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公开(公告)号：US4652541A
公开(公告)日：1987-03-24
申请号：US642462
申请日：1984-08-20
CPC分类号： C08F10/00
摘要： A catalyst component for polymerization of olefins which is prepared by reacting a magnesium alkoxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with a carboxylic acid halide and/or carboxylic acid anhydride, and contacting the resulting contact product with a titanium compound.
摘要翻译： 一种用于烯烃聚合的催化剂组分，其通过使烷氧基镁与具有至少一个氢 - 硅键的硅化合物反应制备，使反应产物与羧酸酰卤和/或羧酸酐接触，并使所得的接触产物 与钛化合物。
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公开(公告)号：US4625003A
公开(公告)日：1986-11-25
申请号：US771392
申请日：1985-08-30
CPC分类号： C08F10/00
摘要： A titanium halide containing catalyst component for polymerization of olefins which is prepared by reacting a magnesium hydrocarbyloxide with a silicon compound having at least one hydrogen-silicon bond, contacting the reaction product with an electron donor compound, contacting the resulting contact product two or more times with a titanium halide and between one of the multiple titanium halide contacts, contacting the titanium halide contacted solid with a halide of an element selected from the group consisting of elements of Groups IIIa, IVa, and Va of the Periodic Table of elements.
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公开(公告)号：US4588793A
公开(公告)日：1986-05-13
申请号：US765763
申请日：1985-08-15
CPC分类号： C08F10/00
摘要： A titanium-containing catalyst component for polymerization of olefins which is prepared by reacting a magnesium hydrocarbyl oxide with a silicon compound having a hydrogen-silicon bond, contacting the reaction product with an electron donor compound, contacting the resulting contact product with an organoaluminum compound and further with a titanium compound.
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公开(公告)号：US4401799A
公开(公告)日：1983-08-30
申请号：US59414
申请日：1979-07-20
申请人： Hiroshi Ueno , Eiji Sezaki , Naomi Inaba , Tokuo Makishima , Koh Watanabe , Shozo Wada
发明人： Hiroshi Ueno , Eiji Sezaki , Naomi Inaba , Tokuo Makishima , Koh Watanabe , Shozo Wada
CPC分类号： C08F10/00
摘要： A titanium trichloride catalytic complex is produced by reducing titanium tetrachloride with an organo-metal compound and then treating the resulting reduced solids product with a chlorinated saturated aliphatic hydrocarbon having three to eight carbon atoms in the presence of a complexing agent. The resulting titanium trichloride complex composition, when employed as a co-catalyst with an organo-metal compound for Ziegler-type catalysts in polymerization of .alpha.-olefins, results in uniform polymer grains with unexpectedly high polymerization activity and high stereoregular polymer yielding ratios.
摘要翻译： 通过用有机金属化合物还原四氯化钛然后在络合剂的存在下用具有3-8个碳原子的氯化饱和脂族烃处理所得的还原固体产物来制备三氯化钛催化络合物。 所得到的三氯化钛复合物组合物当用作α-烯烃聚合中的齐格勒型催化剂的有机金属化合物的助催化剂时，导致均匀的聚合物颗粒具有意想不到的高聚合活性和高立体规则聚合物产率。
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25.发明授权Catalyst component for polymerization of alpha-olefins and method for using the same 失效用于α-烯烃聚合的催化剂组分及其使用方法
公开(公告)号：US4370257A
公开(公告)日：1983-01-25
申请号：US177024
申请日：1980-08-11
申请人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Masafumi Imai , Hiroshi Ueno , Naomi Inaba , Makoto Yoda , Shozo Wada
摘要： A process for producing a magnesium containing support for titanium comprising contacting magnesium metal, a halogenated hydrocarbon and a compound represented by the formula X'.sub.m C(OR').sub.4-m wherein X' is a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.10 alkyl, aryl, cycloalkyl or halogenated alkyl, aryl, cycloalkyl group, R' is a C.sub.1 -C.sub.20 alkyl, aryl or cycloalkyl group and m is 0, 1 or 2 to form a magnesium-containing solid represented by the formula R'OMgX and thereafter contacting the magnesium-containing solid with a Lewis base or a compound which can form an ester such as benzoyl chloride and a titanium compound such as titanium tetrachloride. The obtained magnesium supported titanium composition is useful as a catalyst component in combination with a co-catalyst organoaluminum compound for the polymerization of olefins.
