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公开(公告)号：US08597567B2
公开(公告)日：2013-12-03
申请号：US12612034
申请日：2009-11-04
CPC分类号： C04B35/475 , C04B35/495 , C04B35/62218 , C04B2235/3201 , C04B2235/3203 , C04B2235/3255 , C04B2235/3291 , C04B2235/3298 , C04B2235/5445 , C04B2235/6025 , C04B2235/6562 , C04B2235/6587 , C04B2235/77 , C04B2235/787 , C04B2235/79 , C04B2235/9623 , H01L41/1873 , H01L41/43
摘要： A ceramic sheet is produced by a method in which inorganic particles including, as a main component, an oxide represented by general formula ABO3 and containing a volatile component are mixed such that the A/B ratio is 1.05 or more, the inorganic particles are formed into a self-supported planar shaped body with a thickness of 30 μm or less, and the shaped body is fired, without an inactive layer or with an inactive layer which does not substantially react with the shaped body and is disposed adjacent to the shaped body, at a temperature-rising rate of 30° C./min or more in a temperature range which is equal to or higher than a temperature at which the volatile component is volatilized.
摘要翻译： 通过将以通式ABO3表示的含有挥发性成分的氧化物作为主要成分的无机粒子混合，使A / B比为1.05以上的方法制造陶瓷片，形成无机粒子 成为具有30μm以下的自支撑平面状体，成形体被烧成而不具有非活性层或不与成形体基本上反应的非活性层，并与成形体相邻配置 在等于或高于挥发性成分挥发的温度的温度范围内以30℃/分钟以上的升温速度进行。
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32.发明授权公开(公告)号：US08212455B2
公开(公告)日：2012-07-03
申请号：US12358559
申请日：2009-01-23
IPC分类号： H01L41/08
CPC分类号： H01L41/0973 , C01G23/003 , C01G25/00 , C01G25/006 , C01G33/006 , C01G35/006 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/62 , C01P2004/80 , C01P2006/40 , C04B35/462 , C04B35/475 , C04B35/493 , C04B35/495 , C04B35/6262 , C04B35/62685 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3251 , C04B2235/3255 , C04B2235/3279 , C04B2235/3298 , C04B2235/365 , C04B2235/5292 , C04B2235/5445 , C04B2235/6025 , C04B2235/768 , C04B2235/787 , H01L41/083 , H01L41/1873 , H01L41/1876 , H01L41/1878 , H01L41/43 , Y10T29/42
摘要： An actuator includes a fired ceramic substrate having a space opened downward, a first electrode formed on the upper surface of the fired ceramic substrate above the space, a piezoelectric/electrostrictive body formed on the first electrode so that the volume changes with input and output of electric power, and a second electrode formed on the piezoelectric/electrostrictive body. The piezoelectric/electrostrictive body is composed of Pb(Zr1-xTix)O3 or (Li, Na, K) (Nb, Ta)O3 as a main component and contains crystals oriented along the direction of an electric field. In the actuator, the degree of orientation of the piezoelectric/electrostrictive body can be increased regardless of the orientation of the substrate on which the piezoelectric/electrostrictive body is formed.
摘要翻译： 致动器包括具有向下开口的烧制陶瓷基板，形成在空间上方的烧结陶瓷基板的上表面上的第一电极，形成在第一电极上的压电/电致伸缩体，使得体积随着输入和输出而变化 电力和形成在压电/电致伸缩体上的第二电极。 压电/电致伸缩体由Pb（Zr1-xTix）O3或（Li，Na，K）（Nb，Ta）O3作为主要成分构成，并含有沿电场方向取向的晶体。 在致动器中，可以增加压电/电致伸缩体的取向度，而不管其上形成有压电/电致伸缩体的基板的取向如何。
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33.发明申请CERAMIC SHEET, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING CRYSTALLOGRAPHICALLY-ORIENTED CERAMIC 审中-公开陶瓷片及其制造方法以及用于生产以晶体为主的陶瓷的方法公开(公告)号：US20080248277A1
公开(公告)日：2008-10-09
申请号：US12014314
申请日：2008-01-15
IPC分类号： B32B18/00
CPC分类号： B32B18/00 , C04B37/001 , C04B2237/346
摘要： A ceramic sheet is self-supported and planar and has a thickness of 10 μm or less, wherein a surface of the sheet includes a specific crystal plane, and the number of crystal grains present in the thickness direction of the sheet at any one point is substantially one. Preferably, the aspect ratio of the crystal grains is 3 or more, and the degree of orientation measured by the Lotgering method is 30% or more. The crystal grains may be composed of an oxide represented by general formula ABO3, wherein the A site contains at least one element selected from the group consisting of Li, Na, K, Bi, and Ag, and the B site contains at least one element selected from the group consisting of Nb, Ta, and Ti. The crystal grains may be composed of an oxide having a perovskite structure and an isotropic shape.
