Functionalized high vinyl terminated propylene based oligomers
    37.
    发明授权
    Functionalized high vinyl terminated propylene based oligomers 有权
    官能化高乙烯基封端的丙烯基低聚物

    公开(公告)号:US08399725B2

    公开(公告)日:2013-03-19

    申请号:US12487739

    申请日:2009-06-19

    摘要: This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.

    摘要翻译: 本发明涉及Mn为300〜30,000g / mol,含有10〜90mol%丙烯和10〜90mol%乙烯的官能化共聚物,其中低聚物具有至少X%的烯丙基链端,其中:1 )X =( - 0.94(加入摩尔%乙烯)+100),当共聚低聚物中存在10至60摩尔%的乙烯时,和2)X = 45,当大于60且小于70摩尔%的乙烯为 存在于共聚低聚物中,和3)X =(1.83 *(摩尔%乙烯掺入)-83),当共聚低聚物中存在70至90摩尔%的乙烯时。 本发明还涉及包含丙烯的官能化均聚物,其中所述低聚物具有:至少93%的烯丙基链端,约500至约20,000g / mol的Mn,异丁基链至烯丙基乙烯基的比例为0.8 :1〜1.2:1.0,小于100ppm的铝。 本发明还涉及制备包含丙烯的官能化均聚物或共聚物的方法,其中生产率大于4500g / mmol Hf(或Zr)/小时。

    Polymacromonomer and Process For Production Thereof
    38.
    发明申请
    Polymacromonomer and Process For Production Thereof 失效
    聚异构体及其制备方法

    公开(公告)号:US20120309903A1

    公开(公告)日:2012-12-06

    申请号:US13589388

    申请日:2012-08-20

    IPC分类号: C08F210/06 C08F4/76 C08F4/80

    摘要: This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.

    摘要翻译: 本发明涉及包含至少一种大分子单体和0-20重量%的C 2 -C 12共聚单体的聚异氰酸酯,其中所述大分子单体具有至少70%的乙烯基封端,并且其中所述聚异淀粉体具有:a)ag值小于 0.6,b)大于30,000g / mol的Mw,c)大于20,000g / mol的Mn,d)支链指数(g')vis小于0.5,e)小于25%的乙烯基封端, f)至少70重量%的大分子单体,基于聚共聚单体的重量,g)0至20重量%的含芳族单体,基于聚共聚单体的重量,以及h)任选地,熔点为50℃,或 更多。 本发明还涉及制备这种聚异构体的方法。

    Polymacromonomer and process for production thereof
    39.
    发明授权
    Polymacromonomer and process for production thereof 失效
    聚共聚物及其制备方法

    公开(公告)号:US08283428B2

    公开(公告)日:2012-10-09

    申请号:US12488066

    申请日:2009-06-19

    摘要: This invention relates to a polymacromonomer comprising at least one macromonomer and from 0 to 20 wt % of a C2 to C12 comonomer, wherein the macromonomer has vinyl termination of at least 70%, and wherein the polymacromonomer has: a) a g value of less than 0.6, b) an Mw of greater than 30,000 g/mol, c) an Mn of greater than 20,000 g/mol, d) a branching index (g′)vis of less than 0.5, e) less than 25% vinyl terminations, f) at least 70 wt % macromonomer, based upon the weight of the polymacromonomer, g) from 0 to 20 wt % aromatic containing monomer, based upon the weight of the polymacromonomer and h) optionally, a melting point of 50° C. or more. This invention also relates to processes to make such polymacromonomers.

    摘要翻译: 本发明涉及包含至少一种大分子单体和0-20重量%的C 2 -C 12共聚单体的聚异氰酸酯,其中所述大分子单体具有至少70%的乙烯基封端,并且其中所述聚异淀粉体具有:a)ag值小于 0.6,b)大于30,000g / mol的Mw,c)大于20,000g / mol的Mn,d)支链指数(g')vis小于0.5,e)小于25%的乙烯基封端, f)至少70重量%的大分子单体,基于聚共聚单体的重量,g)0至20重量%的含芳族单体,基于聚共聚单体的重量,以及h)任选地,熔点为50℃,或 更多。 本发明还涉及制备这种聚异构体的方法。