摘要:
Mechanically and thermally improved rechargeable batteries, modules and fluid-cooled battery pack systems. The battery is prismatic in shape with an optimized thickness to width to height aspect ratio which provides the battery with balanced optimal properties when compared with prismatic batteries lacking this optimized aspect ratio. The optimized thickness, width and height allow for maximum capacity and power output, while eliminating deleterious side affects. The battery case design allows for unidirectional expansion which is readily compensated for by applying external mechanical compression counter to that direction. In the module, the batteries are bound within a module bundling/compression means under external mechanical compression which is optimized to balance outward pressure due to expansion and provide additional inward compression to reduce the distance between the positive and negative electrodes, thereby increasing overall battery power. The fluid-cooled battery pack includes; 1) a battery-pack case having coolant inlet and outlet; 2) battery modules within the case such that the battery module is spaced from the case walls and from other battery modules to form coolant flow channels along at least one surface of the bundled batteries; and 3) at least one coolant transport means. The width of the coolant flow channels allows for maximum heat transfer. Finally the batteries, modules and packs can also include means for providing variable thermal insulation to at least that portion of the rechargeable battery system which is most directly exposed to said ambient thermal condition, so as to maintain the temperature of the rechargeable battery system within the desired operating range thereof under variable ambient conditions.
摘要:
Fuel cell cathodes and instant startup fuel cells employing the cathode. The cathodes operate through the mechanism of redox couples which uniquely provide multiple degrees of freedom in selecting the operating voltages available for such fuel cells. Such cathodes provide the fuel cells in which they are used a “buffer” or “charge” of oxidizer available within the cathode at all times.
摘要:
An active electrode composition comprising an active electrode material and a binder where the binder comprises a monosaccharide, a disaccharide, a pectin or a molasses. Preferably, the active electrode material is nickel hydroxide.
摘要:
Fuel cell oxygen electrode and instant startup fuel cells employing such oxygen electrode. The oxygen electrode operates through the mechanism of redox couples which uniquely provide multiple degrees of freedom in selecting the operating voltages available for such fuel cells. Such oxygen electrodes provide the fuel cells in which they are used a “buffer” or “charge” of oxidizer available within the oxygen electrode at all times.
摘要:
A fuel cell which has the ability to start up instantly and can accept recaptured energy such as that of regenerative braking by operating in reverse as an electrolyzer. The instant startup fuel cells have increased efficiency and power availability (higher voltage and current) and a dramatic improvement in operating temperature range of about −20 to 150° C.
摘要:
A fuel cell utilizing parallel flow of a hydrogen stream, an oxygen stream, and an electrolyte solution with respect to the electrodes, while maintaining mechanical support within the fuel cell. The fuel cell utilizes electrode assemblies having a frame overmolded around the electrode to maintain a flow rates and low pressure throughout the fuel cell. The fuel cell is also designed to maintain mechanical support within the fuel cell while the electrodes expand and contract in response to the absorption of oxygen and hydrogen.
摘要:
A hydrogen storage alloy active material for the anode of Ovonic instant startup/regenerative fuel cells. The active material includes a hydrogen storage alloy material with a water reactive chemical hydride additive, which, upon utilization of the active material in an anode of an alkaline electrolyte fuel cell, gives the anode added benefits, not attainable by using hydrogen storage alloy material alone. These added benefits include 1) precharge of the hydrogen storage material with hydrogen; 2) higher porosity/increased surface area/reduced electrode polarization at high currents; 3) simplified, faster activation of the hydrogen storage alloy; and 4) optionally, enhanced corrosion protection for the hydrogen storage alloy.
摘要:
A layered hydrogen absorbing alloy electrode for an alkaline electrochemical cell. The layered electrode comprises a outer layer comprising a metal oxide, metal sulfide or mixtures thereof. The outer layer reduces the internal pressure of electrochemical cell.
摘要:
A positive electrode active material mixture comprising: a nickel hydroxide material, and an additive material comprising at least one element selected from the group consisting of calcium cobalt oxide, calcium titanium oxide, calcium molybdenum oxide, lithium cobalt oxide, and mixtures thereof. A nickel positive electrode comprising this active material mixture. A nickel-based, alkaline electrochemical cell comprising this positive electrode.
摘要:
The present invention discloses a process and apparatus for removing sodium and chloride ions from an aqueous sodium chloride solution, such as seawater or brine. The process includes electrolyzing aqueous sodium chloride to remove chloride and sodium ions in the form of chlorine gas and sodium metal. Preferably, a photovoltaic device, such as a triple junction amorphous silicon solar cell, provides the electrical energy for the electrolysis. The process utilizes electrode material that facilitates the production of chlorine gas and inhibits the evolution of hydrogen from the aqueous sodium chloride solution. The sodium is deposited onto a metal surface having a high hydrogen overpotential to produce sodium amalgam. The processed solution from the electrolysis has a reduced sodium chloride content and may be further processed to produce fresh water for human consumption or agricultural purposes. The sodium amalgam is removed from the aqueous sodium chloride solution and transported to and coupled against an air depolarizing fuel cell in water to produce electrical power with the sodium air fuel cell, power that may be used to operate the apparatus or other machinery. The product of the reaction between the sodium amalgam and the fuel cell is sodium hydroxide that may be reacted with the chlorine gas to produce sodium hypochlorite.