摘要:
The exhaust gas purification device according to the present invention utilizes two NOx absorbents in order to remove NOx from the exhaust gas of an engine operated at a lean air-fuel ratio. The NOx absorbents are disposed, in series, in the exhaust passage of the engine and a nozzle for supplying a reducing agent is disposed in the exhaust passage at a position between the two NOx absorbents. Further, the device includes switching valves for changing the direction of the exhaust gas flow in the exhaust gas passage. When the switching valves are set to direct the exhaust gas flow to one direction, the exhaust gas first flows through one of the NOx absorbents (first NOx absorbent), and after passing through the first NOx absorbent, the reducing agent is supplied to the exhaust gas before it flows into the other NOx absorbent (second NOx absorbent). Thus, the first NOx absorbent absorbs NOx in the exhaust gas, and the NOx absorbed by the second NOabsorbent is released from the second NOx absorbent. When the switching valves are switched, the exhaust gas flows in the opposite direction, and flows through the second NOx absorbent and the first NOx absorbent in this order. In this case, the second NOx absorbent absorbs NOx in the exhaust gas, and the NOx absorbed by the first NOx absorbent is released and reduced to N2. Therefore, by reversing the direction of the exhaust gas periodically, the absorbing operation of NOx and releasing/reducing operation of NOx are performed by two NOx absorbents alternately. Thus, it becomes possible to remove NOx in the exhaust gas continuously while the NOx absorbents are prevented from being saturated by the absorbed NOx.
摘要:
An exhaust manifold (7) of an engine (1) is connected to a three way (TW) catalyst (8a), and the TW catalyst (8a) is connected to an NH3 adsorbing and oxidizing (NH3-AO) catalyst (10a). The engine (1) performs the lean and the rich engine operations alternately and repeatedly. When the engine (1) performs the rich operation and thereby the exhaust gas air-fuel ratio of the exhaust gas flowing into the TW catalyst (8a) is made rich, NOx in the inflowing exhaust gas is converted to NH3 in the TW catalyst (8a). The NH3 is then adsorbed in the NH3-AO catalyst (10a). Next, when the engine (1) performs the lean operation and thereby the exhaust gas air-fuel ratio of the exhaust gas flowing into the TW catalyst (8a) is made lean, NOx in the exhausted gas passes through the TW catalyst (8a), and flows into the NH3-AO catalyst (10a). At this time, NH3 adsorbed in the catalyst (10a) is desorbed therefrom, and reduces the inflowing NOx.
摘要:
An NOx occluding and reducing catalyst is disposed in an exhaust gas passage of an internal combustion engine that operates at a lean air-fuel ratio. When the engine is operating at a lean air-fuel ratio, the NOx occluding and reducing catalyst absorbs NOx in the exhaust gas. To release NOx, the engine is operated at a rich air-fuel ratio so that the exhaust gas flowing into the NOx occluding and reducing catalyst acquires a rich air-fuel ratio. While the engine is operated in a region of moderate lean air-fuel ratios of from the stoichiometric air-fuel ratio to an air-fuel ratio of about 20 at the time when the engine operating air-fuel ratio is changing from a lean air-fuel ratio operation to a rich air-fuel ratio operation, an electronic control unit (ECU) of the engine injects secondary fuel, that does not contribute to combustion, into the cylinders of the engine through the direct cylinder fuel injection valves in the expansion stroke or the exhaust stroke of the cylinders, so that the exhaust gas flowing into the NOx occluding and reducing catalyst acquires a rich air-fuel ratio. This prevents unpurified NOx from flowing out of the NOx occluding and reducing catalyst at the time when the engine operating air-fuel ratio is changed.
摘要:
An exhaust purifying apparatus purifies an unburnt gas component, such as unburnt hydrocarbon (HC), discharged from an internal combustion engine without fail and prevents the unburnt hydrocarbon from being discharged into the atmosphere. In order to achieve this, the exhaust gas purifying apparatus is provided with a plurality of exhaust passages connected to the internal combustion engine. A joint exhaust passage is formed by merging the exhaust passages and an exhaust gas flows through the joint exhaust passage. An adsorption/desorption unit is provided in each of the exhaust passages for adsorbing an unburnt gas component contained in the exhaust gas that flows through each of the exhaust passages at a temperature lower than a predetermined temperature. The adsorption/desorption unit desorbs the adsorbed unburnt gas component at a temperature equal to or higher than the predetermined temperature. A desorption/adjustment mechanism synchronizes timing of the unburnt gas component desorbed from the adsorption/desorption units into the exhaust purifying units.