摘要翻译： 一种用于制备含镁载体的钛的方法，包括使镁金属，卤代烃和由式X'mC（OR'）4-m表示的化合物接触，其中X'是氢原子，卤素原子或C1- C10烷基，芳基，环烷基或卤代烷基，芳基，环烷基，R'为C1-C20烷基，芳基或环烷基，m为0,1或2，形成式R'OMgX 然后使含镁固体与路易斯碱或可形成酯的化合物如苯甲酰氯和钛化合物如四氯化钛接触。 获得的负载镁的钛组合物可用作催化剂组分与用于烯烃聚合的助催化剂有机铝化合物。
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26.发明授权
公开(公告)号：US4242230A
公开(公告)日：1980-12-30
申请号：US29081
申请日：1979-04-11
申请人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
CPC分类号： C08F10/00 , Y10S526/903 , Y10S526/906
摘要： A supported titanium catalyst, adaptable for use in the stereoregular polymerization of .alpha.-olefins, is produced by treating a supported titanium-containing solid, obtained by cogrinding a magnesium halide, tetravalent titanium halide and organic acid ester, with a hydrocarbon, organo halogen compound or mixture thereof with heating. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.
摘要翻译： 一种适用于α-烯烃的有规立体聚合的负载型钛催化剂，是通过将卤化镁，四价卤化钛和有机酸酯与碳氢化合物，有机卤素化合物 或其混合物加热。 所得到的负载型钛催化剂在用作α-烯烃的立构规整聚合方法中用作催化剂体系的有机铝催化剂组分的钛组分时，产生高聚合活性和出乎意料的高立体规则聚合物产率。
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27.发明授权Process for the production of a catalyst component for use in the polymerization of alphaolefins 失效用于生产用于α-烯烃聚合的催化剂组分的方法
公开(公告)号：US4127504A
公开(公告)日：1978-11-28
申请号：US744942
申请日：1976-11-24
申请人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
CPC分类号： C08F10/00
摘要： A process for the production of a catalyst component for use in the polymerization of .alpha.-olefins, which comprises reducing titanium tetrachloride with an organo aluminum compound having the general formula Al Rn X.sub.3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, x represents a halogen atom and n represents a suitable numeral between o
摘要翻译： 一种用于生产用于α-烯烃聚合的催化剂组分的方法，其包括用具有通式Al Rn X3-n的有机铝化合物还原四氯化钛，其中R表示具有1至18个碳原子的烃基 ，x表示卤素原子，n表示o
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28.发明授权Process for the production of a catalyst component for use in the polymerization of .alpha.-olefins 失效制备用于聚合{60-烯烃的催化剂组分的方法
公开(公告)号：US4064069A
公开(公告)日：1977-12-20
申请号：US704310
申请日：1976-07-06
申请人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
发明人： Hiroshi Ueno , Naomi Inaba , Tokuo Makishima , Shozo Wada
摘要： This invention relates to a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity and having a low particle size distribution, which comprises;1. reducing TiCl.sub.4 by diethylaluminum chloride (DEAC), thereby forming a reduced solid (TiCl.sub.3),2. removing the aluminum compounds from the reduced catalyst,3. treating the said reduced solid with the mixture or complex of TiCl.sub.4 and diisoamylether (IAE) and4. separating the solid catalyst from the mixture.The aluminum compounds may be removed by washing with a complexing agent therefor; in a preferred embodiment the complexing agent is di-n-butyl ether.
摘要翻译： 本发明涉及丙烯聚合的催化剂组合物，具有高活性并产生具有高立构规整性和低粒度分布的聚丙烯，其包括： 1.通过二氯化铝（DEAC）还原TiCl 4，从而形成还原固体（TiCl 3），2.从还原催化剂中除去铝化合物，3.用TiCl 4和二异戊醚（IAE）的混合物或复合物处理固体， 和4.从混合物中分离固体催化剂。
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公开(公告)号：US4711940A
公开(公告)日：1987-12-08
申请号：US925843
申请日：1986-10-29
CPC分类号： C08F10/00
摘要： A process for preparing a catalyst component for the polymerization of olefins which comprises the steps of contacting (a) a magnesium dialkoxide soluble in an inert solvent, (b) a silicon compound having the hydrogen-silicon bond, and (c) an electron donor compound with one another in the presence of an inert solvent, and contacting the resulting reaction product with (d) a titanium compound.
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30.发明授权
公开(公告)号：US4348507A
公开(公告)日：1982-09-07
申请号：US173214
申请日：1980-07-28
申请人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
发明人： Hiroshi Ueno , Masafumi Imai , Naomi Inaba , Makoto Yoda , Shozo Wada
CPC分类号： C08F10/00 , Y10S526/906
摘要： A supported titanium catalyst is produced by cogrinding, in combination, a magnesium halide, tetravalent titanium halide, organic acid ester, and an organic halogen compound. The resulting supported titanium catalyst, when employed as a titanium component with an organo aluminum catalyst component for the catalyst system in a process for stereoregular polymerization of .alpha.-olefins, produces high polymerization activity and unexpectedly high stereoregular polymer yielding ratios.
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