Binder combinations based on polyacrylate dispersions
    36.
    发明申请
    Binder combinations based on polyacrylate dispersions 审中-公开
    基于聚丙烯酸酯分散体的粘合剂组合

    公开(公告)号:US20080214766A1

    公开(公告)日:2008-09-04

    申请号:US12072815

    申请日:2008-02-28

    IPC分类号: C08F120/18

    CPC分类号: C09D133/08

    摘要: Aqueous polyacrylate dispersions comprising hydrophobic co-solvents are provided. The dispersions are prepared from copolymers P) which are comprised of I) a hydroxy-functional, hydrophobic polymer containing as structural monomers Ia) (meth)acrylic acid esters having from C1- to C18-hydrocarbon radicals in the alcohol part and/or vinyl aromatic compounds and/or vinyl esters and Ib) hydroxy-functional monomers; and II) a hydroxy-functional, hydrophilic polymer containing as structural components IIa) (meth)acrylic acid esters having from C1- to C18-hydrocarbon radicals in the alcohol part and/or vinyl aromatic compounds and/or vinyl esters, IIb) hydroxy-functional monomers and IIc) acid-functional monomers, and as solvents C) one or more solvents selected from the group consisting of hydrophobic, water-immiscible hydrocarbons having an initial boiling point of from 170° C. to 250° C. and a dry point of from 200° C. to 280° C., to a process for their preparation and to their use as binders for the production of blister-free coatings.

    摘要翻译: 提供了包含疏水性共溶剂的聚丙烯酸酯水分散体。 分散体由共聚物P)制备,其由I)含有作为结构单体的羟基官能的疏水性聚合物Ia)(甲基)丙烯酸酯,其具有C 1至C 12 - 醇部分和/或乙烯基芳族化合物和/或乙烯基酯中的18-烃基和Ib)羟基官能单体; 和II)含有作为结构成分的结构组分的羟基官能的亲水性聚合物IIa)在醇中具有C 1至C 18 - 烃基的(甲基)丙烯酸酯 部分和/或乙烯基芳族化合物和/或乙烯基酯,IIb)羟基官能单体和IIc)酸官能单体和溶剂C)一种或多种选自疏水性,水不混溶烃的溶剂,其具有 初始沸点为170℃至250℃,干燥温度为200℃至280℃,其制备方法和用作生产无泡涂料的粘合剂 。

    Low-solvent, OH-functional dispersions
    38.
    发明授权
    Low-solvent, OH-functional dispersions 有权
    低溶剂,OH官能的分散体

    公开(公告)号:US07199178B2

    公开(公告)日:2007-04-03

    申请号:US11041774

    申请日:2005-01-24

    摘要: A process for preparing copolymer dispersions that includes subjecting A) one or more vinyl monomer mixtures containing a) OH-free (meth)acrylic esters and/or vinylaromatics, b) hydroxy-functional vinyl monomers and/or hydroxy-functional (meth)acrylic esters, c) ionic and/or potentially ionic monomers capable of free-radical copolymerization, and d)optionally further monomers, other than the compounds of components a)–c), capable of free-radical copolymerization; to free-radical polymerization in the presence of e) compounds according to formula (I) where R1 is an aliphatic, araliphatic or aromatic radical having 1 to 18 carbon atoms, R2 is H or CH3, R3, R4 are identical or different aliphatc radicals having 1 to 7 carbon atoms and n is 1 to 4; and subsequently dispersing the resultant copolymer B) before or after addition of a neutralizing agent C) in water. The resulting dispersions can be used to coat substrates.

    摘要翻译: 一种制备共聚物分散体的方法,其包括使A)一种或多种乙烯基单体混合物含有a)不含OH的(甲基)丙烯酸酯和/或乙烯基芳烃,b)羟基官能的乙烯基单体和/或羟基官能(甲基)丙烯酸 酯,c)能够进行自由基共聚的离子和/或潜在的离子单体,和d)任何其它单体,除了能够自由基共聚的组分a)-c)的化合物之外; 在e)根据式(I)的化合物存在下进行自由基聚合,