摘要:
A three-way catalyst (8a) is connected to a first cylinder group 1a. The exhaust gas of the first cylinder group (1a), which has passed through the three-way catalyst (8a), and the exhaust gas of a second cylinder group (1b) are introduced to an exhaust gas purifying catalyst (14). The second cylinder group (1b) performs the lean operation. The first cylinder group (1a) performs the rich operation to synthesize NH.sub.3 from NO.sub.X in the exhaust gas of the first cylinder group (1a) in the three-way catalyst (8a). In the exhaust gas purifying catalyst (14), NO.sub.X in the exhaust gas of the second cylinder group 1b is purified by NH.sub.3 from the three-way catalyst (8a). The amount of HC flowing to the three-way catalyst (8a) is obtained. When the HC amount exceeds a predetermined amount, the first cylinder group 1a must perform the lean operation temporarily, to thereby maintain the excellent catalytic activity of the three-way catalyst (8a).
摘要:
A device for purifying exhaust gas includes an HC adsorbent and an exhaust gas purifying catalyst disposed in an exhaust gas passage in this order from the upstream side. The exhaust gas purifying catalyst is provided with an O.sub.2 storage capability, i.e., the exhaust gas purifying catalyst is capable of absorbing oxygen in the exhaust gas when the air-fuel ratio of the exhaust gas is lean, and is capable of releasing the absorbed oxygen when the air-fuel ratio of the exhaust gas becomes rich. When the engine starts, the HC adsorbent adsorbs HC in the exhaust gas. When the temperature of the exhaust gas becomes high, the HC adsorbent releases the adsorbed HC. The device also includes an engine control unit which operates the engine at a lean air-fuel ratio during a predetermined period before the releasing of the HC from the HC adsorbent occurs. Therefore, oxygen is absorbed and stored in the exhaust gas purifying catalyst before the releasing of HC occurs. When the releasing of HC from the HC adsorbent occurs, the air-fuel ratio of the exhaust gas flowing into the exhaust gas purifying catalyst becomes rich due to the HC released from the HC adsorbent. This causes the exhaust gas purifying catalyst to release the absorbed oxygen, and the HC in the exhaust gas is purified by the exhaust gas purifying catalyst using the released oxygen.
摘要:
The emission control system of the present invention removes the small amounts of polluting gases released from various parts of the automobile. These polluting gases are released from, for example, fuel oozing out from connections of the pipes in the fuel system, lubricating oil oozing out from engine body, and solvents and adhesives remaining in the interior and exterior parts of the automobile. In the emission control system of the present invention, collectors and suction pipes are provided. The collectors are disposed at the parts of the automobile from where the polluting gases are released in such a manner that the collectors enclose these parts. The suction pipes connect the respective collectors to an intake nose of an air cleaner disposed in an intake air passage of the engine. Therefore, the polluting gases released from various parts of the automobile are drawn into the engine through the respective suction pipes before they diffuse into the atmosphere, and are burned in the engine. Thus, according to the present invention, the polluting gases released from various parts of the automobile are prevented from diffusing into the atmosphere.
摘要:
The method for purifying combustion exhaust gas according to the present invention utilizes a NH.sub.3 decomposing catalyst. The NH.sub.3 decomposing catalyst in the present invention is capable of converting substantially all of the NH.sub.3 in the combustion exhaust gas to N.sub.2 when the air-fuel ratio of the exhaust gas is lean and the temperature of the catalyst is within a predetermined optimum temperature range. Further, when the exhaust gas contains NO.sub.x in addition to NH.sub.3, the NH.sub.3 decomposing catalyst is capable of reducing the NO.sub.x in the optimum temperature range even though the air-fuel ratio of the exhaust gas is lean. In the present invention, the conditions of the exhaust gas containing NO.sub.x are adjusted before it is fed to the NH.sub.3 decomposing catalyst in such a manner that the temperature of the exhaust gas is within the optimum temperature range and the air-fuel ratio of the exhaust gas is lean. Further, NH.sub.3 is added to the exhaust gas before it is fed to the NH.sub.3 decomposing catalyst. Therefore, a lean air-fuel ratio exhaust gas, at a temperature within the optimum temperature range, which contains both the NO.sub.x and NH.sub.3 is fed to the NH.sub.3 decomposing catalyst, and the NO.sub.x, as well as the NH.sub.3, in the exhaust gas is completely resolved by the NH.sub.3 decomposing catalyst.
摘要:
A fuel storing device for an automobile comprises a flexible separator means disposed in a fuel storage container for separating the inside of the fuel storage container into a fuel storage portion and a space portion and a fuel vapor preventing means for preventing fuel vapor from gathering in a space between a surface of fuel and said separator means. The fuel vapor preventing means introduces fuel vapor which appears over a surface of liquid fuel into a vapor draining pipe.
摘要:
An exhaust gas purification device comprising a three way catalyst, an oxidizing catalyst and a NOx absorbent which are arranged in this order in the exhaust passage. A rich air-fuel mixture is burned in the combustion chamber, and the exhaust gas discharged from the engine is initially introduced into the three way catalyst. Secondary air is fed into the exhaust passage between the three way catalyst and the oxidizing catalyst so that the air-fuel ratio of the exhaust gas flowing into the oxidizing catalyst and the NOx absorbent becomes lean.