糖翻转方法的计算装置。

公开(公告)号：US20090299055A1

公开(公告)日：2009-12-03

申请号：US12412832

申请日：2009-03-27

申请人： James Edwin Wiley, JR. ,  John Kerr ,  Robert Jansen ,  Gordon Walker

发明人： James Edwin Wiley, JR. ,  John Kerr ,  Robert Jansen ,  Gordon Walker

IPC分类号： C07H1/06

CPC分类号： C07H1/06 ,  C07H5/02

摘要： A process for the recovery of a carbohydrate selected from sucralose and sucralose-6-esters from an aqueous feed stream is disclosed. The process comprises extracting the feed stream with an organic solvent, such as ethyl acetate, back extracting the resulting carbohydrate-containing organic extract with an aqueous solvent, and either crystallizing the carbohydrate from the organic solvent or replacing the organic solvent with water and crystallizing the carbohydrate from water. The process results in an increased overall yield of the carbohydrate.

摘要翻译： 公开了从含水进料流中回收选自三氯蔗糖和三氯蔗糖-6-酯的碳水化合物的方法。 该方法包括用有机溶剂如乙酸乙酯萃取进料流，用水溶剂反萃取所得含碳水化合物的有机萃取物，并将碳水化合物从有机溶剂中结晶或用水代替有机溶剂，并使 来自水的碳水化合物 该方法导致碳水化合物的总收率提高。

公开(公告)号：US20090299054A1

公开(公告)日：2009-12-03

申请号：US12413955

申请日：2009-03-30

申请人： Robert Jansen ,  Gordon Walker ,  John Kerr ,  Anthony Baiada

发明人： Robert Jansen ,  Gordon Walker ,  John Kerr ,  Anthony Baiada

IPC分类号： C13K13/00

CPC分类号： C07H5/02

摘要： A process for the extraction of sucralose from an aqueous solution containing at least sucralose, other chlorinated saccharides, sodium chloride and dimethylammonium chloride into an organic solvent for sucralose by contacting said organic solvent with said solution to extract sucralose into the organic solvent. The ratio of sodium chloride to dimethylammonium chloride in the aqueous solution is increased prior to or during contact so as to increase the partition coefficient of sucralose into said organic solvent.

摘要翻译： 通过使所述有机溶剂与所述溶液接触将三氯半乳蔗糖，其它氯化糖，氯化钠和二甲基氯化铵的水溶液提取到三氯半乳蔗糖的有机溶剂中以将三氯蔗糖萃取到有机溶剂中的方法。 在接触之前或接触期间，水溶液中氯化钠与二甲基氯化铵的比例增加，从而增加三氯蔗糖分配成所述有机溶剂的分配系数。

公开(公告)号：US20090258106A1

公开(公告)日：2009-10-15

申请号：US11917915

申请日：2006-07-14

申请人： Robert Jansen ,  David Sass ,  Gordon Walker ,  Eric Lutz

发明人： Robert Jansen ,  David Sass ,  Gordon Walker ,  Eric Lutz

IPC分类号： A23L1/105 ,  C13K1/06 ,  C12C11/07 ,  A23L1/186 ,  C12C3/12 ,  C13K1/02 ,  A23K1/12 ,  A23L1/10 ,  C12H1/14

CPC分类号： A23J1/12 ,  A23K10/37 ,  A23K20/147 ,  A23K20/163 ,  A23K50/80 ,  A23L7/104 ,  A23L7/115 ,  A23L29/35 ,  A23L33/22 ,  C13K1/02 ,  C13K1/06 ,  Y02A40/818 ,  Y02P60/877

摘要： A corn wet-milling process comprises steeping corn kernels in an aqueous liquid, which produces softened corn; milling the softened corn in a first mill, which produces a first milled corn; separating germ from the first milled corn, thereby producing a germ-depleted first milled corn; milling the germ-depleted first milled corn in a second mill, producing a second milled corn; separating the second milled corn into a first starch/protein portion that comprises starch and protein and a first fiber portion that comprises fiber, starch, and protein; milling the first fiber portion in a third mill, which produces a milled fiber material that comprises fiber, starch, and protein; separating at least some of the starch and protein in the milled fiber material from the fiber therein, producing a second fiber portion that comprises fiber and starch and a second starch/protein portion that comprises starch and protein; and contacting the second fiber portion with at least one enzyme to convert at least some of the starch therein to dextrose. The converted material is screened using one or more screens to separate the fiber from the liquor. The liquor can be fermented to ethanol, or refined to dextrose. The fiber can be pressed and dried as an animal feed.