摘要翻译： 陶瓷片是自支撑的并且是平面的并且具有10um或更小的厚度，其中片材的表面包括特定的晶面，并且在任何一个点处在片材的厚度方向上存在的晶粒的数量是 基本上一个。 优选地，晶粒的纵横比为3以上，并且通过浮法测定的取向度为30％以上。 晶粒可以由通式ABO 3 N表示的氧化物构成，其中A位含有选自Li，Na，K，Bi和Ag中的至少一种元素，以及 B位置包含选自Nb，Ta和Ti中的至少一种元素。 晶粒可以由具有钙钛矿结构和各向同性形状的氧化物构成。
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34.发明授权公开(公告)号：US08158255B2
公开(公告)日：2012-04-17
申请号：US12017567
申请日：2008-01-22
IPC分类号： B32B5/66
CPC分类号： C04B35/495 , C01G29/006 , C01G33/006 , C01G35/006 , C01P2002/34 , C01P2002/72 , C01P2004/03 , C04B35/475 , C04B35/493 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3251 , C04B2235/3279 , C04B2235/3284 , C04B2235/3291 , C04B2235/3298 , C04B2235/365 , C04B2235/5436 , C04B2235/5445 , C04B2235/6025 , C04B2235/762 , C04B2235/786 , C04B2235/79 , Y10T428/2982 , Y10T428/2991
摘要： A plate-like polycrystalline particle is produced by forming inorganic particles into a self-supported, sheet-like shaped body with a predetermined thickness, firing the shaped body, and crushing and classifying the fired shaped body by passing through a mesh having openings with a predetermined size. The inorganic particles are composed of an oxide having a perovskite structure and grow into crystal grains with an isotropic and polyhedral shape. Since grain growth in the thickness direction is limited and grain growth in the surface direction of the sheet is promoted, it is possible to obtain crystal grains having a high aspect ratio and a high degree of orientation. Therefore, in the plate-like polycrystalline particle, in most parts, the number of crystal grains present in the thickness direction of the particle at any one point is one, and a high aspect ratio and a high degree of orientation are achieved.
摘要翻译： 通过将无机粒子形成为具有预定厚度的自支撑的片状体，制成板状多晶粒子，烧成成形体，通过具有开口的网状物进行粉碎分级， 预定尺寸。 无机颗粒由具有钙钛矿结构的氧化物组成并且生长成具有各向同性和多面体形状的晶粒。 由于厚度方向的晶粒生长受到限制，并且促进了片材的表面方向的晶粒生长，因此可以获得具有高纵横比和高取向度的晶粒。 因此，在板状多晶粒子中，在大多数部分中，任何一点存在于粒子的厚度方向上的晶粒的数量为一个，并且实现高纵横比和高取向度。
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公开(公告)号：US20090185971A1
公开(公告)日：2009-07-23
申请号：US12035491
申请日：2008-02-22
CPC分类号： C01G23/003 , C01G25/00 , C01G33/006 , C01G35/006 , C01P2002/34 , C01P2002/52 , C01P2002/72 , C01P2006/40 , C04B35/493 , C04B35/495 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3249 , C04B2235/3251 , C04B2235/3255 , C04B2235/3279 , C04B2235/36 , C04B2235/6025 , C04B2235/787 , C04B2235/80 , H01L41/1873 , H01L41/1876 , H01L41/43
摘要： A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.
