公开(公告)号：US20050065363A1

公开(公告)日：2005-03-24

申请号：US10980238

申请日：2004-11-04

Applicant: Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

Inventor： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

IPC: C07C67/055 ,  C07C67/39

CPC classification number: C07C67/055 ,  C07C69/017 ,  C07C69/157

Abstract: A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups IIIb, IVb, Vb and VIb of the periodic table, and (C) at least one element selected from elements of groups IIIa and IVa of the periodic table. Preferably, element (B) is selected from elements of group VIb of the periodic table, and element (C) is contained in a metal oxide form in the catalyst. The catalytic activity can be maintained at a high level, and a phenyl ester is stably produced. The phenyl ester can be converted to phenol by a conventional procedure.

Abstract translation: 通过使苯，羧酸和分子氧在包含（A）钯，（B）选自IIIb，IVb，Vb族元素中的至少一种元素的催化剂存在下，使苯，羧酸和分子氧彼此反应来制备苯基酯， VIb，和（C）选自元素周期表IIIa和IVa族元素的至少一种元素。 优选地，元素（B）选自元素周期表VIb族的元素，元素（C）以催化剂中的金属氧化物形式包含。 可以将催化活性维持在高水平，并稳定地生产苯酯。 苯基酯可以通过常规方法转化成苯酚。

公开(公告)号：US06528679B1

公开(公告)日：2003-03-04

申请号：US09670268

申请日：2000-09-27

Applicant: Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

Inventor： Yoshihiko Mori ,  Takao Doi ,  Tetsuo Asakawa ,  Takanori Miyake

IPC: C07C67055

CPC classification number: C07C67/055 ,  C07C69/017 ,  C07C69/157

Abstract: A phenyl ester is produced by allowing benzene, a carboxylic acid and molecular oxygen to react with each other in the presence of a catalyst comprising (A) palladium, (B) at least one element selected from elements of groups 13, 14, 15, and 16 and the fourth to sixth periods of the periodic table, and (C) at least one element selected from elements of groups 3, 4 and lanthanoid elements of the periodic table. Preferably, element (B) is selected from elements of group 16 and the fourth to sixth periods of the periodic table, and element (C) is contained in a metal oxide form in the catalyst. The phenyl ester can be converted to phenol by hydrolysis or ester exchange.

Abstract translation: 通过使苯，羧酸和分子氧在催化剂的存在下反应来制备苯酯，所述催化剂包含（A）钯，（B）至少一种选自组13,14,15， 周期表的16和第四至第六周期，以及（C）选自元素周期表中的第3,4族和镧系元素的元素中的至少一种元素。 优选地，元素（B）选自元素周期表第16族元素和第四至第六元素元素，元素（C）以催化剂中的金属氧化物形式包含。 苯基酯可以通过水解或酯交换转化成苯酚。