公开(公告)号：US20090044737A1

公开(公告)日：2009-02-19

申请号：US12173247

申请日：2008-07-15

申请人： Raymond C. Ganga ,  Greg Imig ,  Blake McBurney ,  Robert Jansen ,  John Kerr ,  Steven J. Reust

发明人： Raymond C. Ganga ,  Greg Imig ,  Blake McBurney ,  Robert Jansen ,  John Kerr ,  Steven J. Reust

IPC分类号： F23G5/08 ,  B01D53/56 ,  F23G5/46 ,  F23J15/02 ,  F23B99/00 ,  F23J15/06 ,  F23G5/24

CPC分类号： F23G7/10 ,  F23G5/12 ,  F23G5/46 ,  F23G2202/106 ,  F23G2206/20 ,  F23G2900/00001 ,  F23G2900/7012 ,  F23J7/00

摘要： A method for extracting energy from biomass depleted of at least some carbohydrate, at least some oil, or both by a) introducing the biomass into a vertically elongated combustion chamber having i) at least one suspension burner at the top of the combustion chamber which is capable of projecting a flame down the axis of the combustion chamber, ii) a heat transfer apparatus having at least a portion of a heat collection surface located radially from the flame and below the burner, and iii) an exhaust opening located below the flame and below at least a portion of the heat collection surface; b) combusting the biomass to yield a mixture containing hot flue gas and molten ash above the exhaust opening; c) transferring heat from the hot flue gas to at least a portion of the heat collection surface substantially by radiation prior to any substantial contact of ash to a surface of the combustion chamber, to yield a mixture containing warm flue gas and non-molten ash and having a lower molten ash content than the mixture yielded by the combusting step; and d) cooling the warm flue gas with cold gas, to yield a mixture containing cool flue gas and non-molten ash and having a lower molten ash content than the mixture yielded by the transferring step.

摘要翻译： 一种用于从生物量中提取能量的方法，所述方法是从至少一些碳水化合物，至少一些油或两者中消耗的能量，通过以下方法：a）将生物质引入垂直细长的燃烧室，所述燃烧室具有：i）在燃烧室顶部的至少一个悬浮燃烧器， 能够沿着燃烧室的轴线向下突出火焰，ii）传热装置，其具有位于燃烧器的径向位于燃烧器下方的集热表面的至少一部分，以及iii）位于火焰下方的排气口， 在集热表面的至少一部分下面; b）燃烧生物质以产生在排气口上方含有热烟道气和熔融灰渣的混合物; c）在灰分与燃烧室的任何实质接触之前，基本上通过辐射将热量从热烟道气传递到至少一部分集热表面，以产生含有热烟气和非熔融灰的混合物 并且具有比通过燃烧步骤产生的混合物更低的熔融灰分含量; 和d）用冷气体冷却暖烟道气，得到含有冷烟道气和非熔融灰分的混合物，其熔融灰分含量低于转移步骤产生的混合物。

公开(公告)号：US20080114093A1

公开(公告)日：2008-05-15

申请号：US11869319

申请日：2007-10-09

申请人： Didier Lagneaux ,  Vicky M.J. Bertels ,  Robert Jansen

发明人： Didier Lagneaux ,  Vicky M.J. Bertels ,  Robert Jansen

IPC分类号： C08K3/32 ,  C08J3/22

CPC分类号： C08G18/7664 ,  C08K3/014 ,  C08K3/32 ,  C08L75/04 ,  C08L2666/20

摘要： Thermoplastic polyurethane (TPU) compositions are disclosed comprising TPU polymer, polyisocyanate, and a salt of zirconium phosphate. The compositions have enhanced thermal properties, good processability, and good hydrolysis resistance. Processes are also disclosed to combine the ingredients by melt mixing or to prepare the compositions in-situ as the TPU is being polymerized.

摘要翻译： 公开了包含TPU聚合物，多异氰酸酯和磷酸锆盐的热塑性聚氨酯（TPU）组合物。 该组合物具有增强的热性能，良好的加工性能和良好的耐水解性。 还公开了通过熔融混合来组合这些成分的方法或者在TPU被聚合时原位制备组合物。

公开(公告)号：US20070058234A1

公开(公告)日：2007-03-15

申请号：US11226549

申请日：2005-09-14

申请人： Eric Oettinger ,  Robert Jansen ,  Arthur Turner

发明人： Eric Oettinger ,  Robert Jansen ,  Arthur Turner

IPC分类号： G02B26/08

CPC分类号： G02B26/101 ,  H04N1/047 ,  H04N1/113 ,  H04N2201/02416 ,  H04N2201/02425 ,  H04N2201/0471 ,  H04N2201/04729 ,  H04N2201/04731 ,  H04N2201/04734 ,  H04N2201/04744 ,  H04N2201/04755 ,  H04N2201/04789 ,  H04N2201/04791

摘要： A method for maintaining the amplitude of oscillations of a mirror system comprising a high-Q resonant mirror driven by a high speed drive signal. Sensors monitor the sweep amplitude of the high-Q resonant mirror and a parameter of the drive signal is adjusted to maintain the sweep amplitude of the mirror at a constant value. According to one embodiment, the frequency of the drive signal is adjusted to more closely track the resonant frequency of the mirror, and according to another embodiment, the amplitude of the drive signal is increased to increase the amplitude of the sweep motion of the mirror. According to a third embodiment, the sweep amplitude may be maintained by adjusting both the drive signal amplitude and the drive signal frequency.

摘要翻译： 一种用于维持包括由高速驱动信号驱动的高Q谐振反射镜的反射镜系统的振荡幅度的方法。 传感器监视高Q谐振反射镜的扫描幅度，并调整驱动信号的参数以将反射镜的扫描幅度保持在恒定值。 根据一个实施例，调节驱动信号的频率以更紧密地跟踪反射镜的谐振频率，并且根据另一实施例，增加驱动信号的幅度以增加反射镜的扫描运动的幅度。 根据第三实施例，可以通过调节驱动信号幅度和驱动信号频率来维持扫描振幅。