摘要翻译： 一种晶体取向陶瓷，其包括第一区域，其中晶核保留并且包含预定浓度范围的特定元素并且沿着晶面至少部分地以层状形式延伸，并且在第一区域中含有特定元素的第二区域 与第一区域不同的浓度范围，并且至少部分地沿着晶面延伸成层叠形状。 这些区域交替重复，并且在与晶面正交的方向上存在组成分布。 在第一区域，Na的浓度较高，K浓度较低，Nb浓度较低，Ta浓度高于第二区域，第二区域的Na浓度较低 ，K浓度较高，Nb浓度较高，Ta浓度低于第一区域。
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36.发明授权公开(公告)号：US08728342B2
公开(公告)日：2014-05-20
申请号：US13235662
申请日：2011-09-19
IPC分类号： H01M4/88
CPC分类号： H01M4/525 , C01G45/1228 , C01G51/50 , C01G53/50 , C01P2002/74 , C01P2006/40 , Y10T428/2982
摘要： An object of the present invention is to realize more effective intercalation and deintercalation of lithium ions in a cathode active material. The preset invention provides a cathode active material plate-like particle for a lithium secondary battery, the particle having a layered rock salt structure, wherein lithium-intercalation/deintercalation-plane-oriented grains (primary crystal grains whose (003) plane is oriented so as to intersect a plate surface of the plate-like particle) are present in a dispersed state among numerous (003)-plane-oriented grains (primary crystal grains whose (003) plane is oriented in parallel with the plate surface of the plate-like particle).
摘要翻译： 本发明的一个目的是在阴极活性材料中实现更有效的插入和脱嵌锂离子。 本发明提供了一种用于锂二次电池的阴极活性材料板状颗粒，该颗粒具有层状岩盐结构，其中锂嵌入/脱嵌面取向晶粒（其（003）面取向为一次晶粒 与板状颗粒的板表面相交）在许多（003）平面取向晶粒（其中（003）面与板状颗粒的板表面平行取向的主晶粒）中以分散状态存在， 像粒子）。
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公开(公告)号：US07799158B2
公开(公告)日：2010-09-21
申请号：US12013602
申请日：2008-01-14
CPC分类号： B32B18/00 , C04B35/493 , C04B35/495 , C04B35/64 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3251 , C04B2235/3279 , C04B2235/3284 , C04B2235/365 , C04B2235/5445 , C04B2235/6025 , C04B2235/656 , C04B2235/6562 , C04B2235/661 , C04B2235/768 , C04B2235/787 , C04B2235/79 , C04B2235/9623 , C04B2237/345 , C04B2237/346 , C04B2237/582 , C04B2237/62 , C04B2237/68 , C04B2237/704 , H01L41/1873 , H01L41/43 , Y10S117/902
摘要： A method for producing a crystallographically-oriented ceramic includes the steps of forming a first sheet with a thickness of 10 μm or less containing a first inorganic material in which grain growth occurs at a first temperature or higher and a second sheet containing a second inorganic material in which grain growth occurs at a second temperature higher than the first temperature, laminating one or more each of the first and second sheets to form a laminated body, firing the laminated body at a temperature equal to or higher than the first temperature and lower than the second temperature to cause grain growth in the first inorganic material, and then firing the laminated body at a temperature equal to or higher than the second temperature to cause grain growth in the second inorganic material in the direction of a crystal plane of the first inorganic material.
摘要翻译： 制造结晶取向陶瓷的方法包括以下步骤：形成厚度为10μm以下的第一片材，其含有在第一温度以上发生晶粒生长的第一无机材料和含有第二无机材料的第二片材 其中在比第一温度高的第二温度下发生晶粒生长，层压第一和第二片中的一个或多个以形成层压体，在等于或高于第一温度并低于 所述第二温度在所述第一无机材料中引起晶粒生长，然后在等于或高于所述第二温度的温度下焙烧所述层压体，以使所述第二无机材料在所述第一无机材料的晶面方向上晶粒生长 材料。
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38.发明申请公开(公告)号：US20080206561A1
公开(公告)日：2008-08-28
申请号：US12017567
申请日：2008-01-22
CPC分类号： C04B35/495 , C01G29/006 , C01G33/006 , C01G35/006 , C01P2002/34 , C01P2002/72 , C01P2004/03 , C04B35/475 , C04B35/493 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3251 , C04B2235/3279 , C04B2235/3284 , C04B2235/3291 , C04B2235/3298 , C04B2235/365 , C04B2235/5436 , C04B2235/5445 , C04B2235/6025 , C04B2235/762 , C04B2235/786 , C04B2235/79 , Y10T428/2982 , Y10T428/2991
摘要： A plate-like polycrystalline particle is produced by forming inorganic particles into a self-supported, sheet-like shaped body with a predetermined thickness, firing the shaped body, and crushing and classifying the fired shaped body by passing through a mesh having openings with a predetermined size. The inorganic particles are composed of an oxide having a perovskite structure and grow into crystal grains with an isotropic and polyhedral shape. Since grain growth in the thickness direction is limited and grain growth in the surface direction of the sheet is promoted, it is possible to obtain crystal grains having a high aspect ratio and a high degree of orientation. Therefore, in the plate-like polycrystalline particle, in most parts, the number of crystal grains present in the thickness direction of the particle at any one point is one, and a high aspect ratio and a high degree of orientation are achieved.
