摘要:
A description is given of polyisocyanates of the formula I in which R and R′ are identical or different and are alkyl groups having 1-4 carbon atoms and n is on average from 1.5 to 5 and also of a process for preparing these polyisocyanates in which a polyamine of the formula II in which R, R′, and n are as defined above, is reacted with phosgene. The new polyisocyanates are suitable for producing crosslinked polyurethanes from reaction mixtures with low solvent content and for producing coating compositions or adhesives. Also described are the coating compositions and adhesives, and their use.
摘要:
Method for manufacturing an optically readable digital storage disk having an arbitrary edge contour from a CD-R disk blank, as well as a CD-R disk blank suitable for the manufacture of a storage disk, starts with a blank having a plastic disk that is provided with a reflective layer on the side opposite a scanning side. The reflective layer, which is connected with the plastic disk along a first line, is welded with the plastic disk along an arbitrarily shaped second line that is closed on itself. Afterwards, the storage disk is cut from the CD-R disk blank along a third line that corresponds to the edge contour.
摘要:
Functionalized cyclopentene-derived oligomer mixtures are prepared by reacting oligomer mixtures which contain ethyleneic double bonds in one or more reaction steps starting from cyclopentene-derived oligomer mixtures of the formula I R1R2C═[═CH—(CH2)3—CH═]n═CR3R4 (I) where n is an integer from 1 to 15, and R1, R2, R3 and R4 are, independently of one another, hydrogen or alkyl, and are used as described.
摘要:
Trimming process for adapting a first control loop of a controllable, automatically controlled reference system, which is or represents an aircraft, to a second control loop which simulates the reference system, Flying condition values including controlled variables, which are returned in each control loop for the purpose of the control, are detected, and both control loops are acted upon by the same desired input data. In the first process loop, a conversion of the unreturned flying condition values of the airplane model takes place to the values of the corresponding flying condition values of the reference system. The second process loop is provided for the adaptation of the returned condition values of the airplane simulation system to the corresponding condition values of the reference system.
摘要:
A carbonyl compound or a mixture of two or more carbonyl compounds is catalytically hydrogenated in the presence of a Raney copper catalyst in the form of nuggets.
摘要:
Methylolalkanal of the formula II (R=CH2OH, C1-C22-alkyl, aryl or C6-C22-aralkyl) is prepared spe-wise by a) reacting a C2-C24-aldehyde with formaldehyde in the presence of a tertiary amine, b) separating the reaction mixture i) into a bottom fraction comprising the compound of formula II and an incompletely methylolated compound of the formula III and a distillate stream comprising unconverted or partially converted starting materials, or ii) into an aqueous phase and an organic phase, and recycling the distillate stream or the organic phase to a), and c) subjecting the bottom fraction or the aqueous phase i) to a catalytic or thermal reaction to convert the compound of formula III to the compound of formula II and to a corresponding methylene compound of formula IV (R′=H or R) and ii) separating the reaction product into an overhead stream comprising the compound of formula IV and unconverted formaldehyde which is recycled to a), and a bottom fraction comprising the compound of formula II.
摘要:
Amines are prepared by reacting primary or secondary alcohols, aldehydes or ketones with nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines at elevated temperatures and superatmospheric pressures in the presence of hydrogen and of a catalyst containing copper and oxygen-containing compounds of titanium by a process in which the catalyst is used in the form of moldings which have been prepared with the addition of metallic copper powder.
摘要:
A catalyst comprises, based on the total weight of the catalyst,0.1-6% by weight of cobalt, nickel or a mixture thereof,0.001-25% by weight of ruthenium,0-10% by weight of copper and0-5% by weight of promoterson a porous metal oxide carrier.It preferably comprises 0.1-3% by weight of cobalt and 0.1-3% by weight of nickel. It can be used in hydrogenation reactions, dehydrogenation reactions or hydrogenation/dehydrogenation reactions, in particular in the amination of alkylene oxides, alcohols, aldehydes or ketones with ammonia or primary or secondary amines.