摘要:
A facile mechanochemical intercalation approach was adopted to immobilize ionic liquids into layered materials. The immobilized ionic liquids were found to be useful as catalysts for the coupling reaction of CO2 and propylene oxide to synthesize propylene carbonate. The immobilized ionic liquid exhibited similar reactivity as the free ionic liquid. Overall, the 10 mechanochemical approach proves to be effective in immobilizing ionic liquids in layered compounds and thus may expand the applications of ionic liquids and, meanwhile, improve catalyst separation and recycling.
摘要:
Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a propylene-based impact copolymer.
摘要:
Oriented films and methods of forming the same are discussed herein. The oriented films generally include a propylene based polymer and an additive selected from fluoropolymers, fluoroelastomers and combinations thereof, wherein the additive is present in an amount of from about 50 ppm to about 20,000 ppm.
摘要:
A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer and an epoxy nanocomposite coating. First, disperse a water dispersible filler material in a liquid comprising water, but without any added intercalation agent, to form a dispersion. Second, replace at least a portion of the water of the liquid with an organic solvent so that the water concentration of the liquid is less than six percent by weight to form the filler composition, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing the filler composition.
摘要:
Preforms for use in injection blow molding processes and such processes are described herein. The preforms can have both a body and a neck wherein the external body diameter of the preform is at most 95% of the external neck diameter. The body comprises internal and external diameters that together form a sidewall, the thickness of which can be greater than 2.0 mm. Also disclosed is a mold for the injection molding of the preform described above.
摘要:
Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a metallocene random propylene-based copolymer.
摘要:
A two step method for preparing a filler composition, the filler composition useful to prepare a nanocomposite polymer. The first step is to disperse a water dispersible filler material in a liquid comprising water to form a dispersion. The second step is to replace at least a portion of the water of the liquid with an organic solvent to form the filler composition, the water concentration of the liquid of the filler composition being less than six percent by weight, the average size of at least one dimension of the filler material being less than two hundred nanometers upon examination by transmission electron microscopy of a representative freeze dried sample of the dispersion of the first step. A nanocomposite polymer can be prepared by mixing the above-made filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing a filler having an average size of at least one dimension of the filler of less than two hundred nanometers upon examination by transmission electron microscopy of a representative sample of the polymer. In addition, an epoxy resin composition useful for making a cured epoxy nanocomposite polymer, the epoxy resin composition made by a two step process. The first step is to mix an epoxy resin with the filler composition to form an epoxy resin mixture. The second step is to remove organic solvent from the epoxy resin mixture to form the epoxy resin composition. And, a nanocomposite polymer, made by the step of mixing the filler composition with one or more polymer, polymer component, monomer or prepolymer to produce a polymer containing a filler having an average size of at least one dimension of the filler of less than two hundred nanometers upon examination by transmission electron microscopy of a representative sample of the polymer.
摘要:
Injection stretch blow molded (ISBM) articles and methods of forming the same are provided herein. In one embodiment, the ISBM articles generally include a propylene based random copolymer having a molecular weight distribution of from about 9 to about 20. In another embodiment, the ISBM articles generally include a propylene based random copolymer formed from a Ziegler-Natta catalyst including a succinate internal donor.
摘要:
Nanocomposites and method of making same are provided using nanoplatelets. A nanocomposite is provided, and the nanocomposite includes nanoparticles, inorganic platelets, and a polymer material. A method is provided for dispersing nanoparticles into a polymeric material by using inorganic nanoplatelets.