摘要翻译： 通过将无机粒子形成为具有预定厚度的自支撑的片状体，制成板状多晶粒子，烧成成形体，通过具有开口的网状物进行粉碎分级， 预定尺寸。 无机颗粒由具有钙钛矿结构的氧化物组成并且生长成具有各向同性和多面体形状的晶粒。 由于厚度方向的晶粒生长受到限制，并且促进了片材的表面方向的晶粒生长，因此可以获得具有高纵横比和高取向度的晶粒。 因此，在板状多晶粒子中，在大多数部分中，任何一点存在于粒子的厚度方向上的晶粒的数量为一个，并且实现高纵横比和高取向度。
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39.发明申请公开(公告)号：US20120085967A1
公开(公告)日：2012-04-12
申请号：US13235662
申请日：2011-09-19
IPC分类号： H01M4/525
CPC分类号： H01M4/525 , C01G45/1228 , C01G51/50 , C01G53/50 , C01P2002/74 , C01P2006/40 , Y10T428/2982
摘要： An object of the present invention is to realize more effective intercalation and deintercalation of lithium ions in a cathode active material. The preset invention provides a cathode active material plate-like particle for a lithium secondary battery, the particle having a layered rock salt structure, wherein lithium-intercalation/deintercalation-plane-oriented grains (primary crystal grains whose (003) plane is oriented so as to intersect a plate surface of the plate-like particle) are present in a dispersed state among numerous (003)-plane-oriented grains (primary crystal grains whose (003) plane is oriented in parallel with the plate surface of the plate-like particle).
摘要翻译： 本发明的一个目的是在阴极活性材料中实现更有效的插入和脱嵌锂离子。 本发明提供了一种用于锂二次电池的阴极活性材料板状颗粒，该颗粒具有层状岩盐结构，其中锂嵌入/脱嵌面取向晶粒（其（003）面取向为一次晶粒 与板状颗粒的板表面相交）在许多（003）平面取向晶粒（其中（003）面与板状颗粒的板表面平行取向的主晶粒）中以分散状态存在， 像粒子）。
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公开(公告)号：US07700067B2
公开(公告)日：2010-04-20
申请号：US12035491
申请日：2008-02-22
CPC分类号： C01G23/003 , C01G25/00 , C01G33/006 , C01G35/006 , C01P2002/34 , C01P2002/52 , C01P2002/72 , C01P2006/40 , C04B35/493 , C04B35/495 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3249 , C04B2235/3251 , C04B2235/3255 , C04B2235/3279 , C04B2235/36 , C04B2235/6025 , C04B2235/787 , C04B2235/80 , H01L41/1873 , H01L41/1876 , H01L41/43
摘要： A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.
摘要翻译： 一种晶体取向陶瓷，其包括第一区域，其中晶核保留并且包含预定浓度范围的特定元素并且沿着晶面至少部分地以层状形式延伸，并且在第一区域中含有特定元素的第二区域 与第一区域不同的浓度范围，并且至少部分地沿着晶面延伸成层叠形状。 这些区域交替重复，并且在与晶面正交的方向上存在组成分布。 在第一区域，Na的浓度较高，K浓度较低，Nb浓度较低，Ta浓度高于第二区域，第二区域的Na浓度较低 ，K浓度较高，Nb浓度较高，Ta浓度低于第一区域。
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